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Volumn 43, Issue 18, 2010, Pages 7482-7487

Versatile route to functionalized vinylic addition polynorbornenes

Author keywords

[No Author keywords available]

Indexed keywords

AZIDO GROUP; CLICK CHEMISTRY; FUNCTIONALIZED; MONOMER RATIO; NORBORNENES; NUCLEOPHILIC SUBSTITUTION REACTIONS; NUCLEOPHILIC SUBSTITUTIONS; PHENYLTHIO; POLAR MONOMER; POLYNORBORNENES;

EID: 78651321274     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma101137z     Document Type: Article
Times cited : (42)

References (52)
  • 41
    • 78651283305 scopus 로고    scopus 로고
    • HBr elimination is not observed in these substitution reactions. Only if polymers 7-9 are treated with a stronger base such as a hydroxide salt in refluxing THF does the elimination of HBr become an important process
    • HBr elimination is not observed in these substitution reactions. Only if polymers 7-9 are treated with a stronger base such as a hydroxide salt in refluxing THF does the elimination of HBr become an important process.
  • 42
    • 0033990485 scopus 로고    scopus 로고
    • The reactions were carried out in refluxing THF or toluene. The azido derivative is synthesized under more stringent conditions, DMF at 120 °C, and the resulting polymer 14 is only slightly soluble; the same solubility change is observed in 7 when it is kept in DMF at 120 °C for several hours. The change of properties of polynorbornenes upon heating has been studied and it has been attributed to conformational changes of the rigid cyclic units of the polymer backbone
    • The reactions were carried out in refluxing THF or toluene. The azido derivative is synthesized under more stringent conditions, DMF at 120 °C, and the resulting polymer 14 is only slightly soluble; the same solubility change is observed in 7 when it is kept in DMF at 120 °C for several hours. The change of properties of polynorbornenes upon heating has been studied and it has been attributed to conformational changes of the rigid cyclic units of the polymer backbone (Chu, P. P.; Huang, W.-J.; Chang, F.-C.; Fan, S. Y. Polymer 2000, 401-404).
    • (2000) Polymer , pp. 401-404
    • Chu, P.P.1    Huang, W.-J.2    Chang, F.-C.3    Fan, S.Y.4
  • 51
    • 78651310050 scopus 로고    scopus 로고
    • 3 as internal standard
    • 3 as internal standard.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.