Cyclodehydration of fluorinated diols using the mitsunobu reaction: Highly efficient synthesis of trifluoromethylated cyclic ethers

Synthesis

Volumn , Issue 11, 2010, Pages 1891-1898

  Prakash, G K Surya ^a   Do, Clement ^a   Wang, Fang ^a   Mathew, Thomas ^a   Olah, George A ^a  

^a UNIVERSITY OF SOUTHERN CALIFORNIA   (United States)

Author keywords

Cyclic ethers; Inversion of configuration; Mitsunobu reaction; Stereoselectivity; Trifluoromethylation

Indexed keywords

CYCLIC ETHER; INVERSION OF CONFIGURATION; MITSUNOBU REACTION; MITSUNOBU REACTIONS; TRIFLUOROMETHYLATION;

ETHERS; ORGANIC COMPOUNDS; STEREOSELECTIVITY;

SYNTHESIS (CHEMICAL);

1 (TRIFLUOROMETHYL) 1,3 DIHYDROISOBENZOFURAN; 1,1' (AZODICARBONYL)DIPIPERIDINE; 1,1,1 TRIFLUORO 2 [2 (2 HYDROXYETHYL)PHENYL]PROPAN 2 OL; 1,1,1 TRIFLUORO 2 [2 (HYDROXYMETHYL)PHENYL]PROPAN 2 OL; 1,1,1,3,3,3 HEXAFLUORO 2 [2 (2 HYDROXYETHYL)PHENYL]PROPAN 2 OL; 1,1,1,3,3,3 HEXAFLUORO 2 [2 (HYDROXYMETHYL)PHENYL]PROPAN 2 OL; 2 (TRIISOPROPYLSILYLOXYMETHYL)BENZALDEHYDE; 2 PHENYL 4 (TRIFLUOROMETHYL)OXETANE; 2,2 DIFLUORO 1 [2 (HYDROXYMETHYL)PHENYL] 2 (PHENYLSULFONYL)ETHANOL; 2,2,2 TRIFLUORO 1 [2 (2 HYDROXYETHYL)PHENYL] 1 PHENYLETHANOL; 2,2,2 TRIFLUORO 1 [2 (2 HYDROXYETHYL)PHENYL]ETHANOL; 2,2,2 TRIFLUORO 1 [2 (HYDROXYMETHYL)PHENYL]ETHANOL; 2,3 DIPHENYL 2 (TRIFLUOROMETHYL)OXIRANE; 3 [2 (1,1,1 TRIFLUORO 2 HYDROXYPROPAN 2 YL)PHENYL]PROPAN 1 OL; 3,3,3 TRIFLUORO 1,2 DIPHENYLPOPANE 1,2 DIOL; 4 PHENYL 2,2 BIS(TRIFLUOROMETHYL)OXETANE; 4,4,4 TRIFLUORO 1 PHENYL 3 (TRIFLUOROMETHYL)BUTANE 1,3 DIOL; 4,4,4 TRIFLUORO 1 PHENYLBUTANE 1,3 DIOL; 4,4,4 TRIFLUORO 3 HYDROXY 1 PHENYLBUTAN 1 ONE; ALKANOL; BENZYL ALCOHOL; CYANOMETHYLENE TRIBUTYLPHOSPHORANE; ETHER DERIVATIVE; N,N,N',N' TETRAMETHYLAZODICARBOXAMIDE; TRIBUTYLPHOSPHINE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL PROCEDURES; CHEMICAL STRUCTURE; CYCLODEHYDRATION; METHYLATION; MITSUNOBU REACTION; MOLECULAR STABILITY; STEREOCHEMISTRY; SYNTHESIS; TRIFLUOROMETHYLATION;

EID: 77952753742     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0029-1218753     Document Type: Article

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