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THF can also be used, but this reaction yielded pinkish instead of white powders in toluene. We suspect the color develops from the generation of gold nanoparticles under these experimental conditions
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THF can also be used, but this reaction yielded pinkish instead of white powders in toluene. We suspect the color develops from the generation of gold nanoparticles under these experimental conditions.
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CCDC 773700 for complex 3ga and CCDC 776375-776384 for complexes 3aa′-3ac′, 3ba′, 3da′-3ga′, and 3ia′-3ka′ contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via
-
CCDC 773700 for complex 3ga and CCDC 776375-776384 for complexes 3aa′-3ac′, 3ba′, 3da′-3ga′, and 3ia′-3ka′ contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data-request/cif.
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The Web-based free-access SambVca software is available online at
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The Web-based free-access SambVca software is available online at http://www.molnac.unisa.it/OMtools/sambvca.php.
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For the values obtained using the XRD-determined bond length for Au-C of each complex see the Supporting Information
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For the values obtained using the XRD-determined bond length for Au-C of each complex see the Supporting Information.
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