Tuning electronic behavior of carbonyl metal clusters by substitution of interstitial and capping atoms

Angewandte Chemie - International Edition

Volumn 41, Issue 19, 2002, Pages 3685-3688

  Collini, Davide ^a   Femoni, Cristina ^a   Iapalucci, Maria Carmela ^a   Longoni, Giuliano ^a   Svensson, Per H ^a   Zanello, Piero ^b  

^a UNIVERSITY OF BOLOGNA   (Italy)

^b UNIVERSITY OF SIENA   (Italy)

Author keywords

Carbonyl complexes; Cluster compounds; Electrochemistry; Nickel; Rhodium

Indexed keywords

NICKEL; RHODIUM COMPOUNDS; TUNING;

CARBONYL METAL CLUSTERS;

SUBSTITUTION REACTIONS;

ANTIMONY; ARSENIC; BISMUTH; CARBONYL DERIVATIVE; GERMANIUM; LIGAND; METAL COMPLEX; NICKEL; PHOSPHORUS; RHODIUM; SELENIUM; TELLURIUM; TIN;

ARTICLE; CRYSTAL STRUCTURE; ELECTRON; ELECTRON SPIN RESONANCE; MASS SPECTROMETRY; NANOPARTICLE; OXIDATION REDUCTION POTENTIAL; QUANTUM THEORY; X RAY DIFFRACTION;

EID: 0037020344     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3773(20021004)41:19<3685::AID-ANIE3685>3.0.CO;2-7     Document Type: Article

References (41)

