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Volumn 114, Issue 35, 2010, Pages 11430-11435

Clathrate hydrates for ozone preservation

Author keywords

[No Author keywords available]

Indexed keywords

ATMOSPHERIC PRESSURE; CARBON TETRACHLORIDE; HYDRATION; OZONE; X RAY DIFFRACTION; X RAY DIFFRACTION ANALYSIS; XENON;

EID: 77956311674     PISSN: 15206106     EISSN: 15205207     Source Type: Journal    
DOI: 10.1021/jp105031n     Document Type: Article
Times cited : (29)

References (34)
  • 1
    • 69949148848 scopus 로고    scopus 로고
    • Jablonsky, M. Wood Res. 2009, 54 (2) 73-82
    • (2009) Wood Res. , vol.54 , Issue.2 , pp. 73-82
    • Jablonsky, M.1
  • 7
    • 85067743319 scopus 로고    scopus 로고
    • Refs 1-6 are only recent examples of numerous reports on ozone-related technology. Refs 3, 4, and 6 are review articles, each referring to many previous studies on a specific ozone-application technology
    • Refs 1-6 are only recent examples of numerous reports on ozone-related technology. Refs 3, 4, and 6 are review articles, each referring to many previous studies on a specific ozone-application technology.
  • 8
    • 85067755274 scopus 로고    scopus 로고
    • The various applications of ozonated water have been reported in numerous papers, which cannot be listed here. The literature about ozonated ice is very limited; the following three are probably all of the relevant publications presently available
    • The various applications of ozonated water have been reported in numerous papers, which cannot be listed here. The literature about ozonated ice is very limited; the following three are probably all of the relevant publications presently available.
  • 9
    • 85067760751 scopus 로고    scopus 로고
    • U.S. Patent 7 127 900 B2
    • Yoshimura, K.; Yamamoto, H. U.S. Patent 7 127 900 B2, 2006.
    • (2006)
    • Yoshimura, K.1    Yamamoto, H.2
  • 16
    • 85067741643 scopus 로고    scopus 로고
    • Many studies have been performed about ozone decomposition in water or aqueous solutions. Refs 9-11 are examples of recent papers reporting the chronological decay of the ozone concentration in water
    • Many studies have been performed about ozone decomposition in water or aqueous solutions. Refs 9-11 are examples of recent papers reporting the chronological decay of the ozone concentration in water.
  • 17
    • 85067739758 scopus 로고    scopus 로고
    • Yoshimura et al. (8c) reported that 26% of the amount of ozone initially contained in a cylindrical ice block, 22 mm in diameter and 700 mm in length, was preserved for 10 days while the block was held in a room maintained at-18 °C
    • Yoshimura et al. (8c) reported that 26% of the amount of ozone initially contained in a cylindrical ice block, 22 mm in diameter and 700 mm in length, was preserved for 10 days while the block was held in a room maintained at-18 °C.
  • 19
    • 85067781412 scopus 로고
    • U.K. Patent Specification 961 115
    • Waller, J. G.; McTurk, G. U.K. Patent Specification 961 115, 1964.
    • (1964)
    • Waller, J.G.1    McTurk, G.2
  • 20
    • 85067756931 scopus 로고    scopus 로고
    • Although McTurk and Waller (-15, 16) reported that they had used a crystal of carbon tetrachloride hydrate as a "seed" for forming an ozone-containing hydrate, this is presumably incorrect. It is generally believed that carbon tetrachloride does not form a hydrate by itself. It may form a mixed (or double) hydrate only in the presence of some "help gas", such as methane or nitrogen. (18) It is likely that what McTurk and Waller (15, 16) called the "carbon tetrachloride hydrate" was a mixed hydrate encaging, in addition to carbon tetrachloride, ambient-air-originated oxygen or nitrogen
    • Although McTurk and Waller (-15, 16) reported that they had used a crystal of carbon tetrachloride hydrate as a "seed" for forming an ozone-containing hydrate, this is presumably incorrect. It is generally believed that carbon tetrachloride does not form a hydrate by itself. It may form a mixed (or double) hydrate only in the presence of some "help gas", such as methane or nitrogen. (18) It is likely that what McTurk and Waller (15, 16) called the "carbon tetrachloride hydrate" was a mixed hydrate encaging, in addition to carbon tetrachloride, ambient-air-originated oxygen or nitrogen.
  • 21
    • 0003588755 scopus 로고    scopus 로고
    • 3rd ed.; CRC Press: Boca Raton, FL,; pp, 73 - 85, 179 - 180
    • Sloan, E. D.; Koh, C. A. Clathrate Hydrates of Natural Gases, 3rd ed.; CRC Press: Boca Raton, FL, 2007; pp 53 - 59, 73 - 85, 179 - 180.
    • (2007) Clathrate Hydrates of Natural Gases , pp. 53-59
    • Sloan, E.D.1    Koh, C.A.2
  • 22
    • 85067744512 scopus 로고    scopus 로고
    • 12 cages by ozone molecules in these samples to be up to 6.4% and 37%, respectively. If the evolved gas was a mixture of ozone and oxygen, the mass fraction and the cage occupancy must have been lower than these estimates
    • 12 cages by ozone molecules in these samples to be up to 6.4% and 37%, respectively. If the evolved gas was a mixture of ozone and oxygen, the mass fraction and the cage occupancy must have been lower than these estimates.
  • 23
    • 85067758035 scopus 로고    scopus 로고
    • Patent Abstracts of Japan, Publication 2007-210881,. Released online in Patent and Utility Model Gazette DB of the Japan Patent Office
    • Masaoka, T.; Yamamoto, A.; Motoi, K. Patent Abstracts of Japan, Publication 2007-210881, 2007. Released online in Patent and Utility Model Gazette DB of the Japan Patent Office (http://www.ipdl.inpit.go.jp/homepg-e. ipdl).
    • (2007)
    • Masaoka, T.1    Yamamoto, A.2    Motoi, K.3
  • 25
    • 85067749841 scopus 로고    scopus 로고
    • 2 mixture and Xe
    • 2 mixture and Xe.
  • 26
    • 85067775133 scopus 로고    scopus 로고
    • 2O-rich liquid or ice) + hydrate] equilibrium temperature, corresponding to atmospheric pressure (101.3 kPa). Some information on the equilibrium pressure vs temperature relations is available in Part 1 of the Supporting Information. Note that, despite the above temperature setting, every hydrate during a preservation test could not be thermodynamically stable because compositional equilibrium with the surrounding atmosphere was unavailable
    • 2O-rich liquid or ice) + hydrate] equilibrium temperature, corresponding to atmospheric pressure (101.3 kPa). Some information on the equilibrium pressure vs temperature relations is available in Part 1 of the Supporting Information. Note that, despite the above temperature setting, every hydrate during a preservation test could not be thermodynamically stable because compositional equilibrium with the surrounding atmosphere was unavailable.
  • 34
    • 85067764542 scopus 로고    scopus 로고
    • 12 cages compared to oxygen molecules
    • 12 cages compared to oxygen molecules.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.