Experimental and theoretical studies on the mechanism of photochemical hydrogen transfer from 2-aminobenzimidazole to nπ* and ππ*aromatic ketones

Journal of Physical Chemistry B

Volumn 114, Issue 36, 2010, Pages 11920-11926

  Jornet, Dolors ^a   Bartovský, Pavel ^a   Domingo, Luis R ^b   Tormos, Rosa ^a   Miranda, Miguel A ^a  

^a UNIVERSITAT POLITÈCNICA DE VALÈNCIA   (Spain)

^b UNIVERSITY OF VALENCIA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

ABSTRACTING; AROMATIC COMPOUNDS; AROMATIZATION; DENSITY FUNCTIONAL THEORY; EXCITED STATES; FREE RADICAL REACTIONS; HYDROGEN; ION EXCHANGE; KETONES; MOLECULAR OXYGEN; PHOTOLYSIS; PROTON TRANSFER; QUENCHING; SOLVENTS; SPECTROSCOPY;

AMINO GROUP; AMINYL RADICAL; AROMATIC KETONES; AROMATIC RINGS; BIRADICALS; CARBONYL OXYGEN ATOMS; DENSITY FUNCTIONAL THEORY METHODS; DIFFUSION CONTROL; ELECTRON ACCEPTOR; HYDROGEN ABSTRACTION; HYDROGEN TRANSFER; KETYL RADICALS; LASER FLASH PHOTOLYSIS; MOLECULAR COMPLEXES; QUENCHING RATE CONSTANT; RADICAL ION PAIRS; RADICAL PAIR; REACTION MECHANISM; RELATIVE ENERGIES; SOLVENT POLARITY; SPECTRAL CHANGE; THEORETICAL STUDY; THERMODYNAMIC CALCULATIONS; TRANSIENT ABSORPTION SPECTRA;

RATE CONSTANTS;

EID: 77956511207     PISSN: 15206106     EISSN: 15205207     Source Type: Journal    
DOI: 10.1021/jp1053327     Document Type: Article

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