Unambiguous determination of the adsorption geometry of a metal-organic complex on a bulk insulator

Nano Letters

Volumn 10, Issue 8, 2010, Pages 2965-2971

  Lämmle, Knud ^a   Trevethan, Thomas ^b,c   Schwarz, Alexander ^a   Watkins, Matthew ^b   Shluger, Alexander ^b,c   Wiesendanger, Roland ^a  

^a UNIVERSITY OF HAMBURG   (Germany)

^b UNIVERSITY COLLEGE LONDON   (United Kingdom)

^c TOHOKU UNIVERSITY   (Japan)

Author keywords

Adsorption; Co Salen; DFT; NaCl(001); NC AFM; single molecule

Indexed keywords

ADSORBED MOLECULES; ADSORPTION GEOMETRIES; ADSORPTION SITE; AFM; ATOMIC STRUCTURE; CO-SALEN; COATED TIPS; DENSITY FUNCTIONAL THEORY CALCULATIONS; ENERGY CONFIGURATIONS; LOCAL ENERGY MINIMA; LOW ENERGY CONFIGURATIONS; METAL-ORGANIC; METAL-ORGANIC COMPLEXES; NACL(001); NONCONTACT ATOMIC FORCE MICROSCOPY; SCHIFF BASE COMPLEXES; SINGLE MOLECULE; SUB-LATTICES; TWO MIRRORS;

ADSORPTION; ATOMIC FORCE MICROSCOPY; ATOMS; CHROMIUM; CHROMIUM COMPOUNDS; COBALT COMPOUNDS; DENSITY FUNCTIONAL THEORY; FUNCTIONAL GROUPS; SODIUM CHLORIDE; STEREOCHEMISTRY; SURFACE STRUCTURE; VACUUM;

MOLECULES;

EID: 77955575644     PISSN: 15306984     EISSN: 15306992     Source Type: Journal    
DOI: 10.1021/nl101290t     Document Type: Article

References (46)

