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Volumn 29, Issue 19, 2010, Pages 4298-4304

Erratum: Highly reactive cyclopentadienylcobalt(I) olefin complexes (Organometallics (2010) 29 (4298) DOI: 10.1021/om100692k);Highly reactive cyclopentadienylcobalt(I) olefin complexes

Author keywords

[No Author keywords available]

Indexed keywords

CYCLOADDITION; SUBSTITUTION REACTIONS;

EID: 77957662128     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om101165u     Document Type: Erratum
Times cited : (54)

References (63)
  • 41
    • 77957674369 scopus 로고
    • Ph.D. Thesis, Universität Bochum.
    • Habermann, D. Ph.D. Thesis, Universität Bochum, 1980.
    • (1980)
    • Habermann, D.1
  • 42
    • 0031069002 scopus 로고    scopus 로고
    • Complex 6 has been reported to be synthesized by adaption of the Jonas protocol, without description of experimental details, and the NMR data have been provided
    • Complex 6 has been reported to be synthesized by adaption of the Jonas protocol, without description of experimental details, and the NMR data have been provided: Lenges, C. P.; Brookhart, M.; Grant, B. E. J. Organomet. Chem. 1997, 528, 199
    • (1997) J. Organomet. Chem. , vol.528 , pp. 199
    • Lenges, C.P.1    Brookhart, M.2    Grant, B.E.3
  • 43
    • 77957670890 scopus 로고    scopus 로고
    • note
    • 2 = 0.0696, 193 refined parameters.
  • 44
    • 77957666314 scopus 로고    scopus 로고
    • note
    • 2 = 0.0886, 102 refined parameters.
  • 45
    • 77957666504 scopus 로고    scopus 로고
    • note
    • 2 = 0.0930, 108 refined parameters.
  • 46
    • 0039420077 scopus 로고
    • An X-ray structure determination of 4 was mentioned, but has never been published
    • An X-ray structure determination of 4 was mentioned, but has never been published: Benn, R.; Cibura, K.; Hofmann, P.; Jonas, K.; Rufińska, A. Organometallics 1985, 4, 2214
    • (1985) Organometallics , vol.4 , pp. 2214
    • Benn, R.1    Cibura, K.2    Hofmann, P.3    Jonas, K.4    Rufińska, A.5
  • 47
    • 77957685434 scopus 로고    scopus 로고
    • note
    • The following angles (deg) were found in the trigonal-planar coordination: DB1-Co1-DB2 = 96.1°; DB1-Co1-Cp = 132.5°; DB2-Co1-Cp = 131.5° [here, DB1 (C1, C2) and DB2 (C3, C4) are the center of the double bonds and Cp is the centroid of the cyclopentadienyl ring].
  • 50
    • 77957683746 scopus 로고    scopus 로고
    • note
    • 29Si NMR spectroscopy was possible (see Supporting Information). Solutions of 6, however, can be stored for months at -30 °C in the freezer and used for subsequent reactions without problems.
  • 51
    • 77957657672 scopus 로고
    • 13C NMR data no molecular structures were described and the synthesis described in our paper starting from 6 afforded the pure complexes fast and quantitatively.
    • 13C NMR data no molecular structures were described and the synthesis described in our paper starting from 6 afforded the pure complexes fast and quantitatively.
    • (1985)
    • Cibura, K.1
  • 52
    • 77957654556 scopus 로고    scopus 로고
    • NMR and MS analysis proved the formation of 12; the spectra can be found in the Supporting Information.
    • NMR and MS analysis proved the formation of 12; the spectra can be found in the Supporting Information.
  • 53
    • 77957682363 scopus 로고    scopus 로고
    • note
    • Also compare the following angles: 7: C2-Co1-C2a 90.48(12)°, C1-Co1-C1a 112.8(3)°; 8: C1-Co1-C6 89.52(9)°, C2-Co1-C5 94.10(7)°, C1-Co1-C5 105.06(8)°, C2-Co1-C6 106.16(8)°; 9: C1-Co1-C6 93.2(2)°, C2-Co1-C5 83.3(2)°, C1-Co1-C5 97.4(2)°, C2-Co1-C6 106.6(2)°.
  • 55
    • 77957657037 scopus 로고    scopus 로고
    • For an overview of the different observed shifts see the table in the Supporting Information
    • For an overview of the different observed shifts see the table in the Supporting Information.
  • 57
    • 77957681745 scopus 로고    scopus 로고
    • note
    • Details for the calculations on the relative energetics of the substitution reaction can be found in the Supporting Information.
  • 58
    • 77957676006 scopus 로고    scopus 로고
    • note
    • Complex 9 was found to be unchanged in the composition of its crystal form after about two weeks in air. However, the evaporation of a NMR sample of 9 and leaving the solid residue open to air resulted in decomposition of the complex after 24 h, as proven by NMR.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.