메뉴 건너뛰기




Volumn 43, Issue 9, 2010, Pages 1267-1278

Highly electrophilic organometallics for carbocationic polymerizations: From anion engineering to new polymer materials

Author keywords

[No Author keywords available]

Indexed keywords


EID: 77956950702     PISSN: 00014842     EISSN: 15204898     Source Type: Journal    
DOI: 10.1021/ar100044s     Document Type: Article
Times cited : (47)

References (65)
  • 1
    • 0033433057 scopus 로고    scopus 로고
    • Highly Electrophilic Metallocenes and Their Role in Alkene Polymerizations
    • Bochmann, M. Highly Electrophilic Metallocenes and Their Role in Alkene Polymerizations Top. Catal. 1999, 7, 9-22
    • (1999) Top. Catal. , vol.7 , pp. 9-22
    • Bochmann, M.1
  • 2
    • 84942758281 scopus 로고
    • Ziegler-Natta Catalysis
    • Wilkinson, G.; Stone, F. G. A.; Abel, E. W., Eds.; Pergamon: Oxford
    • Gavens, P. D.; Bottril, M.; Kelland, J. W.; McMeeking, J. Ziegler-Natta Catalysis. In Comprehensive Organometallic Chemistry; Wilkinson, G.; Stone, F. G. A.; Abel, E. W., Eds.; Pergamon: Oxford, 1982; Vol. 3, pp 475 - 547.
    • (1982) Comprehensive Organometallic Chemistry , vol.3 , pp. 475-547
    • Gavens, P.D.1    Bottril, M.2    Kelland, J.W.3    McMeeking, J.4
  • 5
    • 0006375307 scopus 로고
    • Carbocationic Polymerizations: Alkenes and Dienes
    • Allen, G.; Bevington, J. C., Eds.; Pergamon: New York
    • Nuyken, O.; Pask, S. D. Carbocationic Polymerizations: Alkenes and Dienes. In Comprehensive Polymer Science; Allen, G.; Bevington, J. C., Eds.; Pergamon: New York, 1989; Vol. 3, pp 619 - 637.
    • (1989) Comprehensive Polymer Science , vol.3 , pp. 619-637
    • Nuyken, O.1    Pask, S.D.2
  • 6
    • 0343034378 scopus 로고
    • Carbocationic Polymerization: Copolymerization
    • Allen, G.; Bevington, J. C., Eds.; Pergamon: New York
    • Kenndy, J. P. Carbocationic Polymerization: Copolymerization. In Comprehensive Polymer Science; Allen, G.; Bevington, J. C., Eds.; Pergamon: New York, 1989; Vol. 3, pp 705 - 710.
    • (1989) Comprehensive Polymer Science , vol.3 , pp. 705-710
    • Kenndy, J.P.1
  • 7
    • 2142688256 scopus 로고    scopus 로고
    • Intramolecular Coordination of an Alkene to a Mixed Dicyclopentadienyl Benzyl Zirconium Cation Studied by NMR Spectroscopy
    • Galakhov, M. V.; Heinz, G.; Royo, R. Intramolecular Coordination of an Alkene to a Mixed Dicyclopentadienyl Benzyl Zirconium Cation Studied by NMR Spectroscopy Chem. Commun. 1998, 17-18
    • (1998) Chem. Commun. , pp. 17-18
    • Galakhov, M.V.1    Heinz, G.2    Royo, R.3
  • 10
    • 9944249483 scopus 로고    scopus 로고
    • Kinetic and Mechanistic Aspects of Metallocene Polymerization Catalysts
    • Bochmann, M. Kinetic and Mechanistic Aspects of Metallocene Polymerization Catalysts J. Organomet. Chem. 2004, 689, 3982
    • (2004) J. Organomet. Chem. , vol.689 , pp. 3982
    • Bochmann, M.1
  • 11
    • 84889833920 scopus 로고    scopus 로고
    • The Use of Spectroscopy in Metallocene-Based Polymerization Catalysis
    • Heaton, B. T., Ed.; Wiley-VCH: Weinheim, Germany
    • Bochmann, M. The Use of Spectroscopy in Metallocene-Based Polymerization Catalysis. In Catalytic Mechanisms from Spectroscopic Measurements; Heaton, B. T., Ed.; Wiley-VCH: Weinheim, Germany, 2005; pp 311 - 357.
    • (2005) Catalytic Mechanisms from Spectroscopic Measurements , pp. 311-357
    • Bochmann, M.1
  • 12
    • 0018052617 scopus 로고
    • Cationic Olefin Polymerization Using Alkyl Halide Alkylaluminum Initiator Systems
