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Volumn 352, Issue 6, 2010, Pages 1075-1080

The 1,3-diaminobenzene-derived aminophosphine palladium pincer complex {C6H3[NHP(piperidinyl)2]2Pd(Cl)} - A highly active Suzuki-Miyaura catalyst with excellent functional group tolerance

Author keywords

Aminophosphines; C C bond formation; Palladium; Pincer complexes; Suzuki miyaura reaction

Indexed keywords


EID: 77951166255     PISSN: 16154150     EISSN: 16154169     Source Type: Journal    
DOI: 10.1002/adsc.200900848     Document Type: Article
Times cited : (64)

References (64)
  • 3
    • 77951149941 scopus 로고    scopus 로고
    • (Eds.: F. Diederich, P. J. Stang), Wiley-VCH, Weinheim, chap. 2
    • b) A. Suzuki, in: Metal-Catalyzed Cross-Coupling Reactions, (Eds.: F. Diederich, P. J. Stang), Wiley-VCH, Weinheim, 1998, chap. 2;
    • (1998) Metal-Catalyzed Cross-Coupling Reactions
    • Suzuki, A.1
  • 29
    • 0013319981 scopus 로고    scopus 로고
    • For a review on Pd-catalyzed coupling reactions of aryl chlorides, see A. F. Littke, G. C. Fu, Angew. Chem. 2002, 114, 4350;
    • (2002) Angew. Chem. , vol.114 , pp. 4350
    • Littke, A.F.1    Fu, G.C.2
  • 55
    • 77951173475 scopus 로고    scopus 로고
    • note
    • The use of substrates containing ester groups is not appropriate, since significant transesterification was observed. Reactions performed with terminal olefins, such as 1-bromo-4-ethenylbenzene are possible but require prolonged reaction times for high conversions and are accompanied by significant amounts (up to 15%) of the corresponding Heck coupling products.
  • 58
    • 77951184331 scopus 로고    scopus 로고
    • note
    • The reason for the effect of water on the induction period is explained by decomposition of the pincer unit to form the active catalyst (most probably palladium nanoparticles).
  • 59
    • 0013326691 scopus 로고    scopus 로고
    • For a comprehensive review article about the problem of distinguishing true homogeneous catalysis from soluble or other metal-particle heterogeneous catalysis under reducing conditions see: J. A. Widegren, R. G. Finke, J. Mol. Catal. A 2003, 198, 317.
    • (2003) J. Mol. Catal. A , vol.198 , pp. 317
    • Widegren, J.A.1    Finke, R.G.2
  • 60
    • 77951190029 scopus 로고    scopus 로고
    • note
    • [19]


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.