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Krause, J.; Cestaric, G.; Haack, K.-J.; Seevogel, K.; Storm, W.; Pörschke, K.-R. J. Am. Chem. Soc. 1999, 121, 9807
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5
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35348960532
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Blum, K.; Chernyshova, E. S.; Goddard, R.; Jonas, K.; Pörschke, K.-R. Organometallics 2007, 26, 5174, and references therein.
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Blum, K.1
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6
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36248988143
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Berthon-Gelloz, G.; Schumers, J.-M.; Lucaccioni, F.; Tinant, B.; Wouters, J.; I. E. Markó, Organometallics 2007, 26, 5731, and cited references.
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Berthon-Gelloz, G.1
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7
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0343938731
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Reviews
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Reviews: Jonas, K.; Krüger, C. Angew. Chem., Int. Ed. Engl. 1980, 19, 520
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Jonas, K.1
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84985569607
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Jonas, K.; Deffense, E.; Habermann, D. Angew. Chem., Int. Ed. Engl. 1983, 22, 716
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Jonas, K.1
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49749094562
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Agenet, N.; Busine, O.; Slowinski, F.; Gandon, V.; Aubert, C.; Malacria, M. Org. React. 2007, 68, 1
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Agenet, N.1
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Galan, B. R.; Rovis, T. Angew. Chem., Int. Ed. 2009, 48, 2830, and cited references.
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Galan, B.R.1
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Bringmann, G.; Price Mortimer, A. J.; Keller, P. A.; Gresser, M. J.; Garner, J.; Breuning, M. Angew. Chem., Int. Ed. 2005, 44, 5384
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Bringmann, G.1
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Geny, A.; Agenet, N.; Iannazzo, L.; Malacria, M.; Aubert, C.; Gandon, V. Angew. Chem., Int. Ed. 2009, 48, 1810
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30
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69449088566
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Recent examples for the use of 4
-
Recent examples for the use of 4: Sehnal, P.; Stará, I. G.; Šaman, D.; Tichý, M.; Míšek, J.; Cvačka, J.; Rulíšek, L.; Chocholoušová, J.; Vacek, J.; Goryl, G.; Szymonski, M.; Císařová, I.; Starý, I. Proc. Natl. Acad. Sci. 2009, 106, 13169
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Sehnal, P.1
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Tichý, M.4
Míšek, J.5
Cvačka, J.6
Rulíšek, L.7
Chocholoušová, J.8
Vacek, J.9
Goryl, G.10
Szymonski, M.11
Císařová, I.12
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Leboeuf, D.; Gandon, V.; Aubert, C.; Malacria, M. Chem. - Eur. J. 2009, 15, 2129
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Leboeuf, D.1
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49749112950
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Amslinger, S.; Aubert, C.; Gandon, V.; Malacria, M.; Paredes, E.; Vollhardt, K. P. C. Synlett 2008, 2056
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Synlett
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Amslinger, S.1
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Aubert, C.; Betschmann, P.; Eichberg, M. J.; Gandon, V.; Heckrodt, T. J.; Lehmann, J.; Malacria, M.; Masjost, B.; Paredes, E.; Vollhardt, K. P. C.; Whitener, G. D. Chem. - Eur. J. 2007, 13, 7443
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Aubert, C.1
Betschmann, P.2
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Heckrodt, T.J.5
Lehmann, J.6
Malacria, M.7
Masjost, B.8
Paredes, E.9
Vollhardt, K.P.C.10
Whitener, G.D.11
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35
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29144437862
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Hrdina, R.; Stará, I. G.; Dufková, L.; Mitchel, S.; Císařová, I.; Kotora, M. Tetrahedron 2006, 62, 968
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(2006)
Tetrahedron
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, pp. 968
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Hrdina, R.1
Stará, I.G.2
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Mitchel, S.4
Císařová, I.5
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36
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20144364242
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Goswami, A.; Maier, C.-J.; Pritzkow, H.; Siebert, W. J. Organomet. Chem. 2005, 690, 3251
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Goswami, A.1
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37
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77953492952
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Hapke, M.; Kral, K.; Fischer, C.; Spannenberg, A.; Gutnov, A.; Redkin, D.; Heller, B. J. Org. Chem. 2010, 75, 3993-4003
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Hapke, M.1
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Heller, B.7
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38
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38349138606
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Heller, B.; Redkin, D.; Gutnov, A.; Fischer, C.; Bonrath, W.; Karge, R.; Hapke, M. Synthesis 2008, 69
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Synthesis
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Heller, B.1
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Karge, R.6
Hapke, M.7
-
39
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33846585041
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Heller, B.; Gutnov, A.; Fischer, C.; Drexler, H.-J.; Spannenberg, A.; Redkin, D.; Sundermann, C.; Sundermann, B. Chem. - Eur. J. 2007, 13, 1117
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Heller, B.1
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Redkin, D.6
Sundermann, C.7
Sundermann, B.8
-
40
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4544286694
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Gutnov, A.; Heller, B.; Fischer, C.; Drexler, H.-J.; Spannenberg, A.; Sundermann, C.; Sundermann, B. Angew. Chem., Int. Ed. 2004, 43, 3795
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Gutnov, A.1
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Sundermann, B.7
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41
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77957674369
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-
Ph.D. Thesis, Universität Bochum.
-
Habermann, D. Ph.D. Thesis, Universität Bochum, 1980.
