Al12K8[OCH33: A wade, zintl, or metalloid cluster, or a hybrid of all three?

Angewandte Chemie - International Edition

Volumn 49, Issue 18, 2010, Pages 3146-3150

  Henke, Patrick ^a   Trapp, Nils ^b   Anson, Christopher E ^a   Schnöckel, Hansgeorg ^a  

^a KARLSRUHE INSTITUTE OF TECHNOLOGY   (Germany)

^b UNIVERSITY OF FREIBURG   (Germany)

Author keywords

Aluminum; Cluster compounds; Metalloid clusters; Wade clusters; Zintl phases

Indexed keywords

ALUMINUM CLUSTERS; CLUSTER MODELS; DFT CALCULATION; METALLOID CLUSTERS; STRUCTURAL INVESTIGATION; ZINTL PHASIS;

SULFUR COMPOUNDS; THERMODYNAMIC PROPERTIES;

ALUMINUM;

EID: 77951591778     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.200907096     Document Type: Article

References (67)

1. K.-W. Klinkhammer, W. Uhl, I Wagner, W. Hiller, Angew. Chem. 1991, 103, 182;
2. Angew. Chem. Int. Ed. Engl. 1991, 30, 179.
3. A presentation given at Dalton Discussion no. 11: Renaissance of Main Group Elements, University of California, Berkeley (USA), 2008. See Ref. [11].
4. H. W. Roesky, Inorg. Chem. 2004, 43, 7284.
5. K. Wade, Adv. Inorg. Chem. Radiochem. 1976, 18, 1.
6. A. Purath, R. Köppe, H. Schnöckel, Chem. Commun, 1999, 1933.
7. G. Linti, H. Schnöckel, W. Uhl, N. Wiberg in Molecular Clusters of the Main Group Elements (Eds.: M. Drieß, H. Nöth), WileyVCH, Weinheim, 2004, pp. 126.
8. A. Schnepf, G. Stößer, H. Schnöckel, J. Am. Chem. Soc. 2000, 122, 9178.
9. H. Schnöckel, A. Schnepf, ACS Symp. Ser. 2002, 822, 154.
10. H. Schnöckel, A. Schnepf, Adv. Organomet. Chem. 2001, 47, 235.
11. H. Schnöckel, H. Köhnlein, Polyhedron 2002, 21, 489.
12. H. Schnöckel, Dalton Trans. 2008, 4344.
13. H. Schnöckel, Dalton Trans. 2005, 3131.
14. A. Schnepf, G. Stößer, R. Köppe, H. Schnöckel, Angew. Chem. 2000, 112, 1709;
15. Angew. Chem. Int. Ed. 2000, 39, 1637.
16. K. Koch, R. Burgert, H. Schnöckel, Angew. Chem. 2007, 119, 5897;
17. Angew. Chem. Int. Ed. 2007, 46, 5795.
18. K. Koch, H. Schnöckel, Z. Anorg. Allg. Chem. 2007, 633, 873.
19. R. Henning, E. A. Leon-Escamilla, J.-T. Zhao, J. D. Corbett, Inorg. Chem. 1997, 36, 1282.
20. W. Klemm, E. Busmann, Z. Anorg. Allg. Chem. 1963, 319, 297.
21. E. Zintl, Angew. Chem 1939, 52, 1.
22. [23,24]
23. P. Henke, M. Huber, J. Steiner, K. Bowen, B. Eichhorn, H. Schnöckel, J. Am. Chem. Soc. 2009, 131, 5698.
24. S. C. Sevov, J. D. Corbett, Science 1993, 262, 880.
25. G. Cordier, V. Müller, Z. Naturforsch. B 1994, 49, 935;
26. Z.-C. Dong, J. D. Corbett, J. Am. Chem. Soc. 1995, 117, 6447.
27. A. Simon, Coord Chem. Rev. 1997, 163, 253.
28. A. Simon in Clusters of the Heavier Group 13 elements (Eds. : M. Drieß, H. Nöth), Wiley-VCH, Weinheim, 2004, p. 246.
