Noncoordinating anions in carbocationic polymerization

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 35, Issue 2, 1997, Pages 329-344

  Shaffer, Timothy D ^a   Ashbaugh, John R ^a  

^a EXXONMOBIL UPSTREAM RESEARCH COMPANY   (United States)

Author keywords

Carbocationic polymerization; Isobutylene; Metallocenes; Noncoordinating anions; Styrenics

Indexed keywords

CATALYSIS; CATALYST ACTIVITY; CATALYSTS; ETHERS; INITIATORS (CHEMICAL); MOLECULAR STRUCTURE; OLIGOMERS; ORGANOMETALLICS; SOLVENTS; STYRENE;

CARBOCATIONIC POLYMERIZATIONS; ISOBUTYLENE POLYMERIZATIONS; LEWIS ACIDS; METALLOCENES; NONCOORDINATING ANIONS (NCA); STEREOREGULARITY; STYRENICS;

CATIONIC POLYMERIZATION;

EID: 0030871110     PISSN: 0887624X     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1099-0518(19970130)35:2<329::AID-POLA16>3.0.CO;2-R     Document Type: Article

References (35)

1. (a) R. Quyoum, Q. Wang, M.-J. Tudoret, M. C. Baird, and D. J. Gillis, J. Am. Chem. Soc., 116, 6435 (1994);
2. (b) F. Barsan, M. C. Baird, J. Chem. Soc., Chem. Commun., 2065 (1995);
3. (c) Q. Wang, R. Quyoum, D. J. Gillis, M.-J. Tudoret, D. Jeremic, B. K. Hunter, and M. C. Baird, Organometallics, 15, 693 (1996).
4. D. J. Gillis, M.-J. Tudoret, and M. C. Baird, J. Am. Chem. Soc., 115, 2543 (1993).
5. J. P. Kennedy, J. Macromol. Sci. Chem., A6, 329 (1972).
6. (a) L. Balogh, L. Wang, and R. Faust, Macromolecules, 27, 3453 (1994);
7. (b) D. W. Grattan and P. H. Plesch, Makromol. Chem., 181, 751 (1980):
8. (c) F. R. Kalafov, F. M. Nasirov, N. E. Melnikova, B. A. Krentsel, and T. N. Schakltakltinsky, Makromol. Chem. Rapid Commun., 6, 29 (1985);
9. (d) E. Marechal, L. Bui, and H. A. Nguyen, Polym. Bull., 17, 157 (1987).
10. T. D. Shaffer, U.S. Pat. Appl. 08/234,782, April 1994.
11. J. P. Kennedy and E. Marechal, Carbocationic Polymrization, J. Wiley & Sons, New York, 1982.
12. N. Ishihara, T. Seimiya, and M. Kuramoto, Macromolecules, 19, 2465 (1986).
13. C. Pellecchia, P. Longo, A. Grassi, P. Ammendola, and A. Zambelli, Makromol. Chem. Rapid Commun., 8, 277 (1987).
14. N. Ishihara, M. Kuramoto, and M. Uoi, Macromolecules, 21, 3356 (1988).
15. A. Zambelli, L. Oliva, and C. Pellecchia, Macromolecules, 22, 2129 (1989).
16. C. Pellecchia, P. Longo, A. Proto, and A. Zambelli, Makromol. Chem. Rapid Commun., 13, 265 (1992).
17. C. Pellecchia, D. Pappalardo, L. Oliva, and A. Zambelli, J. Am. Chem. Soc., 117, 6539 (1995).
18. Y. Ohsumi, T. Higashimura, and S. Okamura, J. Polym. Sci. A1, 4, 923 (1966).
19. T. Kunitake and C. Aso, J. Polym. Sci. A1, 8, 665 (1970).
20. M. Sawamoto, Prog. Polym. Sci., 16, 11 (1991).
21. J. C. W. Chien, W.-M. Tsai, and M. M. Rausch, J. Am. Chem. Soc., 113, 8570 (1991).
22. A. G. Massey and A. J. Park, J. Organomet. Chem., 2, 245 (1964).
23. M. Mena, M. A. Pellinghelli, P. Royo, R. Serrano, and A. Tiripicchio, J. Chem. Soc., Chem. Commun., 1118 (1986).
24. J. B. Lambert and S. Zhang, J. Chem. Soc., Chem. Commun., 383 (1993).
25. O. Nuyken, S. D. Pask, A. Vischer, and M. Walter, Makromol. Chem., 186, 173 (1985).
26. M. Gyor, H.-C. Wang, and R. Faust, J. Macromol. Sci., Pure Appl. Chem., A29, 639 (1992).
27. K. Matyjaszewski, J. Macromol. Sci., Pure Appl. Chem., A31, 989 (1994).
28. J. M. Moulis, J. Collomb, A. Gandini, and H. Cheradame, Polym. Bull., 3, 197 (1980).
29. J. P. Kennedy and S. Rengachary, Adv. Polym. Sci., 14, 1 (1974).
30. K. Matyjaszewski, C.-H. Lin, and C. Pugh, Macromolecules, 26, 2649 (1993).
31. Z. Guo, D. C. Swenson, and R. F. Jordan, Organometallics, 13, 1424 (1994).
32. + with isobutylene (1:1 mol : mol; 0.17 mol/L) in methylene chloride results in 100% conversion to the indane in 24 h.
33. J. P. Kennedy, Cationic Polymerization of Olefins: A Critical Inventory, J. Wiley & Sons, New York, 1975.
34. S. Stombowski and S. Penczek, Int. Symp. Cationic Polym., Rouen, France, 1973, Communication 35.
35. J. B. Lambert, S. Zhang, C. L. Stern, and J. C. Huffman, Science, 260, 1917 (1993).