An update on nanomaterials-based textiles for protection and decontamination

Journal of the American Ceramic Society

Volumn 93, Issue 12, 2010, Pages 3955-3975

  Sundarrajan, Subramanian ^a   Chandrasekaran, Arun Richard ^b,c   Ramakrishna, Seeram ^a  

^a NATIONAL UNIVERSITY OF SINGAPORE   (Singapore)

^b UNIVERSITY OF MADRAS   (India)

^c NEW YORK UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATED CHARCOAL; BIOLOGICAL WARFARES; BLISTER AGENTS; CERAMIC OXIDES; EFFICIENT CATALYSTS; HIGH ASPECT RATIO; METAL OXIDE NANOPARTICLES; METAL OXIDES; MIXED METAL OXIDE; NANO-MATERIALS; RECENT TRENDS; SYNTHETIC ROUTES; TIO; TOXIC CHEMICALS; UV LIGHT;

ASPECT RATIO; CERAMIC MATERIALS; DECONTAMINATION; FABRICS; METAL IONS; METALLIC COMPOUNDS; NANOPARTICLES; PHOTOCATALYSTS; PROTECTIVE CLOTHING;

METALS;

EID: 78650362308     PISSN: 00027820     EISSN: 15512916     Source Type: Journal    
DOI: 10.1111/j.1551-2916.2010.04117.x     Document Type: Article

References (196)

1. A. I. Mamchik, S. V. Kalinin, and, A. A. Vertegel, " Cryosol Synthesis of Nanocrystalline Alumina," Chem. Mater., 10, 3548-54 (1998).
2. S. Ramesh, E. Sominska, B. Cina, R. Chaim, and, A. Gedanken, " Nanocrystalline γ-Alumina Synthesized by Sonohydrolysis of Alkoxide Precursor in the Presence of Organic Acids: Structure and Morphological Properties," J. Am. Ceram. Soc., 83, 89-94 (2000).
3. J. A. Wang, X. Bokhimi, A. Morales, O. Novaro, T. Lopez, and, R. Gomez, " Aluminum Local Environment and Defects in the Crystalline Structure of SolGel Alumina Catalyst," J. Phys. Chem. B, 103, 299-303 (1999).
4. 3 Doped in and Coated on Silica and Alumina Nanoparticles," J. Phys. Chem. B, 103, 3361-5 (1999).
5. P. A. Dokhale, N. D. Sali, P. M. Kumar, S. V. Bhoraskar, V. K. Rohatgi, V. N. Bhoraskar, S. K. Date, and, S. Badrinarayanan, " Enhanced Surface Activity in Nanocrystalline Alumina as Studied by Neutron Activation Analysis, X-Ray Photoelectron and Infrared Spectroscopy," Mater. Sci. Eng. B, 49, 18-26 (1997).
6. J. S. C. Jang, and, C. C. Koch, " The Hall-Petch Relationship in Nanocrystalline Iron Produced by Ball Milling," Scr. Metall. Mater., 24, 1599-604 (1990).
7. T. C. Chou, D. Adamson, J. Mardinly, and, T. G. Nieh, " Microstructural Evolution and Properties of Nanocrystalline Alumina Made by Reactive Sputtering Deposition," Thin Solid Films, 205, 131-9 (1991).
8. 2 Catalyst for deNOx," J. Metastable Nanocryst. Mater., 23, 95-8 (2005).
9. O. B. Koper, I. Lagadic, A. Volodin, and, K. J. Klabunde, " Alkaline-Earth Oxide Nanoparticles Obtained by Aerogel Methods. Characterization and Rational for Unexpectedly High Surface Chemical Reactivities," Chem. Mater., 9, 2468-80 (1997).
10. Y. Li, and, K. J. Klabunde, " Nanoscale Metal Oxide Particles as Chemical Reagents. Destructive Adsorption of a Chemical Agent Simulant, Dimethyl Methylphosphonate, on Heat-Treated Magnesium Oxide," Langmuir, 7, 1388-93 (1991).
11. Y. Li, O. Koper, M. Atteya, and, K. J. Klabunde, " Adsorption and Decomposition of Organophosphorus Compounds on Nanoscale Metal Oxide Particles. In Situ GC-MS Studies of Pulsed Microreactions over Magnesium Oxide," Chem. Mater., 4, 323-30 (1992).
12. G. W. Wagner, O. B. Koper, E. Lucas, S. Decker, and, K. J. Klabunde, " Reactions of VX, GD, and HD with Nanosize CaO: Autocatalytic Dehydrohalogenation of HD," J. Phys. Chem. B, 104, 5118-23 (2000).
13. A. F. Bedilo, M. J. Sigel, O. B. Koper, M. S. Melgunov, and, K. J. Klabunde, " Synthesis of Carbon-Coated MgO Nanoparticles," J. Mater. Chem., 12, 3599-604 (2002).
14. A. L. Simonian, T. A. Good, S.-S. Wang, and, J. R. Wild, " Nanoparticle-Based Optical Biosensors for the Direct Detection of Organophosphate Chemical Warfare Agents and Pesticides," Anal. Chim. Acta, 534, 69-77 (2005).
15. J. G. Ekerdt, K. J. Klabunde, J. R. Shapley, J. M. White, and, J. T. Yates Jr., " Surface Chemistry of Organophosphorus Compounds," J. Phys. Chem., 92, 6182-8 (1988).
16. N. Choi, J. Kwak, Y. Lim, T. Bahn, K. Yun, J. Kim, J. Huh, and, D. Lee, " Classification of Chemical Warfare Agents Using Thick Film Gas Sensor Array," Sens. Actuators B, 108, 298-304 (2005).
17. 3. Formation of Aluminophosphonates," J. Am. Chem. Soc., 123, 1636-44 (2001).
18. G. W. Wagner, P. W. Bartram, O. Koper, and, K. J. Klabunde, " Reactions of VX, GD, and HD with Nanosize MgO," J. Phys. Chem. B, 103, 3225-8 (1999).
