Electron predators are hydrogen atom traps. Effects of aryl groups on N-Cα bond dissociations of peptide radicals

Journal of Mass Spectrometry

Volumn 45, Issue 11, 2010, Pages 1280-1290

  Tureček, František ^a  

^a UNIVERSITY OF WASHINGTON   (United States)

Author keywords

ab initio; calculations; dissociation mechanisms; electron transfer; peptide dissociations; peptide radicals

Indexed keywords

AB INITIO; AMIDE GROUPS; ARYL GROUP; ATOM MIGRATION; BENZYL GROUP; BOND DISSOCIATION; COMPUTATIONAL RESULTS; CYSTEINE RESIDUES; DISSOCIATION MECHANISMS; ELECTRON TRANSFER; ELECTRONWITHDRAWING; FLUORINE SUBSTITUENTS; H-ATOM TRANSFER; HYDROGEN ATOM TRAP; HYDROGEN ATOMS; KINETIC ANALYSIS; NITRO GROUP; PEPTIDE BACKBONES; PHENYL RINGS; QUENCHING EFFECT; REACTION CHANNELS; TETRAPEPTIDE;

AMIDES; AMINO ACIDS; DISSOCIATION; ELECTRON TRANSITIONS; FLUORINE; FREE RADICAL REACTIONS; HYDROGEN; ORGANIC POLYMERS; PEPTIDES; QUANTUM CHEMISTRY; TWO DIMENSIONAL;

ATOMS;

AMIDE; CYSTEINE; FLUORINE; HYDROGEN; HYDROXYL GROUP; PEPTIDE; TETRAPEPTIDE;

ARTICLE; ATOM TRANSFER RADICAL POLYMERIZATION; CHEMICAL REACTION; ELECTRIC POTENTIAL; ELECTRON; KINETICS; PRIORITY JOURNAL;

BENZYL COMPOUNDS; CARBON; CATALYSIS; ELECTRONS; HYDROGEN; KINETICS; MASS SPECTROMETRY; MOLECULAR CONFORMATION; NITROGEN; PEPTIDES; THERMODYNAMICS;

EID: 78649610720     PISSN: 10765174     EISSN: 10969888     Source Type: Journal    
DOI: 10.1002/jms.1807     Document Type: Article

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