Bulk and surface structure and high-temperature thermoelectric properties of inverse clathrate-III in the Si-P-Te system

Chemistry - A European Journal

Volumn 16, Issue 42, 2010, Pages 12582-12589

  Zaikina, Julia V ^a,b,f   Mori, Takao ^c   Kovnir, Kirill ^b,f   Teschner, Detre ^d   Senyshyn, Anatoliy ^e   Schwarz, Ulrich ^b   Grin, Yuri ^b   Shevelkov, Andrei V ^a  

^a MOSCOW STATE UNIVERSITY   (Russian Federation)

^b MAX PLANCK INSTITUTE FOR CHEMICAL PHYSICS OF SOLIDS   (Germany)

^c NATIONAL INSTITUTE FOR MATERIALS SCIENCE   (Japan)

^d FRITZ HABER INSTITUT DER MAX PLANCK GESELLSCHAFT   (Germany)

^e TECHNICAL UNIVERSITY OF MUNICH   (Germany)

^f FLORIDA STATE UNIVERSITY   (United States)

Author keywords

clathrates; neutron diffraction; thermal stability; thermoelectric materials; Zintl phases

Indexed keywords

AS-CAST; BEST VALUE; CLATHRATES; DIRECT SOLAR; FIGURE OF MERIT; HIGH TEMPERATURE; HIGH THERMAL; METAL-OXIDE; NANO-SIZED; NEW HIGH; PHOSPHORUS ATOM; PHOSPHORUS-DOPED; SURFACE LAYERS; TEMPERATURE RANGE; THERMAL STABILITY; THERMOELECTRIC EFFICIENCY; THERMOELECTRIC MATERIAL; THERMOELECTRIC PROPERTIES; WASTE-HEAT RECOVERY; ZINTL PHASIS;

CHEMICAL STABILITY; ENERGY CONVERSION; HYDRATES; MATERIALS; NEUTRON DIFFRACTION; OPTIMIZATION; PHOSPHORUS; SILICA; SILICON; SOLAR ENERGY; SURFACE STRUCTURE; TELLURIUM; TELLURIUM COMPOUNDS; THERMODYNAMIC STABILITY; THERMOELECTRIC EQUIPMENT; THERMOELECTRICITY; TRANSITION METALS; WASTE HEAT; WASTE HEAT UTILIZATION;

THERMOELECTRIC ENERGY CONVERSION;

EID: 78249244134     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201001990     Document Type: Article

References (61)