19. G. W. Wagner, and, P. W. Bartram, " 31P MAS NMR Study of the Hydrolysis of O,S-Diethyl Phenylphosphonothioate on Reactive Sorbents," J. Mol. Catal. A: Chem., 99, 175-l81 (1995).
20. G. W. Wagner, and, P. W. Bartram, " Reactions of the Nerve Agent Simulant Diisopropyl Fluorophosphate with Self-Decontaminating Adsorbents. A 31P MAS NMR Study," J. Mol. Catal. A: Chem., 144, 419-24 (1999).
21. S. Rajagopalan, O. Koper, S. Decker, and, K. J. Klabunde, " Nanocrystalline Metal Oxides as Destructive Adsorbents for Organophosphorus Compounds at Ambient Temperatures," Chem. Eur. J., 8 [11] 2602-7 (2002).
22. L. D. Rotz, A. S. Khan, S. R. Lillibridge, S. M. Ostroff, and, J. M. Hughes, " Public Health Assessment of Potential Biological Terrorism Agents," Emerg. Infect. Dis., 8 [2] 225-30 (2002).
23. W. D. Burrows, and, S. E. Renner, " Biological Warfare Agents as Threats to Potable Water," Environ. Health Perspect., 107 [12] 975-84 (1999).
24. J. M. Madsen, " Toxins as Weapons of Mass Destruction. A Comparison and Contrast with Biological-Warfare and Chemical-Warfare Agents," Clin. Lab. Med., 21 [3] 593-605 (2001).
25. J. C. Pile, J. D. Malone, E. M. Eitzen, and, A. M. Friedlander, " Anthrax as a Potential Biological Warfare Agent," Arch. Intern. Med., 158, 429-34 (1998).
26. J. R. Morones, J. L. Elechiguerra, A. Camacho, K. Holt, J. B. Kouri, J. T. Ramirez, and, M. J. Yacaman, " The Bactericidal Effect of Silver Nanoparticles," Nanotechnology, 16, 2346-53 (2005).
27. O. B. Koper, J. S. Klabunde, G. L. Marchin, K. J. Klabunde, P. Stoimenov, and, L. Bohra, " Nanoscale Powders and Formulations with Biocidal Activity Toward Spores and Vegetative Cells of Bacillus Species, Viruses, and Toxins," Curr. Microbiol., 44, 49-55 (2002).
28. J. Zhou, S. Ma, Y. C. Kang, and, D. A. Chen, " Dimethyl Methylphosphonate Decomposition on Titania-Supported Ni Clusters and Films: A Comparison of Chemical Activity on Different Ni Surfaces," J. Phys. Chem. B, 108, 11633-44 (2004).
29. X. H. Ren, L. Kou, H. B. Kocer, C. Y. Zhu, S. D. Worley, R. M. Broughton, and, T. S. Huang, " Antimicrobial Coating of an N-halamine Biocidal Monomer on Cotton Fibers via Admicellar Polymerization," Colloids Surf. A, 317, 711-6 (2008).
30. R. Dastjerdi, M. Montazer, and, S. Shahsavan, " A New Method to Stabilize Nanoparticles on Textile Surfaces," Colloids Surf. A, 345, 202-10 (2009).
31. 2/PP Antibacterial Nanocomposites Filament Yarns," J. Text. Inst., 101, 204-13 (2010).
32. Y. Hasebe, K. Kuwahara, and, S. Tokunaga, " Chitosan Hybrid Deodorant Agent for Finishing Textiles," AATCC Rev., 1 [11] 23-8 (2001).
33. Y. Kobayashi, T. Nakanishi, and, J. Komiyama, " Deodorant Properties of Wool Fabrics Dyed with Acid Mordant Dyes and a Copper Salt," Text. Res. J., 72 [2] 125-31 (2002). (Pubitemid 34213066)
34. J. Payne, " From Medical Textiles to Smell-Free Socks," J. Soc. Dyers and Colour., 113, 48-50 (1997).
35. R. Bagherzadeh, M. Montazer, M. Latifi, M. Sheikhzadeh, and, M. Sattari, " Evaluation of Comfort Properties of Polyester Knitted Spacer Fabrics Finished with Water Repellent and Antimicrobial Agents," Fibers Polym., 8 [4] 386-92 (2007).
36. M. Montazer, and, M. G. Afjeh, " Simultaneous X-Linking and Antimicrobial Finishing of Cotton Fabric," J. Appl. Polym. Sci., 103, 178-85 (2007).
37. J. V. Edwards, and, T. Vigo, Bioactive Fibers and Polymers. American Chemical Society, Washington, DC, 2001.
38. R. Dastjerdi, and, M. Montazer, " A Review on the Application of Inorganic Nanostructured Materials in the Modification of Textiles: Focus on Anti-Microbial Properties," Colloids Surf., B, 79, 5-18 (2010).
39. H. Studer, " Antimicrobial Protection for Polyolefin Fibers," Chem. Fibers Int., 47 [5] 373-4 (1997).
40. 2 Nanocomposites for Antimicrobial Coatings," J. Phys. Chem. B, 109 [18] 8889-98 (2005).
41. Y. W. H. Wong, C. W. M. Yuen, M. Y. S. Leung, S. K. A. Ku, and, H. L. I. Lam, " Selected Applications of Nanotechnology in Textiles," AUTEX Res. J., 6 [1] 1-8 (2006).
42. L. Qian, and, J. P. Hinestroza, " Application of Nanotechnology for High Performance Textiles," J. Text. Apparel, Technol. Manage., 4 [1] 1-7 (2004).
43. 4V and Titanium by Streaming Potential and Streaming Current Measurements," Colloids Surf., B, 26, 387-95 (2002).
44. K. Cai, J. Bossert, and, K. D. Jandt, " Does the Nanometre Scale Topography of Titanium Influence Protein Adsorption and Cell Proliferation," Colloids Surf., B, 49, 136-44 (2006).
