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Besides from diethyl ether, dendritic crystals were also obtained from pentane, while powdery products separated from toluene and thf. The sublimates were likewise not suited for a structure determination
-
Besides from diethyl ether, dendritic crystals were also obtained from pentane, while powdery products separated from toluene and thf. The sublimates were likewise not suited for a structure determination.
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3, R1 = 0.061, wR2 = 0.083). The molecules pack differently (no longer parallel stacks, Ni-Ni 5.235 ̊) and adopt a slightly different conformation of the terminal allyl groups. This polymorph was obtained under apparently similar conditions, but could not be reproduced now. For disappearing polymorphs, see: Dunitz, J. D.; Bernstein, J. Ace Chem. Res. 1995, 28, 193.
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3, R1 = 0.061, wR2 = 0.083). The molecules pack differently (no longer parallel stacks, Ni-Ni 5.235 ̊) and adopt a slightly different conformation of the terminal allyl groups. This polymorph was obtained under apparently similar conditions, but could not be reproduced now. For disappearing polymorphs, see: Dunitz, J. D.; Bernstein, J. Ace Chem. Res. 1995, 28, 193.
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1H-correlated spectroscopy.
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1H-correlated spectroscopy.
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