1. G. S. Nolas, J. Sharp, H. J. Goldsmid, in Thermoelectrics: Basic Principles and New Materials Developments, Springer, New York, 2001.
2. J. R. Sootsman, D. Y. Chung, M. G. Kanatzidis, Angew. Chem. 2009, 121, 8768 - 8792
3. Angew. Chem. Int. Ed. 2009, 48, 8616 - 8639.
4. G. J. Snyder, E. S. Toberer, Nat. Mater. 2008, 7, 105 - 114.
5. A. V. Shevelkov, Uspekhi Khimii 2008, 77, 3 - 21
6. A. V. Shevelkov, Russ. Chem. Rev. 2008, 77, 1 - 19.
7. T. M. Tritt, H. Bottner, L. Chen, MRS Bull. 2008, 33, 366 - 368.
8. G. A. Slack, in CRC Handbook of Thermoelectrics (Ed.:, D. M. Rowe,), CRC Press, New York, 1995.
9. M. S. Dresselhaus, G. Chen, M. Y. Tang, R. G. Yang, H. Lee, D. Z. Wang, Z. F. Ren, J.-P. Fleurial, P. Gogna, Adv. Mater. 2007, 19, 1043 - 1053
10. K. Ahn, M. K. Han, J. He, J. Androulakis, S. Ballikaya, C. Uher, V. P. Dravid, M. G. Kanatzidis, J. Am. Chem. Soc. 2010, 132, 5227 - 5235.
11. B. C. Sales, D. Mandrus, R. K. Williams, Science 1996, 272, 1325 - 1328
12. G. S. Nolas, M. Kaeser, R. T Littleton IV, T. M. Tritt, Appl. Phys. Lett. 2000, 77, 1855 - 1857.
13. E. S. Toberer, A. F. May, G. J. Snyder, Chem. Mater. 2010, 22, 624 - 634
14. M. Beekman, G. S. Nolas, J. Mater. Chem. 2008, 18, 842 - 851
15. M. Christensen, S. Johnsen, B. B. Iversen, Dalton Trans. 2010, 39, 978 - 992.
16. J. Nylén, S. Lidin, M. Andersson, B. B. Iversen, H. Liu, N. Newman, U. Häussermann, Chem. Mater. 2007, 19, 834 - 838
17. G. J. Snyder, M. Christensen, E. Nishibori, T. Caillat, B. B. Iversen, Nat. Mater. 2004, 3, 458 - 463.
18. E. S. Toberer, C. A. Cox, S. R. Brown, T. Ikeda, A. F. May, S. M. Kauzlarich, G. J. Snyder, Adv. Funct. Mater. 2008, 18, 2795 - 2800
19. S. R. Brown, S. M. Kauzlarich, F. Gascoin, G. J. Snyder, Chem. Mater. 2006, 18, 1873 - 1877.
20. C. Wood, D. Emin, Phys. Rev. B 1984, 29, 4582 - 4587
21. C. Wood, D. Emin, P. E. Gray, Phys. Rev. B 1985, 31, 6811 - 6814.
22. C. Wood, Rep. Prog. Phys. 1988, 51, 459 - 539
23. G. Joshi, H. Lee, Y. Lan, X. Wang, G. Zhu, D. Wang, R. W. Gould, D. C. Cuff, M. Y. Tang, M. S. Dresselhaus, G. Chen, Z. Ren, Nano Lett. 2008, 8, 4670 - 4674.
24. H. Ohta, K. Sugiura, K. Koumoto, Inorg. Chem. 2008, 47, 8429 - 8436
25. L. Bocher, M. H. Aguirre, D. Logvinovich, A. Shkabko, R. Robert, M. Trottmann, A. Weidenkaff, Inorg. Chem. 2008, 47, 8077 - 8085; significantly higher ZT values were reported for some Co oxides; however these data were not reproduced later by other groups, see reference [14a] and discussion therein.
26. T. Mori, in Handbook on the Physics and Chemistry of Rare Earths, Vol. 38 (Eds.:, K. A. Gschneidner, Jr., J.-C. Bunzli, V. Pecharsky,), North-Holland, Amsterdam, 2008
27. T. Mori, T. Nishimura, J. Solid State Chem. 2006, 179, 2908 - 2915.
28. B. B. Iversen, A. E. C. Palmqvist, D. E. Cox, G. S. Nolas, G. D. Stucky, N. P. Blake, H. Metiu, J. Solid State Chem. 2000, 149, 455 - 458.
29. M. Falmbigl, P. F. Rogl, E. Bauer, M. Kriegisch, H. Mueller, S. Paschen, Mater. Res. Soc. Symp. Proc. 2009, 1166, 1166 -N 06 -03.
30. C. L. Condron, S. M. Kauzlarich, T. Ikeda, G. J. Snyder, F. Haarmann, P. Jeglič, Inorg. Chem. 2008, 47, 8204 - 8212
31. C. L. Condron, S. M. Kauzlarich, F. Gascoin, G. J. Snyder, Chem. Mater. 2006, 18, 4939 - 4945.
32. K. A. Kovnir, A. V. Shevelkov, Uspekhi Khimii 2004, 73, 999 - 1015
33. K. A. Kovnir, A. V. Shevelkov, Russ. Chem. Rev. 2004, 73, 923 - 938.
