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The amount of acid used (3 mol%) was selected for ease of manipulation. Background reactions conducted with acid only did not lead to product formation and permitted recovery of starting material
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The BP86 DFT calculations were performed with the Gaussian03 package using a SVP basis set on main group atoms, and the SDD-ECP basis set on Ru. Solvent effects, dichloroethane, were included with the PCM approach. Further details in the Supporting Information The reaction below conducted under identical catalytic conditions but with the use of a Au-Cl precursor activated by a silver salt yields comparable results (thermodynamic indene) but with apparent slower kinetics as under optimised conditions this transformation mediated by [(IPr)AuOH] and acid reaches completion after 4 h
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