45. 2 Nano-Powder Synthesized by Homogeneous Precipitation Process at Low Temperatures," Colloids Surf., A, 220, 169-77 (2003).
46. 2/DNA/Thionin Nanocomposite Modified Electrode," Colloids Surf., B, 66, 266-73 (2008).
47. 2 Colloid," Colloids Surf., B, 40, 137-42 (2005). (Pubitemid 40228613)
48. 2-Polyacrylic Acid Dispersions with Potential for Molecular Recognition," Colloids Surf., B, 64, 10-5 (2008).
49. 2," Colloids Surf., B, 51, 107-11 (2006).
50. Y. Dong, Z. Bai, L. Zhang, R. Liu, and, T. Zhu, " Finishing of Cotton Fabrics with Aqueous Nano-Titanium Dioxide Dispersion and the Decomposition of Gaseous Ammonia by Ultraviolet Irradiation," J. Appl. Polym. Sci., 99, 286-91 (2006).
51. 2 Films on Cellulose Fibres: Synthesis and Characterization," J. Photochem. Photobiol., A, 189, 286-94 (2007).
52. 2 Photocatalytic Reduction of Selenate Ions," Chem. Eng. J., 95, 179-86 (2003).
53. M. Stamate, and, G. Lazar, " Application of Titanium Dioxide Photocatalysis to Create Self-Cleaning Materials," Rom. Techn. Sci. Acad., 3, 280-5 (2007).
54. 2 Particles in Aqueous Solutions," Ultrason. Sonochem., 15, 386-92 (2008).
55. B. Mahltig, H. Haufe, and, H. Bottcher, " Functionalisation of Textiles by Inorganic Sol-Gel Coatings," J. Mater. Chem., 15, 4385-98 (2005).
56. 2-Rutile Modification Under Daylight Irradiation at Ambient Temperature," J. Photochem. Photobiol., A, 172, 27-43 (2005).
57. 2 Clusters Attached by Chemical Spacers," J. Mol. Catal. A: Chem., 237, 101-8 (2005).
58. R. Blossey, " Self-Cleaning Surfaces-Virtual Realities," Nat. Mater., 2, 301-6 (2003).
59. W. A. Daoud, and, J. H. Xin, " Low Temperature Sol-Gel Processed Photocatalytic Titania Coating," J. Sol-Gel Sci. Technol., 29, 25-9 (2004).
60. W. A. Daoud, J. H. Xin, and, Y. H. Zhang, " Surface Functionalization of Cellulose Fibers with Titanium Dioxide Nanoparticles and their Combined Bactericidal Activities," Surf. Sci., 599, 69-75 (2005).
61. 2 Nanocomposite Prepared by In Situ Polycondensation," J. Appl. Polym. Sci., 100, 1588-93 (2006).
62. 2 Film for Environmental Purification Deposited by Controlled Electron Beam-Excited Plasma," Thin Solid Films, 386, 173-6 (2001).
63. 2 Photocatalysts. 2. Optical Characterization, Photocatalysis, and Potential Application to Air Purification," Chem. Mater., 17, 2596-602 (2005).
64. 2 Photocatalytic Mechanisms in Water Purification by Use of Quinoline, Photo-Fenton Generated OH Radicals and Superoxide Dismutase," J. Phys. Chem. B, 101, 2650-8 (1997).
65. 2)," Solid State Ionics, 177, 229-36 (2006).
66. 2 Thin Films: Effects of Co Doping," Thin Solid Films, 484, 34-8 (2005).
67. J. Verran, G. Sandoval, N. S. Allen, M. Edge, and, J. Stratton, " Variables Affecting the Antibacterial Properties of Nano and Pigmentary Titania Particles in Suspension," Dyes Pigm., 73, 298-304 (2007).
68. Z. W. Pan, Z. R. Dai, and, Z. L. Wang, " Nanobelts of Semiconducting Oxides," Science, 291, 1947-9 (2001).
69. M. S. Arnold, P. Avouris, Z. W. Pan, and, Z. L. Wang, " Field-Effect Transistors Based on Single Semiconducting Oxide Nanobelts," J. Phys. Chem. B, 107, 659-63 (2003).
70. M. Xiong, G. Gu, B. You, and, L. Wu, " Preparation and Characterization of Poly(Styrene Butylacrylate) Latex/Nano-ZnO Nanocomposites," J. Appl. Polym. Sci., 90, 1923-31 (2003).
71. M. A. Behnajady, N. Modirshahla, and, R. Hamzavi, " Kinetic Study on Photocatalytic Degradation of C.I. Acid Yellow 23 by ZnO Photocatalyst," J. Hazard. Mater., 133, 226-32 (2006).
72. Y. Q. Li, S. Y. Fu, and, Y. M. Mai, " Preparation and Characterization of Transparent ZnO/Epoxy Nanocomposites with High-UV Shielding Efficiency," Polymer, 47, 2127-32 (2006).
73. E. Tang, G. Cheng, X. Ma, X. Pang, and, Q. Zhao, " Surface Modification of Zinc Oxide Nanoparticle by PMAA and its Dispersion in Aqueous System," Appl. Surf. Sci., 252, 5227-32 (2006).
74. Z. L. Wang, " Zinc Oxide Nanostructures: Growth, Properties and Applications," J. Phys.: Condens. Matter, 16, 829-58 (2004).
75. Z. L. Wang, " Nanostructures of Zinc Oxide," Mater. Today, 7 [6] 26-33 (2004).
76. Z. L. Wang, " Novel Nanostructures of ZnO for Nanoscale Photonics, Optoelectronics, Piezoelectricity, and Sensing," Appl. Phys. A: Mater. Sci. Process., 88, 7-15 (2007).
