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At this point it is worth noting that Eq. (4) supports different types of ensemble-averaging methods regarding the orientation of the dipole transition moment, where the particular character of the emissive species is accounted in the detailed calculation of Γrel (q, z, ) [16]. In this contribution, we assume the orientation of the dipole transition moment to be fixed during the process of emission. However, applying different ensemble-averaging methods typically results in small quantitative differences only, which have no qualitative impact on the considerations we present.
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