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Volumn 129, Issue 31, 2007, Pages 9538-9539

Mechanistic study of competitive sp3-sp3 and sp 2-sp3 carbon-carbon reductive elimination from a platinum (IV) center and the isolation of a C-C agostic complex

Author keywords

[No Author keywords available]

Indexed keywords

PLATINUM;

EID: 34547743453     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja066195d     Document Type: Article
Times cited : (43)

References (31)
  • 6
    • 0033119285 scopus 로고    scopus 로고
    • Int. Ed, and references therein
    • Rybtchinski, B.; Milstein, D. Angew. Chem., Int. Ed. 1999, 38, 870 and references therein.
    • (1999) Angew. Chem , vol.38 , pp. 870
    • Rybtchinski, B.1    Milstein, D.2
  • 18
    • 34547790514 scopus 로고    scopus 로고
    • See Supporting Information
    • See Supporting Information.
  • 20
    • 34547765653 scopus 로고    scopus 로고
    • PtAr = 636 Hz).
    • PtAr = 636 Hz).
  • 21
    • 34547737679 scopus 로고    scopus 로고
    • 13C coupling constant of the aryl carbon in 3 is 1014 Hz, indicative of the very weak triflate trans to the aryl group.
    • 13C coupling constant of the aryl carbon in 3 is 1014 Hz, indicative of the very weak triflate trans to the aryl group.
  • 22
    • 34547730487 scopus 로고    scopus 로고
    • 3 by GC/MS.
    • 3 by GC/MS.
  • 26
    • 34547780245 scopus 로고    scopus 로고
    • See Supporting Information for details
    • See Supporting Information for details.
  • 27
    • 34547784238 scopus 로고    scopus 로고
    • An alternate mechanism in which the Pt-bound CH3 group itself acts as the nucleophile cannot be conclusively ruled out, though it lacks the precedent of an oxidative addition-type pathway ref 23 and references therein
    • 3 group itself acts as the nucleophile cannot be conclusively ruled out, though it lacks the precedent of an oxidative addition-type pathway (ref 23 and references therein).
  • 30
    • 34547797129 scopus 로고    scopus 로고
    • 3 (the latter of which was observed by NMR and GC/MS).
    • 3 (the latter of which was observed by NMR and GC/MS).
  • 31
    • 34547804516 scopus 로고    scopus 로고
    • 2H NMR spectroscopies.
    • 2H NMR spectroscopies.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.