    • Kennedy, J. P.; Trivedi, P. D. Cationic Olefin Polymerization Using Alkyl Halide Alkylaluminum Initiator Systems Adv. Polym. Sci. 1978, 28, 83-151
    • (1978) Adv. Polym. Sci. , vol.28 , pp. 83-151
    • Kennedy, J.P.1    Trivedi, P.D.2
  • 13
    • 0000991724 scopus 로고
    • Studies on Polymerizations Initiated by Syncatalytic Systems Based on Aluminum Organic Compounds 7. Reaction Mechanisms
    • Magagnini, P. L.; Cesca, S.; Giusti, P.; Priola, A.; Di Maina, M. Studies on Polymerizations Initiated by Syncatalytic Systems Based on Aluminum Organic Compounds 7. Reaction Mechanisms Makromol. Chem. 1977, 178, 2235-2248
    • (1977) Makromol. Chem. , vol.178 , pp. 2235-2248
    • Magagnini, P.L.1    Cesca, S.2    Giusti, P.3    Priola, A.4    Di Maina, M.5
  • 16
    • 73249130329 scopus 로고    scopus 로고
    • A Renaissance in Living Cationic Polymerization
    • Aoshima, S.; Kanaoka, S. A Renaissance in Living Cationic Polymerization Chem. Rev. 2009, 109, 5245-5287
    • (2009) Chem. Rev. , vol.109 , pp. 5245-5287
    • Aoshima, S.1    Kanaoka, S.2
  • 17
    • 77956970651 scopus 로고    scopus 로고
    • note
    • There are a number of metal-free systems based on borate anions similar to the ones described here but which rely on proton initiation. These are beyond the scope of this Account.
  • 18
    • 77956970283 scopus 로고    scopus 로고
    • Reviews
    • Reviews
  • 19
    • 33646099282 scopus 로고    scopus 로고
    • Cationic Group IV Metallocene Complexes and Their Role in Polymerization Catalysis: The Chemistry of Well-Defined Ziegler Catalysts
    • Bochmann, M. Cationic Group IV Metallocene Complexes and Their Role in Polymerization Catalysis: The Chemistry of Well-Defined Ziegler Catalysts J. Chem. Soc., Dalton Trans. 1996, 255-270
    • (1996) J. Chem. Soc., Dalton Trans. , pp. 255-270
    • Bochmann, M.1
  • 20
    • 0033740669 scopus 로고    scopus 로고
    • Cocatalysts for Metal-Catalyzed Olefin Polymerization: Activators, Activation Processes, and Structure-Activity Relationships
    • Chen, E. Y. X.; Marks, T. J. Cocatalysts for Metal-Catalyzed Olefin Polymerization: Activators, Activation Processes, and Structure-Activity Relationships Chem. Rev. 2000, 100, 1391-1434
    • (2000) Chem. Rev. , vol.100 , pp. 1391-1434
    • Chen, E.Y.X.1    Marks, T.J.2
  • 21
    • 0030458202 scopus 로고    scopus 로고
    • +: A Highly Efficient Initiator for the Cationic Polymerisation of Isobutene
    • +: A Highly Efficient Initiator for the Cationic Polymerisation of Isobutene Angew. Chem., Int. Ed. Engl. 1996, 35, 2226-2228
    • (1996) Angew. Chem., Int. Ed. Engl. , vol.35 , pp. 2226-2228
    • Bochmann, M.1    Dawson, D.W.2
  • 26
    • 0033740668 scopus 로고    scopus 로고
    • Carbocationic Alkene Polymerizations Initiated by Organotransition Metal Complexes: An Alternative, Unusual Role for Soluble Ziegler-Natta Catalysts
    • Baird, M. C. Carbocationic Alkene Polymerizations Initiated by Organotransition Metal Complexes: An Alternative, Unusual Role for Soluble Ziegler-Natta Catalysts Chem. Rev. 2000, 100, 1471-1478
    • (2000) Chem. Rev. , vol.100 , pp. 1471-1478
    • Baird, M.C.1
  • 33
    • 0032492563 scopus 로고    scopus 로고
    • Zirconocenes as Initiators for Carbocationic Isobutene Homo- and Co-Polymerizations
    • Carr, A. G.; Dawson, D. M.; Bochmann, M. Zirconocenes as Initiators for Carbocationic Isobutene Homo- and Co-Polymerizations Macromolecules 1998, 31, 2035-2040
