Diversity of catalysis by an imido-hydrido complex of molybdenum. Mechanism of carbonyl hydrosilylation and silane alcoholysis

Journal of the American Chemical Society

Volumn 131, Issue 3, 2009, Pages 908-909

  Peterson, Erik ^a   Khalimon, Andrey Y ^a   Simionescu, Razvan ^a   Kuzmina, Lyudmila G ^b   Howard, Judith A K ^c   Nikonov, Georgii I ^a  

^a BROCK UNIVERSITY   (Canada)

^b KURNAKOV INSTITUTE OF GENERAL AND INORGANIC CHEMISTRY   (Russian Federation)

^c DURHAM UNIVERSITY   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

[CARBONYL; ALCOHOLYSIS; HYDRIDE COMPLEXES; HYDRIDO COMPLEXES; SILYLATION REACTION; SUBSTRATE ACTIVATION;

HYDROSILYLATION; MOLYBDENUM; MOLYBDENUM COMPOUNDS;

SILANES;

BENZALDEHYDE; CARBONYL DERIVATIVE; IMIDO HYDRIDE COMPLEX; IMINE; MOLYBDENUM COMPLEX; NITRILE; SILANE; UNCLASSIFIED DRUG;

ALCOHOLYSIS; ARTICLE; CATALYSIS; CHEMICAL REACTION; HYDROSILYLATION; INFRARED SPECTROSCOPY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; X RAY DIFFRACTION;

EID: 67849103456     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja8085388     Document Type: Article

References (40)

1. (a) Barry, J. T.; Chacon, S. T.; Chisholm, M. H.; Huffman, J. C.; Streib, W. E. J. Am. Chem. Soc. 1995, 117, 1974.
2. (b) Leboeuf, J. F.; Leblanc, J. C.; Moise, C. C. R. Acad. Sci., Ser. II 1988, 307, 1757.
3. (c) Green, M. L. H.; Knowles, P. J. J. Chem. Soc., Perkin Trans. 1 1973, 989.
4. Titanocene catalysts: (a) Halterman, R. L.; Ramsey, T. M.; Chen, Z. J. Org. Chem. 1994, 59, 2642-2644.
5. (b) Harrod, J. F.; Xin, S. Can. J. Chem. 1995, 73, 999.
6. Group 4 metallocene catalysts: (a) Broene, R. D.; Buchwald, S. L. J. Am. Chem. Soc. 1993, 115, 12569.
7. (b) Carter, M. B.; Schiøtt, B.; Gutiérrez, A.; Buchwald, S. L. J. Am. Chem. Soc. 1994, 116, 11667.
8. (c) Yun, J.; Buchwald, S. L. J. Am. Chem. Soc. 1999, 121, 5640.
9. (d) Yun, S. S.; Yong, S. Y.; Lee, S. Bull. Korean Chem. Soc. 1997, 18, 1058.
10. Chalk, A. J.; Harrod, J. F. J. Am. Chem. Soc. 1965, 87, 16.
11. (a) Ojima, I.; Kogure, T.; Kumagai, M.; Horiuchi, S.; Sato, T. J. Organomet. Chem. 1976, 122, 83.
12. (b) Peyronel, J. F.; Kagan, H. B. Nouv. J. Chem. 1978, 2, 211.
13. (c) Reyers, C.; Prock, A.; Giering, W. P. Organometallics 2002, 21, 546, and references cited therein.
14. Zheng, G. Z.; Chan, T. H. Organometallics 1995, 14, 70.
15. (a) Nolin, K. A.; Krumper, J. R.; Pluth, M. D.; Bergman, R. G.; Toste, F. D. J. Am. Chem. Soc. 2007, 129, 14684.
16. (b) Chung, L. W.; Lee, H. G.; Lin, Z.; Wu, Y.-D. J. Ore. Chem. 2006, 71, 6000.
17. (c) Thiel, W. Angew. Chem., Int. Ed. 2003, 42, 5390.
18. (a) Royo, B.; Romão,C.C. J. Mol. Catal. A: Chem. 2005, 236, 107.
19. (b) Reis, P. M.; Romão, C. C.; Royo, B. Dalton Trans. 2006, 1842.
20. (c) Costa, P. J.; Romão, C. C.; Fernandens, A. C.; Royo, B.; Reis, P.; Calhorda, M. J. Chem.-Eur. J. 2007, 13, 3934.
21. (a) Ison, E. A.; Trivedi, E. R.; Corbin, R. A.; Abu-Omar, M. M. J. Am. Chem. Soc. 2005, 127, 15374.
22. (b) Du, G. D.; Abu-Omar, M. M. Organometallics 2006, 25, 4920.
23. (c) Du, G. D.; Fanwick, P. E.; Abu-Omar, M. M. J. Am. Chem. Soc. 2007, 129, 5180.
24. Catalytic reactions: (a) Calas, R.; Frainnet, E.; Bazouin, A. Compt. Rend. 1961, 252, 420.
25. (b) Murai, T.; Sakane, T.; Kato, S. J. Org. Chem. 1990, 55, 449.
26. (c) Caporusso, A. M.; Panziera, N.; Pertici, P.; Pitzalis, E.; Salvadori, P.; Vitulli, G.; Martra, G. J. Mol. Cat. A: Chem. 1999, 150, 275.
27. (d) Khalimon, A. Y.; Simionescu, R.; Kuzmina, L. G.; Howard, J. A. K.; Nikonov, G. I. Angew. Chem., Int. Ed. 2008, 47, 7701.
28. Stoichiometric hydrosilylation: (a) Chalk, A. J. J. Organomet. Chem. 1970, 21, 207.
29. (b) Corriu, R. J. P.; Moreau, J. J. E.; Pataud-Sat, M. J. Organomet. Chem. 1982, 228, 301.
30. (c) Kim, J.; Kang, Y.; Lee, J.; Kong, Y. K.; Gong, M. S.;2 Kang, S. O.; Ko, J. Organometallics 2001, 20, 937.
31. 2 carbonyl complexes, see: (a) Blackmore, I. J.; Emiao, C. J. S.; Buschhaus, M. S. A.; Patric, B. O.; Legzdins, P. Organometallics 2007, 26, 4881, and references therein.
32. (b) Williams, D. S.; Schofield, M. H.; Schrock, R. R. Organometallics 1993, 12, 4560.
33. See Supporting Information for details.
34. (a) Fang, X.; Huhmann-Vincent, J.; Scott, B. L.; Kubas, G. J. J. Organomet. Chem. 2000, 609, 95.
35. (b) Chang, S.; Scharrer, E.; Brookhart, M. J. Mol. Catal. A 1998, 130, 107.
36. (c) Scharrer, E.; Chang, S.; Brookhart, M. Organometallics 1995, 14, 5686.
37. (d) Brookhart, M.; Grant, B. E. J. Am. Chem. Soc. 1993, 115, 2151.
38. (e) Luo, X.-L.; Crabtree, R. H. J. Am. Chem. Soc. 1989, 115, 2527.
39. (a) Belkova, N. V.; Shubina, E. S.; Epstein, L. M. Acc. Chem. Res. 2005, 38, 624.
40. (b) Belkova, N. V.; Dub, P. V.; Baya, M.; Houghton, J. Inorg. Chim. Acta 2007, 360, 149.