77. N. Vigneshwaran, S. Kumar, A. A. Kathe, P. V. Varadarajan, and, V. Prasad, " Functional Finishing of Cotton Fabrics Using Zinc Oxide-Soluble Starch Nanocomposites," Nanotechnology, 17, 5087-95 (2006). (Pubitemid 44523716)
78. A. Becheri, M. Durr, P. L. Nostro, and, P. Baglioni, " Synthesis and Characterization of Zinc Oxide Nanoparticles: Application to Textiles as UV-Absorbers," J. Nanoparticle Res., 10, 679-8 (2007).
79. T. Xu, and, C. S. Xie, " Tetrapod-Like Nano-Particle ZnO/Acrylic Resin Composite and its Multi-Function Property," Prog. Org. Coat., 46, 297-301 (2003).
80. Q. Li, S. L. Chen, and, W. C. Jiang, " Durability of Nano ZnO Antibacterial Cotton Fabric to Sweat," J. Appl. Pol. Sci., 103, 412-6 (2007).
81. R. W. Morrison, " Overview of Current Collecive Protection Filtation Technology " Presented in 2002 NBC Defense Collective Protection Conference, USA, 2002. Available at http://www.natick.army.mil/soldier/jocotas/ ColPro-Papers/Morrison.pdf (accessed May 2, 2010).
82. B. D. Cullity, and, C. D. Graham, Introduction to Magnetic Materials. John Wiley & Sons Inc., New York, 2008.
83. K. A. Easom, K. J. Klabunde, C. M. Sorensen, and, G. C. Hadjipanayis, " Nanoscale Magnetic Particles. New Methods to Surface Protected Metallic and Immiscible Bimetallic Clusters/Particles," Polyhedron, 13 [8] 1197-223 (1994).
84. M. L. Steigerwald, and, L. E. Brus, " Semiconductor Crystallites: A Class of Large Molecules," Acc. Chem. Res., 23 [6] 183-8 (1990).
85. Y. Wang, and, N. Herron, " Quantum Size Effects on the Exciton Energy of CdS Clusters," Phys. Rev. B, 42 [11] 7253-5 (1990).
86. A. N. Goldstein, C. M. Echer, and, A. P. Alivisatos, " Melting in Semiconductor Nanocrystals," Science, 256, 1425-7 (1992).
87. C. R. Henry, " Catalytic Activity of Supported Nanometer-Sized Metal Clusters," Appl. Surf. Sci., 164 [1-4] 252-9 (2000).
88. Y.-C. Yang, " Chemical Detoxification of Nerve Agent VX," Acc. Chem. Res., 32, 109-15 (1999).
89. Y.-C. Yang, J. A. Baker, and, J. R. Ward, " Decontamination of Chemical Warfare Agents," Chem. Rev., 92 [8] 1729-43 (1992).
90. C. L. Carnes, P. N. Kapoor, K. J. Klabunde, and, J. Bonevich, " Synthesis, Characterization, and Adsorption Studies of Nanocrystalline Aluminum Oxide and a Bimetallic Nanocrystalline Aluminum Oxide/Magnesium Oxide," Chem. Mater., 14, 2922-9 (2002).
91. G. Larsen, R. Velarde-Ortiz, K. Minchow, A. Barrero, and, I. G. Loscertales, " A Method for Making Inorganic and Hybrid (Organic/Inorganic) Fibers and Vesicles with Diameters in the Submicrometer and Micrometer Range Via Sol-Gel Chemistry and Electrically Forced Liquid Jets," J. Am. Chem. Soc., 125, 1154-5 (2003).
92. N. Choi, Y. Lee, J. Kwak, J. Park, K. Park, K. Shin, H. Park, J. Kim, J. Huh, and, D. Lee, " Chemical Warfare Agent Sensor Using MEMS Structure and Thick Film Fabrication Method," Sens. Actuators, B, 108, 177-83 (2005). (Pubitemid 40743685)
93. A. Malinauskas, " Chemical Deposition of Conducting Polymers," Polymer, 42, 3957-72 (2001).
94. R. Si, Y. Zhang, L. You, and, C. Yan, " Rare-Earth Oxide Nanopolyhedra, Nanoplates, and Nanodisks," Angew. Chem., Int. Ed., 44, 3256-60 (2005).
95. S. M. Kanan, and, C. P. Tripp, " An Infrared Study of Adsorbed Organophosphonates on Silica: A Prefiltering Strategy for the Detection of Nerve Agents on Metal Oxide Sensors," Langmuir, 17, 2213-8 (2001).
96. C. L. Carnes, J. Stipp, and, K. J. Klabunde, " Synthesis, Characterization, and Adsorption Studies of Nanocrystalline Copper Oxide and Nickel Oxide," Langmuir, 18, 1352-9 (2002).
97. I. Gill, and, A. Ballesteros, " Degradation of Organophosphorous Nerve Agents by Enzyme-Polymer Nanocomposites: Efficient Biocatalytic Materials for Personal Protection and Large-Scale Detoxification," Biotechnol. Bioeng., 70 [4] 400-1 (2000).
98. V. N. Sheinker, and, M. B. Mitchell, " Quantitative Study of the Decomposition of Dimethyl Methylphosphonate (DMMP) on Metal Oxides at Room Temperature and Above," Chem. Mater., 14, 1257-68 (2002).
99. M. B. Mitchell, V. N. Sheinker, and, E. A. Mintz, " Adsorption and Decomposition of Dimethyl Methylphosphonate on Metal Oxides," J. Phys. Chem. B, 101, 11192-203 (1997).
100. M. B. Mitchell, V. N. Sheinker, A. B. Tesfamichael, E. N. Gatimu, and, M. Nunley, " Decomposition of Dimethyl Methylphosphonate (DMMP) on Supported Cerium and Iron Co-Impregnated Oxides at Room Temperature," J. Phys. Chem. B, 107, 580-6 (2003).
101. M. B. Mitchell, V. N. Sheinker, W. W. Cox Jr., E. N. Gatimu, and, A. B. Tesfamichael, " The Room Temperature Decomposition Mechanism of Dimethyl Methylphosphonate (DMMP) on Alumina-Supported Cerium Oxide-Participation of Nano-Sized Cerium Oxide Domains," J. Phys. Chem. B, 108, 1634-45 (2004).
