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Islam, M. M, Ohsaka, T. Manuscript in preparation. The values of Cc (eq 2) and Cd (eq 3) were estimated by using the real parameters (inherent concentrations of ILs, the size of the cations, and values of e) of [EMI, BF4, DMOA, N(Tf)2, and [MTOA, N(Tf)2, The diameters of [EMI, DMOA, and [MTOA, were considered to be 6.0, 6.6, and 14.4 Å, respectively (Ue, M, Murakami, A, Nakamura, S. J. Electrochem. Soc. 2002, 149, 1385, Typically, the values of Cc that are assumed to be independent of the potential were calculated to be 19, 13, and 5 μF cm-2 in [EMI, BF4, DMOA, N(Tf)2, and [MTOA, N(Tf)2, respectively. To calculate the value of Cd, the value of, eq 3) was arbitrarily chosen to be 0.7 for all of the cases, and the temperature was 25°C
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+][N(Tf)2 -], respectively. To calculate the value of Cd, the value of = (eq 3) was arbitrarily chosen to be 0.7 for all of the cases, and the temperature was 25°C.
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