-
(1980)
-
-
Habermann, D.1
-
42
-
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0031069002
-
-
Complex 6 has been reported to be synthesized by adaption of the Jonas protocol, without description of experimental details, and the NMR data have been provided
-
Complex 6 has been reported to be synthesized by adaption of the Jonas protocol, without description of experimental details, and the NMR data have been provided: Lenges, C. P.; Brookhart, M.; Grant, B. E. J. Organomet. Chem. 1997, 528, 199
-
(1997)
J. Organomet. Chem.
, vol.528
, pp. 199
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Lenges, C.P.1
Brookhart, M.2
Grant, B.E.3
-
43
-
-
77957670890
-
-
note
-
2 = 0.0696, 193 refined parameters.
-
-
-
-
44
-
-
77957666314
-
-
note
-
2 = 0.0886, 102 refined parameters.
-
-
-
-
45
-
-
77957666504
-
-
note
-
2 = 0.0930, 108 refined parameters.
-
-
-
-
46
-
-
0039420077
-
-
An X-ray structure determination of 4 was mentioned, but has never been published
-
An X-ray structure determination of 4 was mentioned, but has never been published: Benn, R.; Cibura, K.; Hofmann, P.; Jonas, K.; Rufińska, A. Organometallics 1985, 4, 2214
-
(1985)
Organometallics
, vol.4
, pp. 2214
-
-
Benn, R.1
Cibura, K.2
Hofmann, P.3
Jonas, K.4
Rufińska, A.5
-
47
-
-
77957685434
-
-
note
-
The following angles (deg) were found in the trigonal-planar coordination: DB1-Co1-DB2 = 96.1°; DB1-Co1-Cp = 132.5°; DB2-Co1-Cp = 131.5° [here, DB1 (C1, C2) and DB2 (C3, C4) are the center of the double bonds and Cp is the centroid of the cyclopentadienyl ring].
-
-
-
-
49
-
-
0032558084
-
-
Lenges, C. P.; White, P. S.; Brookhart, M. J. Am. Chem. Soc. 1998, 120, 6965
-
(1998)
J. Am. Chem. Soc.
, vol.120
, pp. 6965
-
-
Lenges, C.P.1
White, P.S.2
Brookhart, M.3
-
50
-
-
77957683746
-
-
note
-
29Si NMR spectroscopy was possible (see Supporting Information). Solutions of 6, however, can be stored for months at -30 °C in the freezer and used for subsequent reactions without problems.
-
-
-
-
51
-
-
77957657672
-
-
13C NMR data no molecular structures were described and the synthesis described in our paper starting from 6 afforded the pure complexes fast and quantitatively.
-
13C NMR data no molecular structures were described and the synthesis described in our paper starting from 6 afforded the pure complexes fast and quantitatively.
-
(1985)
-
-
Cibura, K.1
-
52
-
-
77957654556
-
-
NMR and MS analysis proved the formation of 12; the spectra can be found in the Supporting Information.
-
NMR and MS analysis proved the formation of 12; the spectra can be found in the Supporting Information.
-
-
-
-
53
-
-
77957682363
-
-
note
-
Also compare the following angles: 7: C2-Co1-C2a 90.48(12)°, C1-Co1-C1a 112.8(3)°; 8: C1-Co1-C6 89.52(9)°, C2-Co1-C5 94.10(7)°, C1-Co1-C5 105.06(8)°, C2-Co1-C6 106.16(8)°; 9: C1-Co1-C6 93.2(2)°, C2-Co1-C5 83.3(2)°, C1-Co1-C5 97.4(2)°, C2-Co1-C6 106.6(2)°.
-
-
-
-
54
-
-
0010387673
-
-
Ondracek, J.; Schehlmann, V.; Maixner, J.; Kratochvil, B. Collect. Czech. Chem. Commun. 1990, 55, 2447
-
(1990)
Collect. Czech. Chem. Commun.
, vol.55
, pp. 2447
-
-
Ondracek, J.1
Schehlmann, V.2
Maixner, J.3
Kratochvil, B.4
-
55
-
-
77957657037
-
-
For an overview of the different observed shifts see the table in the Supporting Information
-
For an overview of the different observed shifts see the table in the Supporting Information.
-
-
-
-
56
-
-
0001514961
-
-
Belt, S. T.; Duckett, S. B.; Haddleton, D. M.; Perutz, R. N. Organometallics 1989, 8, 748
-
(1989)
Organometallics
, vol.8
, pp. 748
-
-
Belt, S.T.1
Duckett, S.B.2
Haddleton, D.M.3
Perutz, R.N.4
-
57
-
-
77957681745
-
-
note
-
Details for the calculations on the relative energetics of the substitution reaction can be found in the Supporting Information.
-
-
-
-
58
-
-
77957676006
-
-
note
-
Complex 9 was found to be unchanged in the composition of its crystal form after about two weeks in air. However, the evaporation of a NMR sample of 9 and leaving the solid residue open to air resulted in decomposition of the complex after 24 h, as proven by NMR.
-
-
-
-
60
-
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27644487954
-
-
Hilt, G.; Hess, W.; Vogler, T.; Hengst, C. J. Organomet. Chem. 2005, 690, 5170
-
(2005)
J. Organomet. Chem.
, vol.690
, pp. 5170
-
-
Hilt, G.1
Hess, W.2
Vogler, T.3
Hengst, C.4
-
62
-
-
0000699784
-
-
Olson, W. L.; Nagaki, D. A.; Dahl, L. F. Organometallics 1986, 5, 630
-
(1986)
Organometallics
, vol.5
, pp. 630
-
-
Olson, W.L.1
Nagaki, D.A.2
Dahl, L.F.3
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