102. R. M. Narske, " Solvent Effects on the Heterogeneous Adsorption and Reactions of (2-Chloroethyl)ethyl Sulfide on Nanocrystalline Magnesium Oxide," Langmuir, 18, 4819-25 (2002).
103. S. Utamapanya, K. J. Klabunde, and, J. R. Schlup, " Nanoscale Metal Oxide Particles/Clusters as Chemical Reagents. Synthesis and Properties of Ultrahigh Surface Area Magnesium Hydroxide and Magnesium Oxide," Chem. Mater., 3, 175-81 (1991).
104. O. Koper, Y. Li, and, K. J. Klabunde, " Destructive Adsorption of Chlorinated Hydrocarbons on Ultrafine (Nanoscale) Particles of Calcium Oxide," Chem. Mater., 5, 500-5 (1993).
105. P. D. Hooker, and, K. J. Klabunde, " Destructive Adsorption of Carbon Tetrachloride on Iron(III) Oxide," Environ. Sci. Technol., 28, 1243-7 (1994).
106. O. Koper, E. Lucas, and, K. J. Klabunde, " Development of Reactive Topical Skin Protectants against Sulfur Mustard and Nerve Agents," J. Appl. Toxicol., 19, 59-70 (1999).
107. V. Stengl, S. Bakardjieva, M. Marikova, P. Bezdicka, and, J. Subrt, " Magnesium Oxide Nanoparticles Prepared by Ultrasound Enhanced Hydrolysis of Mg-Alkoxides," Mater. Lett., 57, 3998-4003 (2003).
108. 2: Kinetic Investigations and Catalyst Deactivation," Appl. Catal., B, 42, 77-87 (2003).
109. 2," Environ. Sci. Technol., 37, 3448-53 (2003).
110. S. P. Decker, J. S. Klabunde, A. Khaleel, and, K. J. Klabunde, " Catalyzed Destructive Adsorption of Environmental Toxins with Nanocrystalline Metal Oxides. Fluoro-, Chloro-, Bromocarbons, Sulfur, and Organophosophorus Compounds," Environ. Sci. Technol., 36, 762-8 (2002).
111. G. M. Medine, V. Zaikovskii, and, K. J. Klabunde, " Synthesis and Adsorption Properties of Intimately Intermingled Mixed Metal Oxide Nanoparticles," J. Mater. Chem., 14, 757-63 (2004).
112. P. K. Stoimenov, R. L. Klinger, G. L. Marchin, and, K. J. Klabunde, " Metal Oxide Nanoparticles as Bactericidal Agents," Langmuir, 18, 6679-86 (2002).
113. L. Huang, D. Li, Y. Lin, M. Wei, D. G. Evans, and, X. Duan, " Controllable Preparation of Nano-MgO and Investigation of its Bactericidal Properties," J. Inorg. Biochem., 99, 986-93 (2005).
114. 2 Photocatalytic Membranes with a Hierarchical Mesoporous Multilayer Structure: Synthesis, Characterization, and Multifunction," Adv. Funct. Mater., 16, 1067-74 (2006).
115. W. K. Son, J. H. Youk, T. S. Lee, and, W. H. Park, " Preparation of Antimicrobial Ultrafine Cellulose Acetate Fibers with Silver Nanoparticles," Macromol. Rapid Commun., 25, 1632-7 (2004).
116. A. Melaiye, Z. Sun, K. Hindi, A. Milsted, D. Ely, D. H. Reneker, C. A. Tessier, and, W. J. Youngs, " Silver(I)-Imidazole Cyclophane Gem-Diol Complexes Encapsulated by Electrospun Tecophilic Nanofibers: Formation of Nanosilver Particles and Antimicrobial Activity," J. Am. Chem. Soc., 127, 2285-91 (2005).
117. M. Atteya, and, K. J. Klabunde, " Nanoscale Metal Oxide Particles as Chemical Reagents. Heats of Adsorption of Heteroatom-Containing Organics on Heat -Treated Magnesium Oxide Samples of Varying Surface Areas," Chem. Mater., 3 [1] 182-7 (1991).
118. E. Knözinger, O. Diwald, and, M. Sterrer, " Chemical Vapour Deposition-A New Approach to Reactive Surface Defects of Uniform Geometry on High Surface Area Magnesium Oxide," J. Mol. Catal. A: Chem., 162 [1-2] 83-95 (2000).
119. B.-Q. Xu, J.-M. Wei, H.-Y. Wang, K.-Q. Sun, and, Q.-M. Zhu, " Nano-MgO: Novel Preparation and Application as Support of Ni Catalyst for CO2 Reforming of Methane," Catal. Today, 68 [1-3] 217-25 (2001).
120. C. Henrist, J.-P. Mathieu, C. Vogels, A. Rulmont, and, R. Cloots, " Morphological Study of Magnesium Hydroxide Nanoparticles Precipitated in Dilute Aqueous Solution," J. Cryst. Growth, 249 [1-2] 321-30 (2003).
121. M. S. El-Shall, W. Slack, W. Vann, D. Kane, and, D. Hanley, " Synthesis of Nanoscale Metal Oxide Particles Using Laser Vaporization/ Condensation in a Diffusion Cloud Chamber," J. Phys. Chem., 98 [12] 3067-70 (1994).
122. A. V. Vorontsov, A. A. Panchenko, E. N. Savinov, C. Lion, and, P. G. Smirniotis, " Photocatalytic Degradation of 2-Phenethyl-2-chloroethyl Sulfide in Liquid and Gas Phases," Environ. Sci. Technol., 36 [23] 5261-9 (2002).
123. A. V. Vorontsov, L. Davydov, E. P. Reddy, C. Lion, E. N. Savinov, and, P. G. Smirniotis, " Routes of Photocatalytic Destruction of Chemical Warfare Agent Simulants," New J. Chem., 26, 732-44 (2002).
