Nickel-catalyzed stereoselective glycosylation with C(2)- N-substituted benzylidene d-glucosamine and galactosamine trichloroacetimidates for the formation of 1,2-cis-2-amino glycosides. applications to the synthesis of heparin disaccharides, GPI anchor pseudodisaccharides, and α-GalNAc

Journal of the American Chemical Society

Volumn 132, Issue 40, 2010, Pages 14288-14302

  Mensah, Enoch A ^a   Yu, Fei ^a   Nguyen, Hien M ^a  

^a E11 SSH   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ANOMERICS; BENZYLIDENE; COUPLING PROCESS; COUPLING PRODUCT; DISACCHARIDE DONOR; GALACTOSAMINE; GLUCOSAMINES; GLYCOCONJUGATES; GLYCOPEPTIDES; GLYCOSYL DONORS; HEPARIN DISACCHARIDE; HIGH YIELD; KEY COMPONENT; LIGAND COMPLEXES; LOW-YIELD; MECHANISTIC STUDIES; NOVEL METHODS; PROTECTING GROUP; REACTION TIME; REACTIVE SITE; STATE-OF-THE-ART METHODS; STEREO-SELECTIVE; TRICHLOROACETIMIDATES;

CATALYSIS; COMPLEXATION; ESTERIFICATION; GLYCOSYLATION; OLIGOSACCHARIDES; POLYSACCHARIDES; SUBSTITUTION REACTIONS; SYNTHESIS (CHEMICAL);

NICKEL;

ALCOHOL DERIVATIVE; BENZYLIDENE DERIVATIVE; DISACCHARIDE; GALACTOSAMINE; GLUCOSAMINE; GLYCOCONJUGATE; GLYCOPEPTIDE; GLYCOSIDE; HEPARIN DERIVATIVE; NICKEL COMPLEX; NUCLEOPHILE; OLIGOSACCHARIDE;

ARTICLE; CATALYSIS; CATALYST; COMPLEX FORMATION; CROSS COUPLING REACTION; GLYCOSYLATION; QUANTUM YIELD; REACTION ANALYSIS; REACTION TIME; STEREOCHEMISTRY; SYNTHESIS;

ACETYLGALACTOSAMINE; BENZYLIDENE COMPOUNDS; CATALYSIS; GALACTOSAMINE; GLUCOSAMINE; GLYCOSYLATION; GLYCOSYLPHOSPHATIDYLINOSITOLS; HEPARIN; NICKEL;

EID: 77957705226     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja106682m     Document Type: Article

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