Coexistence of two thermally induced intramolecular electron transfer processes in a series of metal complexes [M(Cat-N-BQ)(Cat-N-SQ)]/ [M(Cat-N-BQ)2] (M = Co, Fe, and Ni) bearing non-innocent catechol-based ligands: A combined experimental and theoretical study

Chemistry - A European Journal

Volumn 16, Issue 22, 2010, Pages 6666-6677

  Evangelio, Emi ^a   Bonnet, Marie Laure ^b   Cabañas, Miquel ^c   Nakano, Motohiro ^d   Sutter, Jean Pascal ^e   Dei, Andrea ^f   Robert, Vincent ^b   Ruiz Molina, Daniel ^a  

^a CATALAN INSTITUTE OF NANOSCIENCE AND NANOTECHNOLOGY ICN2   (Spain)

^b UNIVERSITÉ DE LYON   (France)

^c UNIVERSITAT AUTÒNOMA DE BARCELONA   (Spain)

^d OSAKA UNIVERSITY   (Japan)

^e LCC LABORATOIRE DE CHIMIE DE COORDINATION   (France)

^f Dept of Chemistry   (Italy)

Author keywords

Electron transfer; Magnetic properties; Mixed valent compounds; Radicals; Valence tautomerism

Indexed keywords

AB INITIO; CHARGE TRANSFER STATE; ELECTRON TRANSFER; ELECTRON TRANSFER PROCESS; EXPERIMENTAL STUDIES; INTERMOLECULAR ELECTRON TRANSFER; INTRA-MOLECULAR ELECTRON TRANSFER; MIXED-VALENT COMPOUNDS; NMR SPECTROSCOPY; SPIN STATE; THEORETICAL STUDY; THERMALLY INDUCED; TRIDENTATE SCHIFF-BASE; VARIABLE TEMPERATURE;

ELECTRON TRANSITIONS; ELECTRON TRANSPORT PROPERTIES; LIGANDS; MAGNETIC PROPERTIES; METAL COMPLEXES; METAL IONS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHENOLS; SPIN DYNAMICS;

FREE RADICAL REACTIONS;

EID: 77953146369     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200902568     Document Type: Article

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