Proton-transfer reactions on hexanuclear platinum clusters: Reversible heterolytic cleavage of H2 and C-H activation affording a linear, cluster-containing polymer

Chemistry - A European Journal

Volumn 16, Issue 31, 2010, Pages 9468-9477

  Leoni, Piero ^a   Marchetti, Lorella ^a   Bonuccelli, Veronica ^a   Mohapatra, Swagat K ^a   Albinati, Alberto ^b   Rizzato, Silvia ^b  

^a UNIVERSITY OF PISA   (Italy)

^b UNIVERSITY OF MILAN   (Italy)

Author keywords

C H activation; Cluster compounds; Ethers; Platinum; Polymers

Indexed keywords

C-H ACTIVATION; C-H BOND; CLUSTER COMPOUNDS; CLUSTER UNITS; DIALKYL ETHERS; DIHYDROGEN; EDGE-BRIDGING; HETEROLYTIC CLEAVAGE; HETEROLYTIC SPLITTING; HEXANUCLEAR CLUSTERS; LOW TEMPERATURES; PLATINUM CLUSTERS; PROTON TRANSFER REACTIONS; REACTIVE SITE; REVERSE REACTIONS; SINGLE CRYSTAL X-RAY DIFFRACTION; SUBSTITUTED CLUSTERS;

ACTIVATION ANALYSIS; COMPLEXATION; ETHERS; HYDRIDES; LIGANDS; NEGATIVE IONS; ORGANIC COMPOUNDS; PLATINUM; POLYMERS; REACTION INTERMEDIATES; X RAY DIFFRACTION;

PLATINUM COMPOUNDS;

EID: 77955799770     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201000809     Document Type: Article

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