1. Besenbacher, F.; Lauritsen, J. V.; Wendt, S. Nano Today 2007, 2, 30
2. Venkatamaraman, L. Nano Lett. 2006, 6, 458
3. Heath, J. R. Rev. Mater. Res. 2009, 39, 30
4. Miller, J. S.; Epstein, A. J. MRS Bull. 2000, 25, 21
5. Hla, S. W.; Rieder, K.-H. Annu. Rev. Phys. Chem. 2003, 54, 307
6. Jenkins, S. J. Proc. R. Soc. London, Ser. A 2009, 465, 2949
7. Onishi, H.; Sasahara, A.; Uetsuka, H.; Ishibashi, T. Appl. Surf. Sci. 2002, 188, 257
8. Namai, Y.; Fukui, K.; Iwasawa, Y. Nanotechnology 2004, 15, S49
9. Nony, L.; Bennewitz, R.; Pfeiffer, O.; Gnecco, E.; Baratoff, A.; Meyer, E.; Eguchi, T.; Gourdon, A.; Joachim, C. Nanotechnology 2004, 15, S91
10. Burke, S. A.; Mativetsky, J. M.; Hoffmann, R.; Grütter, P. Phys. Rev. Lett. 2005, 94, 096102
11. Kunstmann, T.; Schlarb, A.; Fendrich, M.; Wagner, T.; Möller, R. Phys. Rev. B 2005, 71, 121403
12. Dienel, T.; Loppacher, C.; Mannfeld, S. C. B.; Forker, R.; Fritz, T. Adv. Mater. 2008, 20, 959
13. Burke, S. A.; Ji., W.; Mativetsky, J. M.; Topple, J. M.; Fostner, S.; Gao, H.-J.; Guo, H.; Grütter, P. Phys. Rev. Lett. 2008, 100, 186104
14. Schütte, J.; Bechstein, R.; Rahe, P.; Kühnle, A.; Langhals, H. Phys. Rev. B 2009, 79, 045428
15. Loske, F.; Bechstein, R.; Schütte, J.; Ostendorf, F.; Reichling, M.; Kühnle, A. Nanotechnology 2009, 20, 065606
16. Fremy, S.; Schwarz, A.; Lämmle, K.; Prosenc, M.; Wiesendanger, R. Nanotechnology 2009, 20, 405608
17. Hofer, W. A.; Foster, A. S.; Shluger, A. L. Rev. Mod. Phys. 2003, 75, 1287
18. Sawada, D.; Sugimoto, Y.; Morita, K.; Abe, M.; Morita, S. Appl. Rev. Lett. 2009, 94, 173117
19. Sushko, M. L.; Gal, A. Y.; Watkins, M.; Shluger, A. L. Nanotechnology 2006, 17, 2062-2072
20. Atodiresei, N.; Caciuc, V.; Blugel, S.; Holscher, H. Phys. Rev. B 2008, 77, 153408
21. Gross, L.; Mohn, F.; Moll, N.; Liljeroth, P.; Meyer, G. Science 2009, 325, 1110
22. Eigler, D. M.; Lutz, C. P.; Rudge, W. E. Nature 1991, 352, 600
23. Bartels, L.; Meyer, G.; Rieder, K. H. Appl. Phys. Lett. 1997, 71, 213
24. Other names for Co-Salen are Salcomine and N, N ?-1,2- Ethylenebis(salicylideniminato)-cobalt(II).
25. Tsumaki, T. Bull. Chem. Soc. Jpn. 1938, 13, 252
26. Vankatarananan, N. S.; Kuppuraj, G.; Rajagopal, S. Coord. Chem. Rev. 2005, 249, 1249
27. Kaiser, U.; Schwarz, A.; Wiesendanger, R. Nature 2007, 446, 522
28. Schmidt, R.; Lazo, C.; Hölscher, H.; Pi, U. H.; Caciuc, V.; Schwarz, A.; Wiesendanger, R.; Heinze, S. Nano Lett. 2009, 9, 200
29. Foster, A. S.; Shluger, A. L. Surf. Sci. 2001, 490, 211
30. Liebmann, M.; Schwarz, A.; Langkat, S. M.; Wiesendanger, R. Rev. Sci. Instrum. 2010, 81, 053902
31. The supersharp Si cantilevers (about 2 nm nominal tip radius) were purchased from Nanosensors (www.nanosensors.com).
32. Lämmle, K.; Schwarz, A.; Wiesendanger, R. Rev. Sci. Instrum. 2002, 73, 3508
33. Albrecht, T. R.; Grütter, P.; Horne, D.; Rugar, D. J. Appl. Phys. 1991, 69, 669
34. Bammerlin, M.; Lüthi, R.; Meyer, E.; Baratoff, A.; Lü, J.; Guggisberg, M.; Gerber, C.; Howald, L.; Güntherodt, H.-J. Probe Microsc. 1997, 1, 3
35. Bennewitz, R.; Pfeiffer, O.; Schär, S.; Barwich, V.; Meyer, E.; Kantorovich, L. N. Appl. Surf. Sci. 2002, 188, 232
36. Trevethan, T.; Kantorovich, L. Nanotechnology 2005, 16, S79
37. Hoffmann, R.; Weiner, D.; Schirmeisen, A.; Foster, A. S. Phys. Rev. B 2009, 80, 115426
38. bias) curves used for tip characterization are shown in the supplemenary of ref 27.
39. Becke, A. D. J. Chem. Phys. 1993, 98, 5648
40. Lee, C.; Yang, W.; Parr, R. G. Phys. Rev. B 1988, 37, 785
41. Makhmutovaa, R. I.; Vakulina, I. V.; Talipova, R. F.; Movsumzadeb, E. M.; Chuvashova, D. A. J. Molec. Struct. THEOCHEM 2007, 819, 21
42. Henson, N. J.; Hay, P. J.; Redondo, A. Inorg. Chem. 1999, 38, 1618
43. Sushko, P. V.; Shluger, A. L.; Baetzold, R. C.; Catlow, C. R. A. J. Phys.: Condens. Matter 2000, 12, 8257
44. Ortmann, F.; Bechstedt, F.; Schmidt, W. G. Phys. Rev. B 2006, 73, 205101
45. Boys, S. F.; Bernardi, F. Mol. Phys. 1970, 19, 553
46. Foord, J. S.; Lambert, R. M. Langmuir 1986, 2, 677