The role of acyloxyphosphonium ions and the stereochemical influence of base in the phosphorane-mediated esterification of alcohols

Angewandte Chemie - International Edition

Volumn 42, Issue 34, 2003, Pages 4051-4054

  McNulty, James ^a   Capretta, Alfredo ^a   Laritchev, Vladimir ^a   Dyck, Jeff ^b   Robertson, Al J ^c  

^a MCMASTER UNIVERSITY   (Canada)

^b BROCK UNIVERSITY   (Canada)

^c Cytec Canada Inc   (Canada)

Author keywords

Acylation; Amines; Peroxides; Phosphanes; Synthetic methods

Indexed keywords

ESTERIFICATION; ESTERS; REACTION KINETICS; STEREOCHEMISTRY;

MITSUNOBU MECHANISM;

ALCOHOLS;

AMINE; BASE; ESTER DERIVATIVE; HEXANOL; ION; LACTIC ACID ETHYL ESTER; MENTHOL; PEROXIDE; PHOSPHONIUM DERIVATIVE; PHOSPHORANE DERIVATIVE; PROPANOL;

ACYLATION; ADDITION REACTION; ARTICLE; CHIRALITY; ESTERIFICATION; HYPOTHESIS; MITSUNOBU REACTION; OXIDATION REDUCTION REACTION; POLYMERIZATION; REACTION ANALYSIS; STEREOCHEMISTRY;

EID: 0141761618     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200351209     Document Type: Article

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