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Volumn 9, Issue 1, 2011, Pages 101-104

A combined mechanistic and computational study of the gold(I)-catalyzed formation of substituted indenes

Author keywords

[No Author keywords available]

Indexed keywords

COMPUTATIONAL STUDIES; HYDROARYLATION; IN-SITU;

EID: 78650158120     PISSN: 14770520     EISSN: None     Source Type: Journal    
DOI: 10.1039/c0ob00758g     Document Type: Article
Times cited : (48)

References (35)
  • 2
    • 51249100498 scopus 로고    scopus 로고
    • A. Arcadi Chem. Rev. 2008 108 3266 3325
    • (2008) Chem. Rev. , vol.108 , pp. 3266-3325
    • Arcadi, A.1
  • 23
    • 0032486218 scopus 로고    scopus 로고
    • The amount of acid used (3 mol%) was selected for ease of manipulation. Background reactions conducted with acid only did not lead to product formation and permitted recovery of starting material
    • J. H. Teles S. Brode M. Chabanas Angew. Chem., Int. Ed. 1998 37 1415 1418
    • (1998) Angew. Chem., Int. Ed. , vol.37 , pp. 1415-1418
    • Teles, J.H.1    Brode, S.2    Chabanas, M.3
  • 24
    • 34249006882 scopus 로고    scopus 로고
    • The BP86 DFT calculations were performed with the Gaussian03 package using a SVP basis set on main group atoms, and the SDD-ECP basis set on Ru. Solvent effects, dichloroethane, were included with the PCM approach. Further details in the Supporting Information The reaction below conducted under identical catalytic conditions but with the use of a Au-Cl precursor activated by a silver salt yields comparable results (thermodynamic indene) but with apparent slower kinetics as under optimised conditions this transformation mediated by [(IPr)AuOH] and acid reaches completion after 4 h
    • N. Marion S. P. Nolan Angew. Chem., Int. Ed. 2007 46 2750 2752
    • (2007) Angew. Chem., Int. Ed. , vol.46 , pp. 2750-2752
    • Marion, N.1    Nolan, S.P.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.