Influence of media and homoconjugate pairing on transition metal hydride protonation. An IR and DFT study on proton transfer to CpRuH(CO)(PCy3)

Journal of the American Chemical Society

Volumn 125, Issue 25, 2003, Pages 7715-7725

  Belkova, Natalia V ^a   Besora, Maria ^b   Epstein, Lina M ^a   Lledós, Agustí ^b   Maseras, Feliu ^b   Shubina, Elena S ^a  

^a A N NESMEYANOV INSTITUTE OF ORGANOELEMENT COMPOUNDS   (Russian Federation)

^b UNIVERSITAT AUTÒNOMA DE BARCELONA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

CHLORINE COMPOUNDS; DISCRETE FOURIER TRANSFORMS; ENTHALPY; ENTROPY; HYDRIDES; HYDROGEN BONDS; INCLUSIONS; NEGATIVE IONS; POSITIVE IONS; PROTONS; REACTION KINETICS; RUTHENIUM COMPOUNDS; SOLVENTS; STRENGTH OF MATERIALS; THERMAL EFFECTS;

PROTONATION;

TRANSITION METAL COMPOUNDS;

ANION; CATION; DICHLOROMETHANE; HEXANE; HYDROGEN; LIGAND; PROTON; RUTHENIUM COMPLEX; SOLVENT; TRANSITION ELEMENT;

ARTICLE; CALCULATION; CHEMICAL ANALYSIS; CHEMICAL BINDING; CHEMICAL INTERACTION; CHEMICAL REACTION KINETICS; COMPLEX FORMATION; CONCENTRATION RESPONSE; CONJUGATE; ELECTRIC POTENTIAL; ENTHALPY; ENTROPY; HYDROGEN BOND; HYPOTHESIS; MOLECULAR STABILITY; POLARIZATION; PROTON TRANSPORT; REACTION ANALYSIS; SYNTHESIS; TECHNIQUE; TEMPERATURE DEPENDENCE; THEORETICAL MODEL;

EID: 0038546634     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja029712a     Document Type: Article

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