Cascading transformations within a dynamic self-assembled system

Nature Chemistry

Volumn 2, Issue 8, 2010, Pages 684-687

  Campbell, Victoria E ^a   De Hatten, Xavier ^a,b   Delsuc, Nicolas ^b   Kauffmann, Brice ^b   Huc, Ivan ^b   Nitschke, Jonathan R ^a  

^a UNIVERSITY OF CAMBRIDGE   (United Kingdom)

^b UNIVERSITÉ DE BORDEAUX   (France)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 77954917327     PISSN: 17554330     EISSN: 17554349     Source Type: Journal    
DOI: 10.1038/nchem.693     Document Type: Article

References (40)

1. Ludlow, R. F. & Otto, S. Systems Chemistry. Chem. Soc. Rev. 37, 101-108 (2007).
2. Lehn, J.-M. Programmed chemical systems: multiple subprograms and multiple processing/expression of molecular information. Chem. Eur. J. 6, 2097-2102 (2000).
3. Lee, D. H., Severin, K. & Ghadiri, M. R. Autocatalytic networks: the transition from molecular self-replication to molecular ecosystems. Curr. Opin. Chem. Biol. 1, 491-496 (1997).
4. Jullien, L., Lemarchand, A., Charier, S., Ruel, O. & Baudin, J. B. Two-site molecules as a road for engineering complexity in chemical systems. J. Phys. Chem. B 107, 9905-9917 (2003).
5. Kindermann, M., Stahl, I., Reimold, M., Pankau, W. M. & Von Kiedrowski, G. Systems chemistry: kinetic and computational analysis of a nearly exponential organic replicator. Angew. Chem. Int. Ed. 44, 6750-6755 (2005).
6. Mukhopadhyay, P., Zavalij, P. Y. & Isaacs, L. High fidelity kinetic self-sorting in multi-component systems based on guests with multiple binding epitopes. J. Am. Chem. Soc. 128, 14093-14102 (2006).
7. Sarma, R. J. & Nitschke, J. R. Self-assembly in systems of subcomponents: simple rules, subtle consequences. Angew. Chem. Int. Ed. 47, 377-380 (2008).
8. Severin, K. The advantage of being virtual-target-induced adaptation and selection in dynamic combinatorial libraries. Chem. Eur. J. 10, 2565-2580 (2004).
9. Gomperts, B., Kramer, I. & Tatham, P. Signal Transduction (Academic Press, 2002).
10. Jeong, H., Tombor, B., Albert, R., Oltvai, Z. N. & Barabasi, A. L. The large-scale organization of metabolic networks. Nature 407, 651-654 (2000).
11. De Silva, A. P. & Uchiyama, S. Molecular logic and computing. Nature Nanotech. 2, 399-410 (2007).
12. Gupta, T. & van Der Boom, M. E. Redox-active monolayers as a versatile platform for integrating Boolean logic gates. Angew. Chem. Int. Ed. 47, 5322-5326 (2008).
13. Von Delius, M., Geertsema, E. M. & Leigh, D. A. A synthetic small molecule that can walk down a track. Nature Chem. 2, 96-101 (2010).
14. Badjic, J. D., Balzani, V., Credi, A., Silvi, S. & Stoddart, J. F. A molecular elevator. Science 303, 1845-1849 (2004).
15. Collin, J.-P., Dietrich-Buchecker, C., Gaviña, P., Jimenez-Molero, M. C. & Sauvage, J.-P. Shuttles and muscles: linear molecular machines based on transition metals. Acc. Chem. Res. 34, 477-487 (2001).
16. Schalley, C. A., Beizai, K. & Vogtle, F. On the way to rotaxane-based molecular motors: studies in molecular mobility and topological chirality. Acc. Chem. Res. 34, 465-476 (2001).
17. Eelkema, R. et al. Molecular machines: nanomotor rotates microscale objects. Nature 440, 163 (2006).
18. De Silva, A. P. & McClenaghan, N. D. Molecular-scale logic gates. Chem. Eur. J. 10, 574-586 (2004).
19. Kay, E. R., Leigh, D. A. & Zerbetto, F. Synthetic molecular motors and mechanical machines. Angew. Chem. Int. Ed. 46, 72-191 (2007).
20. Credi, A., Balzani, V., Langford, S. J. & Stoddart, J. F. Logic operations at the molecular level. An XOR gate based on a molecular machine. J. Am. Chem. Soc. 119, 2679-2681 (1997).
