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Volumn 16, Issue 26, 1997, Pages 5964-5973

Study of the evolution of η1-η2-enylpalladium complexes when the palladium-migration process is blocked

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EID: 0142143199     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9707228     Document Type: Article
Times cited : (16)

References (49)
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    • note
    • 3 used as solvent, since the quantity of the compounds handled in the monitored experiments, and so the amount of crotonato formed, is very small.
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    • note
    • 19F NMR spectrum of 14 and 17, probably as a result of the prochiral nature of the double bond and the dimeric nature of the complexes. The diastereomeric ratios are 1:0.6 (14) and 1:0.8 (17).
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    • note
    • 1H NMR spectrum of 22 was difficult to assign because of heavy overlapping of its signals with other compounds.
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    • note
    • A small amount of starting diallyl sulfone is catalytically isomerized to 2,3-dihydro-3,4-dimethylthiophene-1,1-dioxide (32, 4%) by "PdHBr" through insertion into Pd-H bonds and cyclization.
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    • note
    • 3 elimination gives 39 and allyl(dimethyl)bromosilane.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.