    • (1998) Macromolecules , vol.31 , pp. 2035-2040
    • Carr, A.G.1    Dawson, D.M.2    Bochmann, M.3
  • 34
    • 0032366872 scopus 로고    scopus 로고
    • + cation as a novel initiator for carbocationic isobutene homo- and isobutene/isoprene co-polymerisations
    • + Cation as a Novel Initiator for Carbocationic Isobutene Homo- and Isobutene/Isoprene Co-Polymerizations Macromol. Rapid Commun. 1998, 19, 205-207 (Pubitemid 128477839)
    • (1998) Macromolecular Rapid Communications , vol.19 , Issue.4 , pp. 205-207
    • Carr, A.G.1    Dawson, D.M.2    Bochmann, M.3
  • 35
    • 0001164683 scopus 로고    scopus 로고
    • Cationic Zirconocene Hydrides: A New Type of Highly Effective Initiators for Carbocationic Polymerizations
    • Carr, A. G.; Dawson, D. M.; Thornton-Pett, M.; Bochmann, M. Cationic Zirconocene Hydrides: A New Type of Highly Effective Initiators for Carbocationic Polymerizations Organometallics 1999, 18, 2933-2935
    • (1999) Organometallics , vol.18 , pp. 2933-2935
    • Carr, A.G.1    Dawson, D.M.2    Thornton-Pett, M.3    Bochmann, M.4
  • 36
    • 0038236398 scopus 로고    scopus 로고
    • Isobutene Polymerization and Isobutene-Isoprene Copolymerization Catalyzed by Cationic Zirconocene Hydride Complexes
    • Garratt, S.; Carr, A. G.; Langstein, G.; Bochmann, M. Isobutene Polymerization and Isobutene-Isoprene Copolymerization Catalyzed by Cationic Zirconocene Hydride Complexes Macromolecules 2003, 36, 4276-4287
    • (2003) Macromolecules , vol.36 , pp. 4276-4287
    • Garratt, S.1    Carr, A.G.2    Langstein, G.3    Bochmann, M.4
  • 41
    • 33646374941 scopus 로고    scopus 로고
    • Solvent-Ligated Transition Metal Complexes as Initiators for the Polymerization of Isobutene
    • note
    • Similar anions have more recently also been used in combination with cationic transition metal acetonitrile complexes to generate low molecular weight polyisobutene at 30 °C: Nuyken, O.; Vierle, M.; Kühn, F. E.; Zhang, Y. Solvent-Ligated Transition Metal Complexes as Initiators for the Polymerization of Isobutene Macromol. Symp. 2006, 236, 69
    • (2006) Macromol. Symp. , vol.236 , pp. 69
    • Nuyken, O.1    Vierle, M.2    Kühn, F.E.3    Zhang, Y.4
  • 44
    • 0035900939 scopus 로고    scopus 로고
    • Synthesis, Structures and Reactivity of Weakly Coordinating Anions with Delocalized Borate Structure: The Assessment of Anion Effects in Metallocene Polymerization Catalysts
    • Zhou, J.; Lancaster, S. J.; Walker, D. A.; Beck, S.; Thornton-Pett, M.; Bochmann, M. Synthesis, Structures and Reactivity of Weakly Coordinating Anions with Delocalized Borate Structure: The Assessment of Anion Effects in Metallocene Polymerization Catalysts J. Am. Chem. Soc. 2001, 123, 223-237
    • (2001) J. Am. Chem. Soc. , vol.123 , pp. 223-237
    • Zhou, J.1    Lancaster, S.J.2    Walker, D.A.3    Beck, S.4    Thornton-Pett, M.5    Bochmann, M.6
  • 47
    • 77956957569 scopus 로고
    • (Sumitomo Chem. Co.) Method for the Preparation of Isobutene Polymers and Catalysts for Use therein. Brit. Pat. Appl. 1,343,670
    • (Sumitomo Chem. Co.) Method for the Preparation of Isobutene Polymers and Catalysts for Use therein. Brit. Pat. Appl. 1,343,670, 1971.
    • (1971)
  • 48
    • 0018435425 scopus 로고
    • Isobutylene Polymerization in the Presence of UV Light, Organic Iodides and Zinc Iodide
    • Diem, T.; Kennedy, J. P.; Chou, R. T. Isobutylene Polymerization in the Presence of UV Light, Organic Iodides and Zinc Iodide Polym. Bull. 1979, 1, 281-285