29. J. D. Corbett, Angew. Chem. 2000, 112, 682;
30. Angew. Chem. Int. Ed. 2000, 39, 670.
31. [28,29]
32. G. Linti, S. Coban, D. Dutta, Z. Anorg. Allg. Chem. 2004, 630, 319.
33. B. Quillian, P. Wei, C. S. Wannere, P. v. R. Schleyer, G. H. Robinson, J. Am. Chem. Soc. 2009, 131, 3168.
34. R. Wolf, W. UhI, Angew. Chem. 2009, 121, 6905;
35. Angew. Chem. Int. Ed. 2009, 48, 6114.
36. C. Dohmeier, D. Loos, H. Schnöckel, Angew. Chem. 1996, 108, 141;
37. Angew. Chem. Int. Ed. Engl. 1996, 35, 129.
38. -3. See The Supporting Information (S3) for refinement details. CCDC 757644 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac. uk/data-request/cif.
39. 3 groups causing less repulsion and therefore longer KAl distances.
40. 3 groups causing less repulsion and therefore longer KAl distances.
41. C. Klemp, M. Bruns, J. Gauss, U. Häussermann, G. Stößer, L. van Wüllen, M. Jansen, H. Schnöckel, J. Am. Chem. Soc. 2001, 123, 9099.
42. C. Klemp, R. Köppe, E. Weckert, H. Schnöckel, Angew. Chem. 1999, 111,1851;
43. Angew. Chem. Int. Ed. 1999, 38, 1739.
44. 27Al NMR spectra obviously have to be assigned to byproducts, because there is no correlation to the calculated products (see the Supporting Information).
45. [38]
46. J. Vollet, R. Bürgert, H. Schnöckel, Angew. Chem. 2005, 117, 7117;
47. Angew. Chem. Int. Ed. 2005, 44, 6956.
48. [40]
49. C. Dohmeier, M. Mocker, H. Schnöckel, A. Lötz, U Schneider, R. Ahlrichs, Angew. Chem. 1993, 105, 1491;
50. Angew. Chem. Int. Ed. Engl. 1993, 32,1428.
51. A. L. Kerlin, W. G. Clark, Phys. Rev. B 1975, 12, 3533.
52. D. Hechtfischer, R. Karcher, K. Luders, J. Phys. F1973, 3, 2021.
53. I Hartig, A. Schnepf, I de Jongh, D. Bono, H. Schnöckel, Z. Anorg. Allg. Chem. 2007, 633, 63.
54. P. Yang, R. Koppe, T. Duan, J. Hartig, G. Hadiprono, B. Pilawa, I. Keilhauer, H. Schnöckel, Angew. Chem. 2007, 119, 3650;
55. Angew. Chem. Int. Ed. 2007, 46, 3579.
56. M. Binnewies, E. Milke, Thermochemical Data of Elements and Compounds, Wiley-VCH, 2002.
57. [47] methods and further sophisticated calculations, are a challenge for theoretical investigations.
58. A. Savin, R. Nesper, S. Wengert, T. F. Fässler, Angew. Chem. 1997, 109, 1892;
59. Angew. Chem. Int. Ed. Engl. 1997, 36, 1808.
60. M. Ruck, F. Steden, Z. Anorg. Allg. Chem. 2007, 633, 1556.
61. N. J. Bjerrum, G. P. Smith, Inorg. Chem. 1967, 6, 1968.
62. H. Schäfer, M. Binnewies, W. Domke, J. Karbinski, Z. Anorg. Allg. Chem. 1974, 403, 116.
63. H. Schäfer, Z. Anorg. Allg. Chem. 1975, 414, 151.
64. H. Schäfer, J. Cryst. Growth 1975, 31, 31.
65. T. Duan, E. Baum, R. Burgert, H. Schnöckel, Angew. Chem. 2004, 116, 3252;
66. Angew. Chem. Int. Ed. 2004, 43, 3190.
67. 3 + 14KBr.