124. I. E. Wachs, " Molecular Engineering of Supported Metal Oxide Catalysts," Chem. Eng. Sci., 45 [8] 2561-5 (1990).
125. K. S. W. Sing, D. H. Everett, R. A. W. Haul, L. Moscou, R. A. Pierotti, J. Rouquérol, and, T. Siemieniewska, " Reporting Physisorption Data for Gas/Solid Systems with Special Reference to the Determination of Surface Area and Porosity," Pure Appl. Chem., 57 [4] 603-19 (1985).
126. A.-H. Lu, and, F. Schüth, " Nanocasting Pathways to Create Ordered Mesoporous Solids," C. R. Chim., 8 [3-4] 609-20 (2005).
127. A. Michalkova, M. Ilchenko, L. Gorb, and, J. Leszczynski, " Theoretical Study of the Adsorption and Decomposition of Sarin on Magnesium Oxide," J. Phys. Chem. B, 108, 5294-303 (2004).
128. T. M. Tesfai, V. N. Sheinker, and, M. B. Mitchell, " Decomposition of Dimethyl Methylphosphonate (DMMP) on Alumina-Supported Iron Oxide," J. Phys. Chem. B, 102 [38] 7299-302 (1998).
129. M. K. Templeton, and, W. H. Weinberg, " Adsorption and Decomposition of Dimethyl Methylphosphonate on an Aluminum Oxide Surface," J. Am. Chem. Soc., 107 [1] 97-108 (1985).
130. L. Cao, S. R. Segal, S. L. Suib, X. Tang, and, S. Satyapal, " Thermocatalytic Oxidation of Dimethyl Methylphosphonate on Supported Metal Oxides," J. Catal., 194, 60-70 (2000).
131. Y. Fangli, H. Peng, Y. Chunlei, H. Shulan, and, L. Jinlin, " Preparation and Properties of Zinc Oxide Nanoparticles Coated with Zinc Aluminate," J. Mater. Chem., 13, 634-7 (2003).
132. H. Y. Zhu, J.-C. Zhao, J. W. Liu, X. Z. Yang, and, Y. N. Shen, " General Synthesis of a Mesoporous Composite of Metal Oxide and Silicate Nanoparticles from a Metal Salt and Laponite Suspension for Catalysis," Chem. Mater., 18 [17] 3993-4001 (2006).
133. R. Richards, W. Li, S. Decker, C. Davidson, O. Koper, V. Zaikovski, A. Volodin, T. Rieker, and, K. J. Klabunde, " Consolidation of Metal Oxide Nanocrystals. Reactive Pellets with Controllable Pore Structure That Represent a New Family of Porous, Inorganic Materials," J. Am. Chem. Soc., 122 [20] 4921-5 (2000).
134. 3," J. Mater. Sci.: Mater. Med., 16, 53-6 (2005).
135. S. Makhluf, R. Dror, Y. Nitzan, Y. Abramovich, R. Jelinek, and, A. Gedanken, " Microwave-Assisted Synthesis of Nanocrystalline MgO and Its Use as a Bacteriocide," Adv. Funct. Mater., 15, 1708-15 (2005).
136. M. J. Wilson, " Clay Mineralogy and Related Characteristics of Geophagic Materials," J. Chem. Ecol., 29 [7] 1525-47 (2003).
137. S. Ramakrishna, K. Fujihara, W.-E. Teo, T.-C. Lim, and, Z. Ma, An Introduction to Electrospinning and Nanofibers. World Scientific Publisher, Singapore, 2005.
138. S. Sundarrajan, and, S. Ramakrishna, " Fabrication of Nanocomposite Membranes from Nanofibers and Nanoparticles for Protection Against Chemical Warfare Simulants," J. Mater. Sci., 42 [20] 8400-7 (2007).
139. S. Sundarrajan, D. Pliszka, S. Ramakrishna, A. Jaworek, A. Krupa, and, M. Lackowski, " A Novel Process for the Fabrication of Nanocomposites Membranes," J. Nanosci. Nanotechnol., 9 [7] 4442-7 (2009).
140. M. Roso, S. Sundarrajan, D. Pliszka, S. Ramakrishna, and, M. Modesti, " Multifunctional Membranes Based on Spinning Technologies: The Synergy of Nanofibers and Nanoparticles," Nanotechnology, 19, 285707, 6pp (2008).
141. N. L. Lala, R. Ramaseshan, L. Bojun, S. Sundarrajan, R. S. Barhate, L. Ying-Jun, and, S. Ramakrishna, " Fabrication of Nanofibers with Antimicrobial Functionality Used as Filters: Protection Against Bacterial Contaminants," Biotechnol. Bioeng., 97, 1357-65 (2007).
142. W-E. Teo, and, S. Ramakrishna, " Electrospun Nanofibers as a Platform for Multifunctional, Hierarchically Organized Nanocomposite," Compos. Sci. Technol., 69, 1804-17 (2009).
143. R. Ramaseshan, S. Sundarrajan, Y. Liu, R. Barhate, N. Lala, and, S. Ramakrishna, " Functionalized Polymer Nanofibre Membranes for Protection from Chemical Warfare Simulants," Nanotechnology, 17, 2947-53 (2006).
144. L. Campanella, C. Colapicchioni, G. Favero, M. Sammartino, and, M. Tomassetti, " Organophosphorus Pesticide (Paraoxon) Analysis Using Solid State Sensors," Sens. Actuators B, 33, 25-33 (1996).
145. J. Sojka-Ledakowicz, J. Lewartowska, M. Kudzin, M. Leonowicz, T. Jesionowski, K. Siwinska-Stefanska, and, A. Krysztafkiewicz, " Functionalization of Textile Materials by Alkoxysilane-Grafted Titanium Dioxide," J. Mater. Sci., 44 [14] 3852-60 (2009).
