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Volumn 29, Issue 10, 2010, Pages 2332-2342

C-C bond activation of a cyclopropyl phosphine: isolation and reactivity of a tetrameric rhodacyclobutane

Author keywords

[No Author keywords available]

Indexed keywords

14-ELECTRON COMPLEX; AGOSTIC INTERACTIONS; C-C BOND ACTIVATION; C-C BONDS; CATALYTIC PROCESS; CHLORIDE ABSTRACTION; CIS-CYCLOOCTENE; CYCLOPROPYL; CYCLOPROPYL GROUP; FUNCTIONALIZATIONS; FUNCTIONALIZED PHOSPHINE; H NMR SPECTROSCOPY; NMR SPECTROSCOPY; PHOSPHINE LIGANDS; REDUCTIVE ELIMINATION; REGIO-SELECTIVE; SALT METATHESIS; SOLID-STATE STRUCTURES; TERMINAL ALKENES;

EID: 77952361655     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om100105p     Document Type: Article
Times cited : (23)

References (82)
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    • The organic fragment in this complex results from the Diels-Alder addition of hexafluorobut-2-yne to norbornadiene and binds through coordination of an alkene and adoption of a metallocyclobutane ring
    • The organic fragment in this complex results from the Diels-Alder addition of hexafluorobut-2-yne to norbornadiene and binds through coordination of an alkene and adoption of a metallocyclobutane ring (Evans, J. A.; Kemmitt, R. D. W.; Kimura, B. Y.; Russell, D. R. J. Chem. Soc., Chem. Commun. 1972, 509).
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    • 2 solution (under Ar) for extended periods (days) of time, demonstrating that it is the thermodynamically preferred product in this system
    • 2 solution (under Ar) for extended periods (days) of time, demonstrating that it is the thermodynamically preferred product in this system.
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    • 2′ dihedral angle of 171.6° (average over two disordered components) in the solid state, matching similar trends observed in 1-5 (Table 2)
    • 2′ dihedral angle of 171.6° (average over two disordered components) in the solid state, matching similar trends observed in 1-5 (Table 2).
  • 76
    • 0031059866 scopus 로고    scopus 로고
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    • Carter, C. W., Jr.; Sweet, R. M., Eds.; Academic Press: San Diego
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    • Otwinowski, Z.1    Minor, W.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.