    • (1979) Polym. Bull. , vol.1 , pp. 281-285
    • Diem, T.1    Kennedy, J.P.2    Chou, R.T.3
  • 49
    • 4544234398 scopus 로고    scopus 로고
    • Arylzinc Complexes as New Initiator Systems for the Production of Isobutene Copolymers with High Isoprene Content
    • Garratt, S.; Guerrero, A.; Hughes, D. L.; Bochmann, M. Arylzinc Complexes as New Initiator Systems for the Production of Isobutene Copolymers with High Isoprene Content Angew. Chem., Int. Ed. 2004, 43, 2166-2169
    • (2004) Angew. Chem., Int. Ed. , vol.43 , pp. 2166-2169
    • Garratt, S.1    Guerrero, A.2    Hughes, D.L.3    Bochmann, M.4
  • 51
    • 33749141140 scopus 로고
    • Scales of Nucleophilicity and Electrophilicity: A System for Ordering Polar Organic and Organometallic Reactions
    • Mayr, H.; Patz, M. Scales of Nucleophilicity and Electrophilicity: A System for Ordering Polar Organic and Organometallic Reactions Angew. Chem., Int. Ed. Engl. 1994, 33, 938-957
    • (1994) Angew. Chem., Int. Ed. Engl. , vol.33 , pp. 938-957
    • Mayr, H.1    Patz, M.2
  • 52
    • 77956955403 scopus 로고    scopus 로고
    • Ph.D. Thesis, University of East Anglia
    • Guerrero, A. Ph.D. Thesis, University of East Anglia, 2007.
    • (2007)
    • Guerrero, A.1
  • 53
    • 33645383779 scopus 로고    scopus 로고
    • Synthesis and Crystal Structure of Ethyl Zinc Chloride
    • Guerrero, A.; Hughes, D. L.; Bochmann, M. Synthesis and Crystal Structure of Ethyl Zinc Chloride Organometallics 2006, 25, 1525-1527
    • (2006) Organometallics , vol.25 , pp. 1525-1527
    • Guerrero, A.1    Hughes, D.L.2    Bochmann, M.3
  • 54
    • 34347361552 scopus 로고    scopus 로고
    • "Highly Reactive" Poly(isobutene)s via Room-Temperature Polymerization with a New Zinc-Based Initiator System
    • Guerrero, A.; Kulbaba, K.; Bochmann, M. "Highly Reactive" Poly(isobutene)s via Room-Temperature Polymerization with a New Zinc-Based Initiator System Macromolecules 2007, 40, 4124-4126
    • (2007) Macromolecules , vol.40 , pp. 4124-4126
    • Guerrero, A.1    Kulbaba, K.2    Bochmann, M.3
  • 55
    • 55349115436 scopus 로고    scopus 로고
    • Alkylzink Chlorides as New Initiators for the Polymerization and Copolymerization of Isobutene
    • Guerrero, A.; Kulbaba, K.; Bochmann, M. Alkylzink Chlorides as New Initiators for the Polymerization and Copolymerization of Isobutene Macromol. Chem. Phys. 2008, 209, 1714-1720
    • (2008) Macromol. Chem. Phys. , vol.209 , pp. 1714-1720
    • Guerrero, A.1    Kulbaba, K.2    Bochmann, M.3
  • 60
    • 0000087231 scopus 로고    scopus 로고
    • Interactions between Carbocations and Anions in Crystals
    • Laube, T. Interactions between Carbocations and Anions in Crystals Chem. Rev. 1998, 98, 1277-1312
    • (1998) Chem. Rev. , vol.98 , pp. 1277-1312
    • Laube, T.1
  • 64
    • 34547662956 scopus 로고    scopus 로고
    • Evidence for Mixed-Ion Clusters in Metallocene Catalysts: Influence on Ligand Exchange Dynamics and Catalyst Activity
    • Alonso-Moreno, C.; Lancaster, S. J.; Zuccaccia, C.; Macchioni, A.; Bochmann, M. Evidence for Mixed-Ion Clusters in Metallocene Catalysts: Influence on Ligand Exchange Dynamics and Catalyst Activity J. Am. Chem. Soc. 2007, 127, 9282-9283
    • (2007) J. Am. Chem. Soc. , vol.127 , pp. 9282-9283
    • Alonso-Moreno, C.1    Lancaster, S.J.2    Zuccaccia, C.3    MacChioni, A.4    Bochmann, M.5


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.