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Volumn 43, Issue 16, 2004, Pages 2166-2169

Arylzinc complexes as new initiator systems for the production of isobutene copolymers with high isoprene content

Author keywords

Anions; Copolymerization; Isobutene; Lewis acids; Zinc

Indexed keywords

BUTENES; COPOLYMERIZATION; COPOLYMERS; CROSSLINKING; MOLECULAR WEIGHT;

EID: 4544234398     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200353787     Document Type: Article
Times cited : (37)

References (63)
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    • note
    • 5H is also observed.
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    • For Li and Mg salts of triarylzincates see for example: K. Thiele, H. Görls, W. Seidel, Z. Anorg. Allg. Chem. 1998, 624, 555; M. Krieger, G. Geiseler, K. Harms, J. Merle, W. Massa, K. Dehnicke, Z. Anorg. Allg. Chem. 1998, 624, 1387.
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    • Thiele, K.1    Görls, H.2    Seidel, W.3
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    • note
    • 1 = 0.059 for "observed" reflections. CCDC 228529 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/ retrieving.html (or from the Cambridge Crystallographic Data Centre, 12, Union Road, Cambridge CB21EZ, UK; fax: (+44)1223-336-033; or deposit@ccdc.cam.ac.uk).
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    • b) J. H. Williams, J. K. Cockcroft, A. N. Fitch, Angew. Chem. 1992, 104, 1666; Angew. Chem. Int. Ed. Engl. 1992, 31, 1655;
    • (1992) Angew. Chem. Int. Ed. Engl. , vol.31 , pp. 1655
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    • note
    • 2, [Zn] = 0.1 M and [tBuX] = 0.01-0.1 M (X = Cl, Br or I). Polymers were analyzed by size-exclusion chromatography in THF at 25 °C using a Polymer Laboratories GPC-220 instrument equipped with a dual refractive index/light-scattering detector.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.