34. V. Pacheco, R. Cardoso Gil, Yu. Grin, The 11th European Conference on Solid State Chemistry, Program Schedule and Abstract Book, Caen, 2007, 194.
35. A. Saramat, G. Svensson, A. E. C. Palmqvist, C. Stiewe, E. Mueller, D. Platzek, S. G. K. Williams, D. M. Rowe, J. D. Bryan, G. D. Stucky, J. Appl. Phys. 2006, 99, 023708 /1- 5.
36. J. V. Zaikina, K. A. Kovnir, F. Haarmann, W. Schnelle, U. Burkhardt, H. Borrmann, U. Schwarz, Yu. Grin, A. V. Shevelkov, Chem. Eur. J. 2008, 14, 5414 - 5422.
37. J. V. Zaikina, K. A. Kovnir, U. Schwarz, H. Borrmann, A. V. Shevelkov, Z. Kristallogr. New Cryst. Struct. 2007, 222, 177 - 179
38. K. Kishimoto, T. Koyanagi, K. Akai, M. Matsuura, Jpn. J. Appl. Phys. 2007, 46, L746 - L748
39. F. Philipp, P. Schmidt, J. Cryst. Growth 2008, 310, 5402 - 5408
40. J. V. Zaikina, K. A. Kovnir, U. Burkhardt, W. Schnelle, F. Haarmann, U. Schwarz, Yu. Grin, A. V. Shevelkov, Inorg. Chem. 2009, 48, 3720 - 3730.
41. A. Müller, H. Reuter, S. Dillinger, Angew. Chem. 1995, 107, 2505 - 2539
42. Angew. Chem. Int. Ed. Engl. 1995, 34, 2328 - 2361.
43. J. L. Cohn, G. S. Nolas, V. Fessatidis, T. H. Metcalf, G. A. Slack, Phys. Rev. Lett. 1999, 82, 779 - 782.
44. J. Nylén, M. Andersson, S. Lidin, U. Häusserman, J. Am. Chem. Soc. 2004, 126, 16306 - 16307
45. M. Christensen, B. B. Iversen, Chem. Mater. 2007, 19, 4896 - 4905
46. M. Christensen, N. Lock, J. Overgaard, B. B. Iversen, J. Am. Chem. Soc. 2006, 128, 15657 - 15665.
47. J. V. Zaikina, K. A. Kovnir, A. V. Sobolev, I. A. Presniakov, Y. Prots, M. Baitinger, W. Schnelle, A. V. Olenev, O. I. Lebedev, G. Van Tendeloo, Y. Grin, A. V. Shevelkov, Chem. Eur. J. 2007, 13, 5090 - 5099.
48. E. M. Vass, M. Hävecker, S. Zafeiratos, D. Teschner, A. Knop-Gericke, R. Schlögl, J. Phys. Condens. Matter 2008, 20, 184016
49. K. Kovnir, M. Armbrüster, D. Teschner, T. V. Venkov, L. Szentmiklósi, F. C. Jentoft, A. Knop-Gericke, Yu. Grin, R. Schlögl, Surf. Sci. 2009, 603, 1784 - 1792.
50. NIST Electron Inelastic Mean Free Path Database, version 1.1, can be found under.
51. J. F. Moulder, W. F. Stickle, P. E. Sobol, K. D. Bomben, in Handbook of X-ray Photoelectron Spectroscopy, Physical-Electronics, Inc., Eden Prairie, 1995.
52. A. di Bona, F. Sabary, S. Valeri, P. Michelato, D. Sertore, G. Suberlucq, J. Appl. Phys. 1996, 80, 3024 - 3030
53. P. Michelato, C. Pagani, D. Sertore, A. di Bona, S. Valeri, Nucl. Instr. Meth. Phys. Res. A 1997, 393, 464 - 468
54. D. Bisero, A. di Bona, P. Paradisi, S. Valeri, J. Appl. Phys. 2000, 87, 543 - 548.
55. Chemistry, Structure and Bonding of Zintl Phases and Ions (Ed.:, S. M. Kauzlarich,), VCH, Weinheim, 1996.
56. J. R. Salvador, C. Malliakas, J. R. Gour, M. G. Kanatzidis, Chem. Mater. 2005, 17, 1636 - 1645.
57. 2, while the ρ values were obtained by smoothly extrapolating the resistivity results shown in Figure 5a.
58. X. Shi, J. Yang, S. Bai, J. Yang, H. Wang, M. Chi, J. R. Salvador, W. Zhang, L. Chen, W. Wong-Ng, Adv. Funct. Mater. 2010, 20, 755 - 763.
59. J. V. Zaikina, W. Schnelle, K. A. Kovnir, A. V. Olenev, Y. Grin, A. V. Shevelkov, Solid State Sci. 2007, 9, 664 - 671.
60. M. Hoelzel, A. Senyshyn, R. Gilles, H. Boysen, H. Fuess, Neutron News 2007, 18, 23 - 26.
61. V. Petricek, M. Dusek, L. Palatinus, JANA2000, Institute of Physics, Academy of Science of the Czech Republic, 2002.