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Volumn 113, Issue 9, 2009, Pages 3386-3389

Electrical double layer structure in ionic liquids: An understanding of the unusual capacitance-potential curve at a nonmetallic electrode

Author keywords

[No Author keywords available]

Indexed keywords

CAPACITANCE POTENTIALS; CAPACITANCE VALUES; COMPLEX POTENTIALS; DEGREE OF CURVATURES; DIELECTRIC CONSTANTS; ELECTRICAL DOUBLE LAYERS; GC ELECTRODES; GLASSY CARBONS; HIGHLY ORIENTED PYROLYTIC GRAPHITES; IONIC CONCENTRATIONS; METAL ELECTRODES; SEMICONDUCTOR THEORIES;

EID: 65249097183     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp8114447     Document Type: Article
Times cited : (94)

References (24)
  • 24
    • 65249122799 scopus 로고    scopus 로고
    • Islam, M. M, Ohsaka, T. Manuscript in preparation. The values of Cc (eq 2) and Cd (eq 3) were estimated by using the real parameters (inherent concentrations of ILs, the size of the cations, and values of e) of [EMI, BF4, DMOA, N(Tf)2, and [MTOA, N(Tf)2, The diameters of [EMI, DMOA, and [MTOA, were considered to be 6.0, 6.6, and 14.4 Å, respectively (Ue, M, Murakami, A, Nakamura, S. J. Electrochem. Soc. 2002, 149, 1385, Typically, the values of Cc that are assumed to be independent of the potential were calculated to be 19, 13, and 5 μF cm-2 in [EMI, BF4, DMOA, N(Tf)2, and [MTOA, N(Tf)2, respectively. To calculate the value of Cd, the value of, eq 3) was arbitrarily chosen to be 0.7 for all of the cases, and the temperature was 25°C
    • +][N(Tf)2 -], respectively. To calculate the value of Cd, the value of = (eq 3) was arbitrarily chosen to be 0.7 for all of the cases, and the temperature was 25°C.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.