1. a) U. Simon in Metal Clusters in Chemistry, Vol. 3 (Eds.: P. Braunstein, L. A. Oro, P. R. Raithby), Wiley-VCH, Weinheim, 1999, pp. 1342-1363;
2. b) G. Schmid, Y.-P. Liu, M. Schumann, T. Raschke, C. Radehaus, Nano Lett. 2001, 1, 405;
3. c) S. Hoeppener, L. Chi, H. Fuchs, Nano Lett. 2002, 2, 459;
4. d) M. H. V. Werts, M. Lambert, J.-P. Bourgoin, M. Brust, Nano Lett. 2002, 2, 43;
5. e) A. C. Templeton, W. P. Wuelfing, R. W. Murray, Acc. Chem. Res. 2000, 33, 27;
6. f) L. F. Chi, M. Hartig, T. Drechsler, T. Schwaack, C. Seidel, H. Fuchs, G. Schmid, Appl. Phys. Lett. 1998, 66, S187.
7. a) G. Longoni, F. Morazzoni, J. Chem. Soc. Dalton Trans. 1981, 1735;
8. b) V. G. Albano, L. Grossi, G. Longoni, M. Monari, S. Mulley, A. Sironi, J. Am. Chem. Soc. 1992, 114, 5708;
9. c) J. Sinzig, L. J. de Jongh, A. Ceriotti, R. Della Pergola, G. Longoni, M. Stener, K. Albert, N. Rosch, Phys. Rev. Lett. 1998, 81, 3211.
10. G. Longoni, C. Femoni, M. C. Iapalucci, P. Zanello, in Metal Clusters in Chemistry, Vol. 2 (Eds.: P. Braunstein, L. A. Oro, P. R. Raithby), Wiley-VCH, Weinheim, 1999, pp, 1137-1158.
11. a) D. F. Rieck, R. A. Montag, T. S. McKechnie, L. F. Dahl, J. Am. Chem. Soc. 1986, 108, 1330;
12. b) R. E. Des Enfants, J. A. Gavney, R. K. Hayashi, A. D. Rae, L. F. Dahl, A. Bjarnason, J. Organomet. Chem. 1990, 383, 543;
13. c) D. F. Rieck, J. A. Gavney, R. L. Norman, R. K. Hayashi, L. F. Dahl, J. Am. Chem. Soc. 1992, 114, 10369;
14. d) J. P. Zebrowski, R. K. Hayashi, A. Bjarnason, L. F. Dahl, J. Am. Chem. Soc. 1992, 114, 3121;
15. e) A. J. Kahaian, J. B. Thoden, L. F. Dahl, J. Chem. Soc. Chem. Commun. 1992, 353;
16. f) J. P. Zebrowski, R. K. Hayashi, L. F. Dahl, J. Am. Chem. Soc. 1993, 115, 1142;
17. g) P. D. Mlynek, L. F. Dahl. Organometallics 1997, 16, 1641;
18. h) P. D. Mlynek, L. F. Dahl, Organometallics 1997, 16, 1655.
19. a) V. G. Albano, F. Demartin, M. C. Iapalucci, G. Longoni, A. Sironi, V. Zanotti, J. Chem. Soc. Chem. Commun. 1990, 547;
20. b) V. G. Albano, F. Demartin, M. C. Iapalucci, F. Laschi, G. Longoni, A. Sironi, P. Zanello, J. Chem. Soc. Dalton Trans. 1991, 739;
21. c) V. G. Albano, F. Demartin, M. C. Iapalucci, G. Longoni, M. Monari, P. Zanello, J. Chem. Soc. Dalton Trans. 1992, 497;
22. d) V. G. Albano, F. Demartin, C. Femoni, M. C. Iapalucci, G. Longoni, M. Monari, P. Zanello, J. Organomet. Chem. 2000, 593-594, 325.
23. a) S. Martinengo, G. Ciani, A. Sironi, P. Chini, J. Am. Chem. Soc. 1978, 100, 7096;
24. b) G. Ciani, A. Sironi, S. Martinengo, J. Organomet. Chem. 1980, 192, C42;
25. c) J. L. Vidal, R. C. Schoening, Inorg. Chem. 1981, 20, 265;
26. d) G. Ciani, A. Sironi, S. Martinengo, J. Chem. Soc. Dalton Trans. 1982, 1099.
27. J. L. Vidal, L. A. Kapicak, J. M. Troup, J. Organomet. Chem. 1981, 215, C11.
28. F. Demartin, C. Femoni, M. C. Iapalucci, A. Lombardi, G. Longoni, C. Marin, P. H. Svensson, J. Organomet. Chem. 2000, 614-615, 294.
29. D. A. Nagaki, J. V. Badding, A. M. Stacy, L. F. Dahl, J. Am. Chem. Soc. 1986, 108, 3825.
30. Kα radiation (λ = 0.71073 Å); the final R value was 0.0457 (wR = 0.0804) for 17837 independent reflections having I> 2σ(1).
31. Kα radiation (λ= 0.71073 Å); the final R value was 0.0735 (wR = 0.2162) for 4056 independent reflections having 1 > 2σ.
32. 4[3] contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12. Union Road, Cambridge CB21EZ, UK; fax: (+ 44) 1223-336-033; or deposit@ccdc.cam.ac.uk).
33. G. M. Sheldrick, SADABS. Universität Gottingen, Germany.
34. G. M. Sheldrick, SHELXS-97, Program for the Solution of Crystal Structures, Universität Göttingen, Germany, 1997
35. Handbook of Chemistry and Physics (Ed.: R. C. Weast), CRC Press, Cleveland, 1977
36. a) A. E. Stevens, C. S. Feigerle, W. C. Lineberger, J. Am. Chem. Soc. 1982, 104, 5026;
37. b) M. R. A. Blomberg, P. E. M. Siegbahn, T. J. Lee, A. P. Rendell, J. E. Rice, J. Chem. Phys. 1991, 95, 5898.
38. C. Mealli, D. M. Proserpio, J. Chem. Educ. 1990, 67, 399.
39. a) B. T. Heaton, C. Brown, D. O. Smith, L. Strona, R. J. Goodfellow, P. Chini, S. Martinengo, J. Am. Chem. Soc. 1980, 102, 6175;
40. b) C. Allevi, B. T. Heaton, C. Seregni, L. Strona, R. J. Goodfellow, P. Chini, S. Martinengo, J. Chem. Soc. Dalton Trans. 1986, 1375.
41. D. M. P. Mingos, L. Zheniang, J. Chem. Soc. Dalton Trans. 1988, 1657.