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21344459809
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US Department of Energy, Office of Basic Energy Sciences US DOE, Washington, DC
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US Department of Energy, Office of Basic Energy Sciences, Basic Research Needs for the Hydrogen Economy, US DOE, Washington, DC, 2004
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(2004)
Basic Research Needs for the Hydrogen Economy
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3
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34147134345
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Recent information can be found at:
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Recent information can be found at: http://www.eere.energy.gov/ hydrogenandfuelcells
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15
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32244446213
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R. S. Smith B. D. Kay B. Schmid L. Li N. Hess M. Gutowski T. Autrey Prep. Pap. Am. Chem. Soc., Div. Fuel Chem. 2005 50 112
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(2005)
Prep. Pap. Am. Chem. Soc., Div. Fuel Chem.
, vol.50
, pp. 112
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Smith, R.S.1
Kay, B.D.2
Schmid, B.3
Li, L.4
Hess, N.5
Gutowski, M.6
Autrey, T.7
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20
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20544432530
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A. Gutowska L. Li Y. Shin C. M. Wang X. S. Li J. C. Linehan R. S. Smith B. D. Kay B. Schmid W. J. Shaw M. Gutowski T. Autrey Angew. Chem., Int. Ed. 2005 44 3578
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(2005)
Angew. Chem., Int. Ed.
, vol.44
, pp. 3578
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Gutowska, A.1
Li, L.2
Shin, Y.3
Wang, C.M.4
Li, X.S.5
Linehan, J.C.6
Smith, R.S.7
Kay, B.D.8
Schmid, B.9
Shaw, W.J.10
Gutowski, M.11
Autrey, T.12
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34147164362
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See Fig. S1 in supplementary material
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See Fig. S1 in supplementary material
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34147148394
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3
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3
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25
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34147131618
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NMR Basic Princliples and Progress Grundlagen und Forschritte
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P. Diehl, E. Fluck, R. Kosfeld, H. Noth and B. Wrackmeyer, Springer-Verlag, Berlin, Heidelberg, New York
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NMR Basic Princliples and Progress Grundlagen und Forschritte, Nuclear Magnetic Resonance Spectroscopy of Boron Compounds, ed., P. Diehl,,, E. Fluck,,, R. Kosfeld,,, H. Noth, and, B. Wrackmeyer,, Springer-Verlag, Berlin, Heidelberg, New York, 1978
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(1978)
Nuclear Magnetic Resonance Spectroscopy of Boron Compounds, Ed.
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26
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34147159525
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2 peaks significantly broadened. If it is cooled before the old phase is completely consumed, it returns largely to old phase, but with some new phase and DADB still present. In both cases, within 1 min of reheating, the spectra looked identical to when the heating stopped
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2 peaks significantly broadened. If it is cooled before the old phase is completely consumed, it returns largely to old phase, but with some new phase and DADB still present. In both cases, within 1 min of reheating, the spectra looked identical to when the heating stopped
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27
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34147168509
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No visible melting of the polycrystalline material was observed. See supplementary material, Fig. S2, showing photographic images of AB in a melting point capillary at 90°C at times of 5, 20, 25, 30, 35, 40, 50 and 60 min
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No visible melting of the polycrystalline material was observed. See supplementary material, Fig. S2, showing photographic images of AB in a melting point capillary at 90°C at times of 5, 20, 25, 30, 35, 40, 50 and 60 min
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29
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34147189913
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2 species we observed from the decomposition of AB
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2 species we observed from the decomposition of AB
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30
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34147099385
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4 resonance of DADB precedes the formation of the dimer species
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4 resonance of DADB precedes the formation of the dimer species
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33
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34147164879
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Control experiments show that addition of a small fraction of DADB to a pure sample of AB significantly reduces if not eliminates the observed induction period at 88°C. The details of these experiments will be reported in a subsequent paper
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Control experiments show that addition of a small fraction of DADB to a pure sample of AB significantly reduces if not eliminates the observed induction period at 88°C. The details of these experiments will be reported in a subsequent paper
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35
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34147106844
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note
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2 peaks at similar intensities. Despite these spectral features, both sets of data yield similar results in terms of product identity and yield
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