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Volumn 133, Issue 5, 2011, Pages 1290-1293

Oxygen binding to [Pd(L)(L′)] (L= NHC, L′ = NHC or PR 3, NHC = N -heterocyclic carbene). Synthesis and structure of a paramagnetic trans -[Pd(NHC)2(η1-O2) 2] complex

Author keywords

[No Author keywords available]

Indexed keywords

COMPUTATIONAL STUDIES; DIAMAGNETIC COMPLEX; N-HETEROCYCLIC CARBENES; OXYGEN BINDING; P-TOLYL; REACTIVITY CHANGES; SECOND ORDERS; SOLUTION CALORIMETRY; STERIC PRESSURE; STOPPED-FLOW KINETICS;

EID: 79551716815     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja1103348     Document Type: Article
Times cited : (51)

References (37)
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    • 3676 For a review on the role of NHC in late transition metal catalysis, see
    • Díez-González, S.; Marion, N.; Nolan, S. P. Chem. Rev. 2009, 109, 3612-3676 For a review on the role of NHC in late transition metal catalysis, see
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    • Díez-González, S.1    Marion, N.2    Nolan, S.P.3
  • 12
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    • references cited therein,-183 For seminal work on transition metal-peroxo complexes, see
    • and references cited therein Vaska, L. Acc. Chem. Res. 1976, 9, 175-183 For seminal work on transition metal-peroxo complexes, see
    • (1976) Acc. Chem. Res. , vol.9 , pp. 175
    • Vaska, L.1
  • 23
    • 79551703183 scopus 로고    scopus 로고
    • CCDC-800882 (3) and CCDC-800883 (5) contain the supplementary crystallographic data for this contribution. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via.
    • CCDC-800882 (3) and CCDC-800883 (5) contain the supplementary crystallographic data for this contribution. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/ data-request/cif.
  • 24
    • 79551703493 scopus 로고    scopus 로고
    • 2) was 0.1261 for 6664 reflections, I > 2σ(I).
    • 2) was 0.1261 for 6664 reflections, I > 2σ(I).
  • 25
    • 33746217434 scopus 로고    scopus 로고
    • 3869 This is close to the O-O bond distance value of 1.280(3) Å reported for the only other related superoxide structure the authors could locate, that for a Cu complex
    • Würtele, C.; Gaoutchenova, E.; Harms, K.; Holthausen, M. C.; Sundermeyer, J.; Schindler, S. Angew. Chem., Int. Ed. 2006, 45, 3867-3869 This is close to the O-O bond distance value of 1.280(3) Å reported for the only other related superoxide structure the authors could locate, that for a Cu complex
    • (2006) Angew. Chem., Int. Ed. , vol.45 , pp. 3867
    • Würtele, C.1    Gaoutchenova, E.2    Harms, K.3    Holthausen, M.C.4    Sundermeyer, J.5    Schindler, S.6
  • 27
    • 75649103176 scopus 로고    scopus 로고
    • For NHC ligand steric parameters, see
    • For NHC ligand steric parameters, see: Clavier, H.; Nolan, S. P. Chem. Commun. 2010, 46, 841-861
    • (2010) Chem. Commun. , vol.46 , pp. 841-861
    • Clavier, H.1    Nolan, S.P.2
  • 32
    • 79551697029 scopus 로고    scopus 로고
    • Preliminary stopped-flow studies at -20 ̊C show a biphasic process.
    • Preliminary stopped-flow studies at -20 ̊C show a biphasic process.
  • 34
    • 79551692800 scopus 로고    scopus 로고
    • 2) was 0.0375 for 10 468 reflections, I > 2σ(I).
    • 2) was 0.0375 for 10 468 reflections, I > 2σ(I).
  • 35
    • 33745688109 scopus 로고    scopus 로고
    • For a selection of monohydroperoxide structurally characterized complexes, see the following.;,-2907 For Pd-NHC
    • For a selection of monohydroperoxide structurally characterized complexes, see the following. Konnick, M. M.; Gandhi, B. A.; Guzei, I. A.; Stahl, S. S. Angew. Chem., Int. Ed. 2006, 45, 2904-2907 For Pd-NHC
    • (2006) Angew. Chem., Int. Ed. , vol.45 , pp. 2904
    • Konnick, M.M.1    Gandhi, B.A.2    Guzei, I.A.3    Stahl, S.S.4


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.