Nucleophilicity and nucleofugality of phenylsulfinate (PhSO 2-): A key to understanding its ambident reactivity

Journal of the American Chemical Society

Volumn 132, Issue 13, 2010, Pages 4796-4805

  Baidya, Mahiuddin ^a   Kobayashi, Shinjiro ^a   Mayr, Herbert ^a  

^a UNIVERSITY OF MUNICH   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

AQUEOUS ACETONITRILE; AZIDE ION; BENZHYDRYLIUM IONS; CARBOCATIONS; CORRELATION EQUATION; DIFFERENT SOLVENTS; ELECTROPHILICITY; INTRINSIC BARRIERS; IONIZATION RATES; MALONATES; NUCLEOPHILICITIES; RELATIVE REACTIVITIES; SECOND-ORDER RATE CONSTANTS; STOPPED-FLOW TECHNIQUES; SULFINATES;

ACETONITRILE; ACTIVATION ENERGY; ARGON; IONIZATION; IONS; NUCLEOPHILES; OXYGEN; PARTICLE DETECTORS; SULFUR;

RATE CONSTANTS;

ACETONITRILE; AZIDE; BENZENE DERIVATIVE; DIMETHYL SULFOXIDE; MALONIC ACID; NUCLEOPHILE; OXYGEN; SOLVENT; SULFONE DERIVATIVE;

AMINO ACID SUBSTITUTION; ARTICLE; CHEMICAL REACTION; DIFFUSION; ENERGY; IONIZATION; ISOMER; SPECTROPHOTOMETRY; THERMODYNAMICS; THERMOSTABILITY;

KINETICS; MOLECULAR STRUCTURE; STEREOISOMERISM; SULFENIC ACIDS;

EID: 77950795121     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja9102056     Document Type: Article

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