The role of solvent on the mechanism of proton transfer to hydride complexes: The case of the [W3PdS4H3CdHiPe3(CO)] + cubane cluster

Chemistry - A European Journal

Volumn 16, Issue 5, 2010, Pages 1613-1623

  Algarra, Andrés G ^a   Basallote, Manuel G ^a   Feliz, Marta ^b   Jesus Fernandez Trujillo M ^a   Llusar, Rosa ^b   Safont, Vicent S ^b  

^a Campus Univ Rio San Pedro ^*  (Spain)

^b UNIVERSITAT JAUME I   (Spain)

Author keywords

Cluster compounds; Density functional calculations; Kinetics; Palladium; Sulfides; Tungsten

Indexed keywords

ACETONITRILE-WATER MIXTURE; ACID CONCENTRATIONS; ACID MOLECULES; CLUSTER COMPOUNDS; CUBANE CLUSTERS; DENSITY-FUNCTIONAL CALCULATIONS; DFT CALCULATION; DIHYDROGEN; DIHYDROGEN BONDS; HYDRIDE CLUSTER; HYDRIDE COMPLEXES; ION PAIRING; REACTION PATHWAYS; SECOND ORDERS; SECOND-ORDER DEPENDENCE; SOLVATED PROTONS; STRUCTURAL CHANGE;

ACETONITRILE; ACIDS; COMPLEXATION; DICHLOROMETHANE; HYDROGEN BONDS; PALLADIUM; PROBABILITY DENSITY FUNCTION; PROTON TRANSFER; REACTION KINETICS; SULFUR COMPOUNDS; TUNGSTEN; TUNGSTEN COMPOUNDS;

COORDINATION REACTIONS;

PALLADIUM; PROTON; SOLVENT; SULFIDE; TUNGSTEN;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; KINETICS; X RAY CRYSTALLOGRAPHY;

CATALYSIS; CRYSTALLOGRAPHY, X-RAY; KINETICS; MOLECULAR STRUCTURE; PALLADIUM; PROTONS; SOLVENTS; SULFIDES; TUNGSTEN;

EID: 75949103227     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200902233     Document Type: Article

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