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Volumn 12, Issue 5, 2010, Pages 804-80

Glycerol as a cheap, safe and sustainable solvent for the catalytic and regioselective β,β-diarylation of acrylates over palladium nanoparticles

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EID: 77952382115     PISSN: 14639262     EISSN: 14639270     Source Type: Journal    
DOI: 10.1039/b925021b     Document Type: Article
Times cited : (70)

References (31)
  • 1
    • 0034249671 scopus 로고    scopus 로고
    • For selected overviews concerning the Mizoroki–Heck reaction, please see
    • For selected overviews concerning the Mizoroki–Heck reaction, please see:I. P. Beletskaya A. V. Cheprakov Chem. Rev. 2000 100 3009-3066.
    • (2000) Chem. Rev. , vol.100 , pp. 3009-3066
    • Beletskaya, I.P.1    Cheprakov, A.V.2
  • 2
    • 84879868832 scopus 로고    scopus 로고
    • M. Oestreich, John Wiley & Sons, Hoboken, NJ, USA
    • The Mizoroki–Heck Reaction, ed. M. Oestreich, John Wiley & Sons, Hoboken, NJ, USA, 2009.
    • (2009) The Mizoroki–Heck Reaction
  • 27
    • 0027702139 scopus 로고
    • The oxidation of glycerol by palladium is not favourable under our conditions and usually requires the assistance of promoters such as Bi or Au. For more information, please see
    • The oxidation of glycerol by palladium is not favourable under our conditions and usually requires the assistance of promoters such as Bi or Au. For more information, please see: H. Kimura Appl. Catal., A 1993 105 147-158.
    • (1993) Appl. Catal., A , vol.105 , pp. 147-158
    • Kimura, H.1
  • 30
    • 85032769606 scopus 로고    scopus 로고
    • 2. However, as can be visually observed in the Fig. 2 (dark color of the glycerol phase), we found that only the glycerol phase was contaminated with Pd. Therefore, after elimination of the glycerol phase by decantation, only a negligible contamination of the reaction products with Pd was observed
    • 2. However, as can be visually observed in the Fig. 2 (dark color of the glycerol phase), we found that only the glycerol phase was contaminated with Pd. Therefore, after elimination of the glycerol phase by decantation, only a negligible contamination of the reaction products with Pd was observed.


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