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Volumn 118, Issue 36, 1996, Pages 8580-8587

Cubic group 13 heterosiloxanes with four Co3(CO)9C cluster units as substituents: Novel soluble model compounds for synthetic zeolites showing catalytic activity in hydroformylation reactions

Author keywords

[No Author keywords available]

Indexed keywords

COBALT COMPLEX; METAL COMPLEX; ORGANOSILICON DERIVATIVE;

EID: 0029822819     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja952986w     Document Type: Article
Times cited : (40)

References (42)
  • 2
    • 10144245875 scopus 로고    scopus 로고
    • note
    • There have been several mechanistic studies to identify the real active species in this system.
  • 7
    • 0040262500 scopus 로고
    • Yoshida, S., Takezawa, N., Ono, T., Eds.; VCH: Weinheim; Kodansha: Tokyo
    • Ichikawa, M.; Rao, L.-f.; Fukuoka, A. Catalytic Science and Technology; Yoshida, S., Takezawa, N., Ono, T., Eds.; VCH: Weinheim; Kodansha: Tokyo, 1991; Vol. 1, pp 111-116.
    • (1991) Catalytic Science and Technology , vol.1 , pp. 111-116
    • Ichikawa, M.1    Rao, L.-F.2    Fukuoka, A.3
  • 8
    • 10144224186 scopus 로고
    • Eley, D. D., Pines, H., Weisz, P. B., Eds.; Academic Press: New York
    • Maxwell, E. Advances in Catalysis 31; Eley, D. D., Pines, H., Weisz, P. B., Eds.; Academic Press: New York, 1982.
    • (1982) Advances in Catalysis 31
    • Maxwell, E.1
  • 22
    • 10144236457 scopus 로고
    • Smolin, Yu. I.; Shepelev, Yu. F.; Ershov, A. S.; Khobbel, D. Dokl. Akad. Nauk SSSR 1987, 297, 1377; Chem. Abstr. 1988, 108, 229950 f.
    • (1988) Chem. Abstr. , vol.108
  • 25
    • 10144232709 scopus 로고    scopus 로고
    • note
    • Due to the poor solubility of the Al compound 2 in n-hexane, a solution spectrum for this compound could not be obtained. The spectrum was recorded only as a Nujol mull.
  • 41
    • 10144245874 scopus 로고    scopus 로고
    • note
    • A comparison of these values with that listed in Table 1 for catalytic runs carried out for 18 h indicates that the hydroformylation reaction is almost complete after 3 h in the case of 2 and 3, while the reaction with 4 is only half-way through.
  • 42
    • 10144222839 scopus 로고    scopus 로고
    • note
    • 13CO. The resonances of the apical carbon atoms could not be detected in the case of the Ga and In compounds 3 and 4 probably due to the line broadening owing to the spin-spin coupling with the three cobalt atoms.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.