Role of the azadithiolate cofactor in models for [FeFe]-hydrogenase: Novel structures and catalytic implications

Journal of the American Chemical Society

Volumn 132, Issue 50, 2010, Pages 17733-17740

  Olsen, Matthew T ^a   Rauchfuss, Thomas B ^a   Wilson, Scott R ^a  

^a UNIVERSITY OF ILLINOIS AT URBANA CHAMPAIGN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

[FEFE]HYDROGENASES; ACID-BASE PROPERTY; ATOM TRANSFER; BENZYL DERIVATIVES; CARBONYL COMPLEXES; COFACTORS; DICATIONS; DISPROPORTIONATIONS; HIGH ACTIVITY; HYDROGENASES; MIXED VALENCE; MODEL COMPLEXES; NOVEL STRUCTURES; PROTON COUPLED ELECTRON TRANSFERS; REDOX BEHAVIOR; SYNTHETIC MODELS;

AMMONIUM COMPOUNDS; ETHYLENE;

ORGANIC COMPOUNDS;

AMMONIA; AZADITHIOLATE COFACTOR; BENZYL DERIVATIVE; IRON HYDROGENASE; THIOL DERIVATIVE; UNCLASSIFIED DRUG;

ACID BASE BALANCE; ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; COMPLEX FORMATION; CRYSTAL STRUCTURE; CRYSTALLOGRAPHY; ELECTROCHEMISTRY; ENZYME ACTIVITY; ENZYME STRUCTURE; HYDROGENATION; OXIDATION REDUCTION REACTION; PROTON TRANSPORT; SYNTHESIS;

AZA COMPOUNDS; CATALYSIS; CATALYTIC DOMAIN; COENZYMES; HYDROGENASE; IRON-SULFUR PROTEINS; MODELS, MOLECULAR; MOLECULAR STRUCTURE; OXIDATION-REDUCTION; STEREOISOMERISM; THERMODYNAMICS;

EID: 78650285721     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja103998v     Document Type: Article

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