146. J. Sojka-Ledakowicz, J. Lewartowska, M. Kudzin, T. Jesionowski, K. Siwinska-Stefanska, and, A. Krysztafkiewicz, " Modification of Textile Materials with Micro- and Nano-Structural Metal Oxides," Fibres Text. Eastern Eur., 16 [5] 112-6 (2008).
147. K. Parthasarathi, and, S. P. Borkar, " Antibacterial and UV Protection Finishes of Textiles by Metal and Metal Oxide Nano Particles-A Review," Colourage, 54 [7] 43-6 (2007).
148. H. J. Lee, S. Y. Yeo, and, S. H. Jeong, " Antibacterial Effect of Nanosized Silver Colloidal Solution on Textile Fabrics," J. Mater. Sci., 38, 2199-204 (2003).
149. D. Karst, and, Y. Yang, " Potential Advantages and Risks of Nanotechnology for Textiles," AATCC Rev., 6 [3] 44-8 (2006).
150. S. González, M. Fernández-Lorente, and, Y. Gilaberte-Calzada, " The Latest on Skin Photoprotection," Clin. Dermatol., 26, 614-26 (2008).
151. A. Jaworek, A. Krupa, M. Lackowski, A. T. Sobczyk, T. Czech, S. Ramakrishna, S. Sundarrajan, and, D. Pliszka, " Nanocomposite Fabric Formation by Electrospinning and Electrospraying Technologies," J. Electrostat., 67, 435-8 (2009).
152. 2 Nano-Antibacterial Agent by UV Radiation," J. Photochem. Photobiol., A, 188 [1] 98-105 (2007).
153. J. O. Won, Y. S. Kang, B. S. Jung, and, Y. S. Yoon, " Composite Polymers Containing Nanometer-Sized Metal Particles and Manufacturing Method " U.S. Patent 6712997, 2004.
154. M. Epifani, R. Díaz, J. Arbiol, E. Comini, N. Sergent, T. Pagnier, P. Siciliano, G. Faglia, and, J. R. Morante, " Nanocrystalline Metal Oxides from the Injection of Metal Oxide Sols in Coordinating Solutions: Synthesis, Characterization, Thermal Stabilization, Device Processing, and Gas-Sensing Properties," Adv. Funct. Mater., 16, 1488-9 (2006).
155. H. H. Kuhn, " Adsorption at the Liquid/Solid Interface: Metal Oxide Coated Textiles" pp. 281-9 in Book of Papers-International Conference & Exhibition. AATCC, 1998.
156. J. B. Davis, D. B. Marshall, K. S. Oka, R. M. Housley, and, P. E. D. Morgan, " Ceramic Composites for Thermal Protection Systems," Compos., Part A: Appl. Sci. Manufac., 30A [4] 483-8 (1999).
157. T. Yuranova, A. G. Rincon, A. Bozzi, S. Parra, C. Pulgarin, P. Albers, and, J. Kiwi, " Antibacterial Textiles Prepared by RF-Plasma and Vacuum-UV Mediated Deposition of Silver," J. Photochem. Photobiol., A, 161 [1] 27-34 (2003).
158. K. Fujiwara, " Separation Functional Fibers by Radiation Induced Graft Polymerization and Application," Nucl. Instrum. Methods Phys. Res., Sect. B, 265 [1] 150-5 (2007).
159. E. Schollmeyer, T. Textor, and, T. Bahners, " Organically Modified Ceramics for Coating Textile Materials. Magic World of Textiles " pp. 318-22 Book of Proceedings of the International Textile, Clothing & Design Conference, 1st, Dubrovnik, Croatia, October 6-9, 2002.
160. R. Zimehl, T. Textor, T. Bahners, and, E. Schollmeyer, " Smart Textiles-When Colloid Chemistry Bears a Challenge," Progr. Colloid Polym. Sci., 125, 49-53 (2004).
161. B. Mahltig, E. Gutmann, D. C. Meyer, M. Reibold, B. Dresler, K. Günther, D. Faßler, and, H. Böttcher, " Solvothermal Preparation of Metallized Titania Sols for Photocatalytic and Antimicrobial Coatings," J. Mater. Chem., 17, 2367-74 (2007).
162. G. W. Wagner, Q. Chen, and, Y. Wu, " Reactions of VX, GD, and HD with Nanotubular Titania," J. Phys. Chem. C, 112 [31] 11901-6 (2008).
163. 2 Nanocomposite on the Properties of Bioactive Continuous Filament Yarns," Fibers Polym., 9 [6] 727-34 (2008).
164. R. Dastjerdi, M. R. M. Mojtahedi, and, A. M. Shoshtari, " Comparing the Effect of Three Processing Methods for Modification of Filament Yarns with Inorganic Nanocomposite Filler and their Bioactivity Against Staphylococcus aureus," Macromol. Res., 17 [6] 378-87 (2009).
165. R. Dastjerdi, M. R. M. Mojtahedi, A. M. Shoshtari, A. Khosroshahi, and, A. J. Moayed, " Fiber to Fabric Processability of Silver/Zinc Loaded Nanocomposite Yarns," Text. Res. J., 79 [12] 1099-107 (2009).
166. R. Dastjerdi, M. R. M. Mojtahedi, and, A. M. Shoshtari, " Processing, Properties of Nanocomposite Filament Yarns with Various Filler Concentrations from Two Different Modification Methods," Macromol. Symp., 274 [1] 154-65 (2008).
167. 2 under UV Light and Different Polycarboxylic Acid," J. Hwa Gang Text., 10, 104-1 (2003).
168. C. C. Wang, and, C. C. Chen, " Physical Properties of Crosslinked Cellulose Catalyzed with Nano Titanium Dioxide," J. Appl. Pol. Sci., 97, 2450-6 (2005).
169. L. Suna, J. A. Rippona, P. G. Cookson, O. Koulaeva, and, X. Wang, " Effects of Undoped and Manganese-Doped Zinc Oxide Nanoparticles on the Colour Fading of Dyed Polyester Fabrics," Chem. Eng. J., 147, 391-8 (2009).
