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Volumn 46, Issue 41, 2010, Pages 7831-7833

The unexpected mechanism of carbonyl hydrosilylation catalyzed by (Cp)(ArN)Mo(H)(PMe3)

Author keywords

[No Author keywords available]

Indexed keywords

CARBONYL DERIVATIVE; PHOSPHINE;

EID: 77957845996     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/c0cc01850c     Document Type: Article
Times cited : (36)

References (45)
  • 26
    • 2942544978 scopus 로고    scopus 로고
    • 3 in the first step See Supporting information for details
    • R. M. Bullock Chem.-Eur. J. 2004 10 2366
    • (2004) Chem.-Eur. J. , vol.10 , pp. 2366
    • Bullock, R.M.1
  • 29
    • 0000444420 scopus 로고
    • KIE: 0.76 (16 °C), 0.80 (26 °C), 1.12 (36 °C), 1.37 (46 °C) Small KIE was previously observed for ionic heterolytic cleavage, ref. 8 The formation of a silane σ-complex has been previously postulated for the ionic heterolytic cleavage mechanism (ref. 8a)
    • D. S. Williams M. H. Schofield R. R. Schrock Organometallics 1993 12 4560
    • (1993) Organometallics , vol.12 , pp. 4560
    • Williams, D.S.1    Schofield, M.H.2    Schrock, R.R.3
  • 41


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.