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2642647443
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2-enyl palladacycles is referred to as n.5-membered, n being the number of atoms in the cycle and adding 0.5 to account for the π-coordination of the double bond to the metal (see, for example: Omae, I. Angew. Chem., Int. Ed. Engl. 1982, 21, 889).
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17
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85087250102
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-
note
-
3 used as solvent, since the quantity of the compounds handled in the monitored experiments, and so the amount of crotonato formed, is very small.
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21
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37049100924
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23
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37049084935
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(a) Henderson, W.; Kemmitt, R. D. W.; Prouse, L. J. S.; Russell, D. R. J. Chem. Soc., Dalton Trans. 1989, 259.
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Henderson, W.1
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37049074802
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(b) Chiu, K. W.; Fawcett, J.; Henderson, W.; Kemmitt, R. D. W. J. Chem. Soc., Dalton Trans. 1987, 733.
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26
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85087250442
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-
note
-
19F NMR spectrum of 14 and 17, probably as a result of the prochiral nature of the double bond and the dimeric nature of the complexes. The diastereomeric ratios are 1:0.6 (14) and 1:0.8 (17).
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27
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3743145108
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Schlosser, M., Ed.; Wiley: Chichester, Chapter 5
-
The cyclization reactions of dimethyl diallylmalonate have been studied, see: (a) Hegedus, L. S. In Organometallics in Synthesis; Schlosser, M., Ed.; Wiley: Chichester, 1994; Chapter 5. (b) Larock, R. C. Adv. Met.-Org. Chem. 1994, 3, 97. (c) Oppolzer, W. Angew. Chem., Int. Ed. Engl. 1989, 28, 38. (d) Grigg, R.; Mitchell, T. R. B.; Ramasubbu, A. J. Chem. Soc., Chem. Commun. 1979, 669.
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Hegedus, L.S.1
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28
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0002776257
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The cyclization reactions of dimethyl diallylmalonate have been studied, see: (a) Hegedus, L. S. In Organometallics in Synthesis; Schlosser, M., Ed.; Wiley: Chichester, 1994; Chapter 5. (b) Larock, R. C. Adv. Met.-Org. Chem. 1994, 3, 97. (c) Oppolzer, W. Angew. Chem., Int. Ed. Engl. 1989, 28, 38. (d) Grigg, R.; Mitchell, T. R. B.; Ramasubbu, A. J. Chem. Soc., Chem. Commun. 1979, 669.
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Larock, R.C.1
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84990107570
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The cyclization reactions of dimethyl diallylmalonate have been studied, see: (a) Hegedus, L. S. In Organometallics in Synthesis; Schlosser, M., Ed.; Wiley: Chichester, 1994; Chapter 5. (b) Larock, R. C. Adv. Met.-Org. Chem. 1994, 3, 97. (c) Oppolzer, W. Angew. Chem., Int. Ed. Engl. 1989, 28, 38. (d) Grigg, R.; Mitchell, T. R. B.; Ramasubbu, A. J. Chem. Soc., Chem. Commun. 1979, 669.
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Oppolzer, W.1
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37049108155
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The cyclization reactions of dimethyl diallylmalonate have been studied, see: (a) Hegedus, L. S. In Organometallics in Synthesis; Schlosser, M., Ed.; Wiley: Chichester, 1994; Chapter 5. (b) Larock, R. C. Adv. Met.-Org. Chem. 1994, 3, 97. (c) Oppolzer, W. Angew. Chem., Int. Ed. Engl. 1989, 28, 38. (d) Grigg, R.; Mitchell, T. R. B.; Ramasubbu, A. J. Chem. Soc., Chem. Commun. 1979, 669.
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0001612711
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Albéniz, A. C.; Espinet, P.; Lin, Y.-S. Organometallics 1997, 16, 4030.
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32
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85087249813
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note
-
1H NMR spectrum of 22 was difficult to assign because of heavy overlapping of its signals with other compounds.
-
-
-
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33
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3743105082
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-
note
-
A small amount of starting diallyl sulfone is catalytically isomerized to 2,3-dihydro-3,4-dimethylthiophene-1,1-dioxide (32, 4%) by "PdHBr" through insertion into Pd-H bonds and cyclization.
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34
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31544457567
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3: (e) Ikenaga, K.; Kikukawa, K.; Matsuda, T. J. Org. Chem. 1987, 52, 1276. (f) Karabelas, K.; Hallberg, A. J. Org. Chem. 1986, 51, 5286. (g) Ikenaga, K.; Kikukawa, K.; Matsuda, T. J. Chem. Soc. Perkin Trans. 1986, 1959.
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3: (e) Ikenaga, K.; Kikukawa, K.; Matsuda, T. J. Org. Chem. 1987, 52, 1276. (f) Karabelas, K.; Hallberg, A. J. Org. Chem. 1986, 51, 5286. (g) Ikenaga, K.; Kikukawa, K.; Matsuda, T. J. Chem. Soc. Perkin Trans. 1986, 1959.
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3: (e) Ikenaga, K.; Kikukawa, K.; Matsuda, T. J. Org. Chem. 1987, 52, 1276. (f) Karabelas, K.; Hallberg, A. J. Org. Chem. 1986, 51, 5286. (g) Ikenaga, K.; Kikukawa, K.; Matsuda, T. J. Chem. Soc. Perkin Trans. 1986, 1959.
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3: (e) Ikenaga, K.; Kikukawa, K.; Matsuda, T. J. Org. Chem. 1987, 52, 1276. (f) Karabelas, K.; Hallberg, A. J. Org. Chem. 1986, 51, 5286. (g) Ikenaga, K.; Kikukawa, K.; Matsuda, T. J. Chem. Soc. Perkin Trans. 1986, 1959.
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0001264281
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3: (e) Ikenaga, K.; Kikukawa, K.; Matsuda, T. J. Org. Chem. 1987, 52, 1276. (f) Karabelas, K.; Hallberg, A. J. Org. Chem. 1986, 51, 5286. (g) Ikenaga, K.; Kikukawa, K.; Matsuda, T. J. Chem. Soc. Perkin Trans. 1986, 1959.
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0343714212
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2- with allyl ether to form palladium-(II)-allyl complex 38 and propenal has also been reported, see: Pietropaolo, R.; Faraone, F.; Sergi, S.; Pietropaolo, D. J. Organomet. Chem. 1972, 42, 177.
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43
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85087249978
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note
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3 elimination gives 39 and allyl(dimethyl)bromosilane.
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44
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0004259440
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