Tough thermoplastic starch modified with polyurethane microparticles: Effects of molecular weight of soft segments in polyurethane

Industrial and Engineering Chemistry Research

Volumn 50, Issue 4, 2011, Pages 2111-2116

  Zhang, Yu ^a   Zhang, Pingping ^a   Chen, Xiaoxia ^a   Wu, Zhengshun ^a   Wu, Qiangxian ^a  

^a CENTRAL CHINA NORMAL UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

ADIPATES; BREAKING ELONGATION; BUTYLENE GLYCOL; LOW MOLECULAR WEIGHT; MATRIX; MICRO-PARTICLES; MODIFIED STARCHES; MULTIFUNCTIONAL GROUP; POLYURETHANE PREPOLYMERS; REACTION EFFICIENCY; REACTION RATIO; SOFT SEGMENTS; SPECIAL STRUCTURE; THERMOPLASTIC STARCH; URETHANE BONDS; WEIGHT-AVERAGE MOLECULAR WEIGHT;

BUTENES; GLYCOLS; MOLECULAR WEIGHT; REINFORCED PLASTICS; STRUCTURE (COMPOSITION);

STARCH;

EID: 79951489848     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie102068v     Document Type: Article

References (34)

1. Cao, X. D.; Chang, P. R.; Huneault, M. A. Preparation and properties of plasticized starch modified with poly(e-caprolactone) based waterborne polyurethane Carbohydr. Polym. 2008, 71, 119-125 (Pubitemid 350016311)
2. Lu, Y. S.; Lan, T.; Patrice, D.; Erre, D. Preparation and properties of starch thermoplastics modified with waterborne polyurethane from renewable resources Polymer. Polym. 2005, 46, 9863-9870 (Pubitemid 41455217)
3. Viviana, P. C.; Mara, C. T. Z.; Anala, V. Relationship Between Structure and Properties of Modified Potato Starch Biodegradable Films J. Appl. Polym. Sci. 2006, 101, 4313-4319
4. Liebert, T.; Kulicke, W. M.; Heinze, Th. Novel approach towards hydrolytically stable starch acetates for physiological applications React. Funct. Polym. 2008, 68, 1-11 (Pubitemid 50008374)
5. Zhang, L. N.; Cao, X. D. Patent CN 1560120A, 2005.
6. Biswas, A.; Shogren, R. L.; Kim, S.; Willett, J. L. Rapid preparation of starch maleate half-esters Carbohydr. Polym. 2006, 64, 484-487
7. Stojanovi, .; Katsikas, L.; Popovi, I.; Jovanovi, S.; Jeremi, K. Thermal stability of starch benzoate Polym. Degrad. Stab. 2005, 87, 177-182
8. Ha, S. K.; Broecker, H. C. Characteristics of polyurethanes incorporating starch granules Polymer 2002, 43, 5227-5234
9. Kweon, D. K.; Cha, D. S.; Park, H. J.; Lim, S. T. Starch-g- polycaprolactone copolymerization using diisocyanate intermediates and thermal characteristics of the copolymers J. Appl. Polym. Sci. 2000, 78, 986-993
10. Barikani, M.; Mohammadi, M. Synthesis and characterization of starch-modified polyurethane Carbohydr. Polym. 2007, 68, 773-780 (Pubitemid 46412475)
11. Tsutomu, O.; Seung, H. L. Effect of aliphatic isocyanates (HDI and LDI) as coupling agents on the properties of eco-composites from biodegradable polymers and corn starch Adhes. J. Sci. Technol. 2004, 18, 905-924
12. Ha, S. K.; Broecker, H. C. The Cross-Linking of Polyurethane Incorporated with Starch Granules and their Rheological Properties: Influences of Starch Content and Reaction Conditions Macromol. Mater. Eng. 2003, 288, 569-577
13. Herrera, M.; Matuschek, G.; Kettrup, A. Thermal degradation of thermoplastic polyurethane elastomers (TPU) based on MDI Polym. Degrad. Stab. 2002, 78, 323-331
14. Santayanon, R.; Wootthikanokkhan, J. Modification of cassava starch by using propionic anhydride and properties of the starch-blended polyester polyurethane Carbohydr. Polym. 2003, 51, 17-24