170. J. Kiwi, and, C. Pulgarin, " Innovative Self-Cleaning and Bactericide Textiles," Catal. Today, 151, 2-7 (2010).
171. O. V. Abramov, A. Gedanken, Y. Koltypin, N. Perkas, I. Perelshtein, E. Joyce, and, T. J. Mason, " Pilot Scale Sonochemical Coating of Nanoparticles Onto Textiles to Produce Biocidal Fabrics," Surf. Coat. Technol., 204, 718-22 (2009).
172. O. B. Koper, and, S. Rajagopalan, " Nanoactive Metal Oxides: Unique Materials with Unlimited Potential " pp. 419-22 in NSTI Nanotech 2006, Misc: Edited by, M. Laudon, and, B. Romanowicz,. NSTI Nanotechnology Conference and Trade Show, Boston, MA, 2006.
173. K. Schaefer, H. Thomas, P. Dalton, and, M. Moeller, " Nano-Fibres for Filter Materials " pp. 125-38 in Multifunctional Barriers for Flexible Structure. Series in Materials Science, Vol. 97, Edited by S. Duquesne, C. Magniez, and G. Camino. Springer, Berlin, 2007.
174. D. Li, J. T. McCann, and, Y. Xia, " Electrospinning: A Simple and Versatile Technique for Producing Ceramic Nanofibers and Nanotubes," J. Am. Ceram. Soc., 89 [6] 1861-9 (2006).
175. H. Park, " Fabrication of Lanthum Copper Oxide Nanofibers by Electrospinning " Ph.D. Thesis, University of Florida, Gainesville, FL, 2005.
176. 3 Electrode Morphology on the Nitric Oxide Response of a Stabilized Zirconia Sensor," Sens. Actuators, B, 96, 53-60 (2003).
177. N. F. Szabo, and, P. K. Dutta, " Strategies for Total NOx Measurement with Minimal CO Interference Utilizing a Microporous Zeolitic Catalytic Filter," Sens. Actuators, B, 88, 168-77 (2003).
178. E. Traversa, A. Bearzotti, M. Miyayama, and, H. Yanagida, " Influence of the Electrode Materials on the Electrical Response of ZnO-Based Contact Sensors," J. Eur. Ceram. Soc., 18, 621-3 (1998).
179. E. Traversa, A. Bearzotti, M. Miyayama, and, H. Yanagida, " Study of the Conduction Mechanism of La2CuO4-Zno Heterocontacts at Different Relative Humidities," Sens. Actuators, B, 25, 714-8 (1995).
180. 2 Gas Sensors," Sens. Actuators, B, 77, 443-6 (2001).
181. N. Yamazoe, " Toward Innovations of Gas Sensor Technology," Sens. Actuators, B, 108, 2-14 (2005).
182. 2 Using tin Oxide Nanowire Sensors," Adv. Mater., 15, 997-1000 (2003).
183. B. Ding, M. Wang, J. Yu, and, G. Sun, " Gas Sensors Based on Electrospun Nanofibers," Sensors, 9, 1609-24 (2009).
184. C. Balazsi, L. Wang, E. O. Zayimc, I. M. Szilagyi, K. Sedlackova, J. Pfeifer, A. L. Toth, and, P. I. Gouma, " Nanosize Hexagonal Tungsten Oxide for Gas Sensing Applications," J. Eur. Ceram. Soc., 28, 913-7 (2008).
185. 3 Nanofibers and their Application for Ammonia Sensing," J. Phys. Chem. B, 110, 23777-82 (2006).
186. P. I. Gouma, P. K. Dutta, and, M. J. Mills, " Structural Stability of Titania Thin Films," NanostructurMater., 11 [8] 1231-7 (1999).
187. 2 Nanoparticles," Sens. Actuators, B, 119, 683-90 (2006). (Pubitemid 44403044)
188. 3 Thin Film Gas Sensors for Selective Ammonia Detection," Sens. Actuators, B, 93, 25-30 (2003).
189. R. Ramakrishnan, and, S. Ramakrishna, " Zinc Titanate Nanofibers for the Detoxification of Chemical Warfare Simulants," J. Am. Ceram. Soc., 90 [6] 1836-42 (2007).
190. G. Hota, S. Sundarrajan, S. Ramakrishna, and, WJ Ng, " One Step Fabrication of MgO Solid and Hollow Submicron fibers via Electrospinning Method," J. Am. Ceram. Soc., 92, 2429-33 (2009).
191. V. Richards, and, B. D. Fahlman, " Chemical Vapor Deposition of Metal Oxide Thin Films: Design of Actively Protective Clothing Against Chemical Warfare Agents. Abstracts of Papers " 227th ACS National Meeting, Anaheim, CA, USA, March 28-April 1, 2004.
192. R. Ramakrishnan, S. Sundarrajan, L. Yingjun, R. S. Barhate, N. L. Lala, and, S. Ramakrishna, " Functionalized Polymer Nanofiber Membranes for Protection from Chemical Warfare Agents," Nanotechnology, 17, 2947-53 (2006).
193. S. Sundarrajan, A. Venkatesan, and, S. Ramakrishna, " Fabrication of Nanostructured Self-Detoxifying Nanofiber Membranes Containing Active Polymeric Functional Groups," Macromol. Rapid Commun., 30 [20] 1769-74 (2009).
194. M. Geppert, M. Hohnholt, I. Grunwald, M. Baeumer, and, R. Dringen, " Accumulation of Iron Oxide Nanoparticles in Cultured Brain Astrocytes " Proceedings of the 6th International Conference on Biomedical Applications of Nanotechnology, March 4-6, Berlin Germany, p. 24, 2009.
195. L. E. Murr, " Nanoparticulate Materials in Antiquity: The Good, the Bad and the Ugly," Mater. Charact., 60, 261-70 (2009).
196. T. L. Dawson, " Nanomaterials for Textile Processing and Photonic Applications," Color. Technol., 124, 261-72 (2008).