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Volumn 48, Issue 4, 2010, Pages 927-935

Intrastrand foldamer crosslinking by reductive amination

Author keywords

Crosslinking; Oligomers; Self organization; Supra molecular structures

Indexed keywords

ALDEHYDE MOIETY; CROSSLINKED; CROSSLINKER; CROSSLINKS; FOLDAMERS; FOLDED STATE; HELICAL CONFORMATION; REDUCTIVE AMINATION; SELF-ORGANIZATION; SELF-ORGANIZATIONS; SOLVENT DENATURATION; SUPRA-MOLECULAR STRUCTURES;

EID: 77958528158     PISSN: 0887624X     EISSN: 10990518     Source Type: Journal    
DOI: 10.1002/pola.23848     Document Type: Article
Times cited : (11)

References (35)
  • 25
    • 57349104751 scopus 로고    scopus 로고
    • Gong, B. Acc Chem Res 2008, 41, 1376-1386.
    • (2008) Acc Chem Res , vol.41 , pp. 1376-1386
    • Gong, B.1
  • 26
    • 36849057990 scopus 로고    scopus 로고
    • Hecht, S.; Huc, I. Foldamers: Structure, Properties, and Application; Wiley-VCH: Weinheim, 2007.
    • Hecht, S.; Huc, I. Foldamers: Structure, Properties, and Application; Wiley-VCH: Weinheim, 2007.
  • 30
    • 77958563557 scopus 로고    scopus 로고
    • Since the Tester sidechain that is attached to the monomer in the adjacent loop would obstruct the ability of the dia-mine crosslinker to reach to the aldehyde handle, it was deleted from the sequence by using monomer 12b
    • Since the Tester sidechain that is attached to the monomer in the adjacent loop would obstruct the ability of the dia-mine crosslinker to reach to the aldehyde handle, it was deleted from the sequence by using monomer 12b.
  • 32
    • 77958546136 scopus 로고    scopus 로고
    • During the initial studies, oligomer 1 contained trimethyl-silyl acetylene end groups as an artifact of the solid-phase synthesis (see Ref. 29), resulting in the different m/z ratios observed in Figure 3 in comparison with the crosslinked oligomer used in the more detailed studies later on. These were later deleted from the sequence for convenience. These end groups do not have a measurable effect on the folding capability of the oligomer and their absence or presence does not affect the crosslinking reaction.
    • During the initial studies, oligomer 1 contained trimethyl-silyl acetylene end groups as an artifact of the solid-phase synthesis (see Ref. 29), resulting in the different m/z ratios observed in Figure 3 in comparison with the crosslinked oligomer used in the more detailed studies later on. These were later deleted from the sequence for convenience. These end groups do not have a measurable effect on the folding capability of the oligomer and their absence or presence does not affect the crosslinking reaction.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.