15. Wu, Q. X. Patent CN 101100531A, 2008.
16. Wu, Q. X.; Wu, Z. S.; Tian, H. F.; Zhang, Y.; Cai, S. L. Structure and Properties of Tough Thermoplastic Starch Modified with Polyurethane Microparticles Ind. Eng. Chem. Res. 2008, 47, 9896-9902
17. Jimenez, G.; Asai, S.; Shishido, A.; Sumita, M. Effect of the soft segment on the fatigue behavior of segmented polyurethanes Eur. Polym. J. 2000, 36, 2039-2050
18. Wang, T. L.; Hsuef, T. H. Synthesis and characterization of new block copolyurethanes based on 1,2-ethylene bis(4-phenylisocyanate) Polym. J. 1996, 28, 839-844
19. Cong, S. F.; Yu, L. R. Polyurethane coatings. Beijing Chem. Ind. Press 2003, 287-288
20. Shukla, R.; Cheryan, M. Zein: the industrial protein from corn Ind. Crops. Prod. 2001, 13, 171-192 (Pubitemid 32826511)
21. Wu, Q. X.; Hiroshi, S.; Seiichiro, I. Processing and Properties of Low Cost Corn Gluten Meal/Wood Fiber Composite Ind. Eng. Chem. Res. 2003, 42, 6765-6773
22. Sheikh, N.; Katbab, A. A.; Mirzadeh, H. Isocyanate-terminated urethane prepolymer as bioadhesive base material: Synthesis and characterization Int. J. Adhes. Adhes. 2000, 20, 299-304
23. Xie, W. L.; Shao, L. Phosphorylation of Corn Starch in an Ionic Liquid Starch/Strke 2009, 61, 702-708
24. Van Soest, J. J. G.; Vliegenthart, J. F. G. Crystallinity in starch plastics: Consequences for material properties Trends Biotechnol. 1997, 15, 208-213 (Pubitemid 27242745)
25. Dai, H. G.; Chang, P. R.; Geng, F. Y.; Yu, J. G.; Ma, X. F. Preparation and Properties of Thermoplastic Starch/Montmorillonite Nanocomposite Using N-(2-Hydroxyethyl) formamide as a New Additive J. Polym. Environ. 2009, 17, 225-232
26. Lin, J. R.; Chen, L. W. Shape-Memorized Crosslinked Ester-Type Polyurethane and Its Mechanical Viscoelastic Model J. Appl. Polym. Sci. 1999, 73, 1305-1319
27. Chen, A. F.; Yao, C.; Zeng, S. M.; Yi, C. F.; Xu, Z. S. Preparation and Properties of Hyperbranched Polyurethanes via Oligomeric A2+bB2 Approach Polym. Bull. 2008, 61, 363-371
28. Lu, Y. S.; Tighzert, L.; Berzin, F.; Rondot., S. Innovative plasticized starch films modified with waterborne polyurethane from renewable resources Carbohydr. Polym. 2005, 61, 174-182 (Pubitemid 41013919)
29. Sailaja, R. R. N.; Seetharamu, S. Itaconic acid-grafted-LDPE as compatibilizer for LDPE-plasticized Tapioca starch blends React. Funct. Polym. 2008, 68, 831-841
30. Zhang, Q. X.; Yu, Z. Z.; Xie, X. L.; Naito, K.; Kagawa, Y. Preparation and crystalline morphology of biodegradable starch/clay nanocomposites Polymer 2007, 48, 7193-7200 (Pubitemid 350054952)
31. Liu, X. X.; Yu, L.; Liu, H. S.; Chen, L.; Li, L. In situ thermal decomposition of starch with constant moisture in a sealed system Polym. Degrad. Stab. 2008, 93, 260-262
32. Chuang, F. S.; Tsen, W. C.; Shu, Y. C. The effect of different siloxane chain-extenders on the thermal degradation and stability of segmented polyurethanes Polym. Degrad. Stab. 2004, 84, 69-77
33. Chuang, F. S. Analysis of thermal degradation of diacetylene-containing polyurethane copolymers Polym. Degrad. Stab. 2007, 92, 1393-1407 (Pubitemid 46977020)
34. Jiang, H. M.; Zheng, Z.; Song, W. H.; Li, Z. M.; Wang, X. L. Alkoxysilane Functionalized Polyurethane/Polysiloxane Copolymers: Synthesis and the Effect of End-Capping Agent Polym. Bull. 2007, 59, 53-63 (Pubitemid 46996053)