21. Petitjean, A., Kyrisakas, N. & Lehn, J.-M. Ion-triggered multistate molecular switching device based on regioselective coordination-controlled ion binding. Chem. Eur. J. 11, 6818-6828 (2005).
22. Schmittel, M. & Mahata, K. Multicomponent assembly of heterometallic isosceles triangles. Inorg. Chem. 3, 822-824 (2009).
23. Champin, B., Sartor, V. & Sauvage, J.-P. A highly rigid ditopic conjugate with orthogonal coordination axes and its zinc(II) and copper(I) complexes. New J. Chem. 32, 1048-1054 (2008).
24. Dietrich-Buchecker, C. O. et al. Quantitative formation of [2]catenanes using copper(I) and palladium(II) as templating and assembling centers: then entwining route and the threading approach. J. Am. Chem. Soc. 125, 5717-5725 (2003).
25. Marquis, A. et al. Messages in molecules: ligand/cation coding and selfrecognition in a constitutionally dynamic system of heterometallic double helicates. Chem. Eur. J. 12, 5623-5641 (2006).
26. Riis-Johannessen, T., Harding, L. P., Jeffery, J. C., Moon, R. & Rice, C. R. Allosteric derpogramming of a trinuclear heterometallic helicate. Dalton Trans. 1577-1587 (2007).
27. Canard, G. & Piguet, C. The origin of the suprising stabilities of highly charged self-assembled polymetallic complexes in solution. Inorg. Chem. 46, 3511-3522 (2007).
28. Albrecht, M., Liu, Y., Zhu, S. S., Schalley, C. A. & Frohlich, R. Self-assembly of heterodinuclear triple-stranded helicates: control by coordination number and charge. Chem. Commun. 1195-1197 (2009).
29. Hahn, F. E., Offermann, M., Isfort, C. S., Pape, T. & Fröhlich, R. Heterobimetallic triple-stranded helicates with directional benzene-o-dithiol catechol ligands. Angew. Chem. Int. Ed. 47, 6794-6797 (2008).
30. Christinat, N., Scopelliti, R. & Severin, K. Multicomponent assembly of boronic acid based macrocycles and cages. Angew. Chem. Int. Ed. 47, 1848-1852 (2008).
31. Pentecost, C. D. et al. A molecular Solomon link. Angew. Chem. Int. Ed. 46, 218-222 (2007).
32. Hutin, M., Franz, R. & Nitschke, J. R. A dynamic tricopper helicate. Chem. Eur. J. 12, 4077-4082 (2006).
33. Campbell, V. E. et al. Interplay of interactions governing the dynamic conversions of acyclic and macrocyclic helicates. Chem. Eur. J. 15, 6138-6142 (2009).
34. Rosen, B. M. et al. The disproportionation of Cu(I)X mediated by ligand and solvent into Cu(0) and Cu(II)X-2 and its implications for SET-LRP. J. Polym. Sci. Pol. Chem. 47, 5606-5628 (2009).
35. Funeriu, D. P., Lehn, J.-M., Fromm, K. M. & Fenske, D. Multiple expression of molecular information: enforced generation of different supramolecular inorganic architectures by processing of the same ligand information through specific coordination algorithms. Chem. Eur. J. 6, 2103-2111 (2000).
36. Piguet, C., Bernardinelli, G., Williams, A. F. & Bocquet, B. Formation of the first isomeric [2]catenates by self-assembly about two different metal ions. Angew. Chem. Int. Ed. 34, 582-584 (1995).
37. Stulz, E., Scott, S. M., Bond, A. D., Teat, S. J. & Sanders, J. K. M. Selection and amplification of mixed-metal porphyrin cages from dynamic combinatorial libraries. Chem. Eur. J. 9, 6039-6048 (2003).
38. Schultz, D. & Nitschke, J. R. Dynamic covalent and supramolecular direction of the synthesis and reassembly of copper(I) complexes. Proc. Natl Acad. Sci. USA 102, 11191-11195 (2005).
39. Schultz, D. & Nitschke, J. R. Designing multistep transformations using the Hammett equation: transimination on a copper(I) template. J. Am. Chem. Soc. 128, 9887-9892 (2006).
40. Schultz, D. & Nitschke, J. R. Kinetic and thermodynamic selectivity in subcomponent substitution. Chem. Eur. J. 13, 3660-3665 (2007).