Folding-Promoted Methylation of a Helical DMAP Analogue

Journal of the American Chemical Society

Volumn 126, Issue 6, 2004, Pages 1648-1649

  Heemstra, Jennifer M ^a   Moore, Jeffrey S ^a  

^a UNIVERSITY OF ILLINOIS AT URBANA CHAMPAIGN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACETYLENE DERIVATIVE; CAVITAND; METHYL IODIDE; N,N DIMETHYLAMINOPYRIDINE DERIVATIVE; OLIGOMER; PHENYLENEETHYNYLENE; POLYCYCLIC AROMATIC HYDROCARBON; PYRIDINE DERIVATIVE; RESORCINOL; SYNTHETIC ENZYME MIMIC; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CONFORMATION; ENERGY TRANSFER; HYDROPHOBICITY; METHYLATION; MICROENVIRONMENT; MOLECULAR MIMICRY; REACTION ANALYSIS; SUPRAMOLECULAR CHEMISTRY;

EID: 1242269275     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja031842b     Document Type: Article

References (18)

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14. (a) Heemstra, J. M.; Moore, J. S. Org. Lett. Submitted for publication. 2003.
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16. The ratio of absorbance bands at 303 and 289 nm in the UV spectrum is consistent with a predominantly cisoid conformation of the PE backbone, based on the analysis described in ref 4.
17. Based on a helical model having six PE monomers per turn unit, as described in: Matsuda, K.; Stone, M. T.; Moore, J. S. J. Am. Chem. Soc. 2002, 124, 11836-11837.
18. 3]) over the concentration range at which k was measured.