Mono and dinuclear rhodium, iridium and ruthenium complexes containing chelating 2,2′-bipyrimidine ligands: Synthesis, molecular structure, electrochemistry and catalytic properties

Journal of Organometallic Chemistry

Volumn 692, Issue 17, 2007, Pages 3664-3675

  Govindaswamy, Padavattan ^a   Canivet, Jérôme ^a   Therrien, Bruno ^a   Süss Fink, Georg ^a   Štěpnička, Petr ^b   Ludvík, Jiří ^c  

^a UNIVERSITY OF NEUCHÂTEL   (Switzerland)

^b CHARLES UNIVERSITY   (Czech Republic)

^c J HEYROVSKÝ INSTITUTE OF PHYSICAL CHEMISTRY   (Czech Republic)

Author keywords

Arene ligands; Dinuclear complexes; Electrochemistry; N ligands; Transfer hydrogenation

Indexed keywords

ARENE LIGANDS; DINUCLEAR COMPLEXES; N LIGANDS; TRANSFER HYDROGENATION;

CATALYSIS; COMPLEXATION; ELECTROCHEMISTRY; HYDROGENATION; LIGANDS; MOLECULAR STRUCTURE; SYNTHESIS (CHEMICAL);

METAL COMPLEXES;

EID: 34447255412     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2007.04.048     Document Type: Article

References (41)

1. Herrmann W.A., and Kohlpaintner C.W. Angew. Chem., Int. Ed. 32 (1993) 1524-1544
2. Xiao J., Wu X., Zanotti-Gerosa A., and Hancock F. Chim. Oggi 23 (2005) 50-55
3. Ogo S., Makihara N., and Watanabe Y. Organometallics 18 (1999) 5470-5474
4. Ogo S., Abura T., and Watanabe Y. Organometallics 21 (2002) 2964-2969
5. Himeda Y., Onozawa-Komatsuzaki N., Sugihara H., Arakawa H., and Kasuga K. J. Mol. Catal. A-Chem. 195 (2003) 95-100
6. Canivet J., Karmazin-Brelot L., and Süss-Fink G. J. Organomet. Chem. 690 (2005) 3202-3211
7. Abura T., Ogo S., Watanabe Y., and Fukuzumi S. J. Am. Chem. Soc. 125 (2003) 4149-4154
8. Ogo S., Uehara K., Abura T., Watanabe Y., and Fukuzumi S. Organometallics 23 (2004) 3047-3052
9. Singh A., Singh N., and Pandey D.S. J. Organomet. Chem. 642 (2002) 48-57
10. Lalrempuia R., and Kollipara M.R. Polyhedron 22 (2003) 3155-3160
11. Baumann F., Stange A., and Kaim W. Inorg. Chem. Commun. 1 (1998) 305-308
12. Brunner H., Köllnberger A., Burgemeister T., and Zabel M. Polyhedron 19 (2000) 1519-1526
13. Aneetha H., Zacharias P.S., Srinivas B., Lee G.H., and Wang Y. Polyhedron 18 (1999) 299-307
14. Fernholt L., Romming C., and Samdal S. Acta Chem. Scand. A 35 (1981) 707-715
15. Berg D.J., Boncella J.M., and Andersen R.A. Organometallics 21 (2002) 4622-4631
16. Bennett M.A., and Smith A.K. J. Chem. Soc., Dalton Trans. (1974) 233-241
17. Volland M.A.O., Hansen S.M., Rominger F., and Hofmann P. Organometallics 23 (2004) 800-816
18. Govindaswamy P., Süss-Fink G., and Therrien B. Organometallics 26 (2007) 915-924
19. 1/2 the half-wave potential in voltammetry at Pt-RDE, ν the scan rate, and ω the rotation frequency of the disc electrode.
20. Ladwig M., and Kaim W. J. Organomet. Chem. 419 (1991) 233-243
21. Ladwig M., and Kaim W. J. Organomet. Chem. 439 (1992) 79-90
22. Kaim W., Reinhardt R., and Sieger M. Inorg. Chem. 33 (1994) 4453-4459
23. + from [(arene)M(bpym)] upon back-oxidation.
24. Kaim W., Reinhardt R., Greulich S., Sieger M., Klein A., and Fiedler J. Collect. Czech. Chem. Commun. 66 (2001) 291-306
25. 7 after 12 h at room temperature and even after 1 h at 50 °C.
26. Reduction of 5 at these potentials is also accompanied with follow-up processes that give rise to minor anodic waves at -0.66 and ca. -0.80 V.
27. Ogo S., Makihara N., Kaneko Y., and Watanabe Y. Organometallics 20 (2001) 4903-4910
28. Štěpnička P., Ludvík J., Canivet J., and Süss-Fink G. Inorg. Chim. Acta 359 (2006) 2369-2374
29. Gabrielsson A., van Leeuwen P., and Kaim W. Chem. Commun. (2006) 4926-4927
30. Kang J.W., Moseley K., and Maitlis P.M. J. Am. Chem. Soc. 91 (1969) 5970-5977
31. Ball R.G., Graham W.A.G., Heinekey D.M., Hoyano J.K., McMaster A.D., Mattson B.M., and Michel S.T. Inorg. Chem. 29 (1990) 2023-2025
32. White C., Yates A., and Maitlis P.M. Inorg. Synth. 29 (1992) 228-234
33. Zelonka R.A., and Baird M.C. Can. J. Chem. 50 (1972) 3063-3072
34. Bennett M.A., and Smith A.K. J. Chem. Soc., Dalton Trans. (1974) 233-240
35. Bennett M.A., Huang T.-N., Matheson T.W., and Smith A.K. Inorg. Synth. 21 (1982) 74-76
36. Sheldrick G.M. Acta Crystall. A46 (1990) 467-473
37. Sheldrick G.M. shelxl-97 (1999), University of Göttingen, Göttingen, Germany
38. Spek A.L. J. Appl. Cryst. 36 (2003) 7-13
39. van der Sluis P., and Spek A.L. Acta Crystall., A 46 (1990) 194-201
40. Farrugia L.J. J. Appl. Cryst. 30 (1997) 565
41. Bruno I.J., Cole J.C., Edgington P.R., Kessler M., Macrae C.F., McCabe P., Pearson J., and Taylor R. Acta Crystall. B58 (2002) 389-397