Fluoride rearrangement reactions of polyphenyl- and polyvinylsilsesquioxanes as a facile route to mixed functional phenyl, vinyl T10 and T12 Silsesquioxanes

Journal of the American Chemical Society

Volumn 132, Issue 11, 2010, Pages 3723-3736

  Asuncion, M Z ^a   Laine, R M ^a  

^a UNIVERSITY OF MICHIGAN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ANALYTICAL METHOD; AVERAGE VALUES; CATALYTIC AMOUNTS; ELECTRONIC INTERACTIONS; EMISSION BEHAVIOR; FUNCTIONALIZED; HECK COUPLING; MALDI TOF MS; MODEL COMPOUND; NMR SPECTROSCOPY; OCTAMERS; POLYPHENYLSILSESQUIOXANE; REARRANGEMENT REACTIONS; SILICA CORES; SILSESQUIOXANES; STARTING MATERIALS; THERMALLY STABLE; UV-VIS ABSORPTIONS;

NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SILICA; SYNTHESIS (CHEMICAL); THERMOGRAVIMETRIC ANALYSIS;

OLIGOMERS;

4 BROMOSTYRENE; FLUORIDE; OLIGOMER; ORGANIC COMPOUND; POLYPHENYLSILSESQUIOXANE; POLYVINYLSILSESQUIOXANE; SILICON DERIVATIVE; STYRENE DERIVATIVE; UNCLASSIFIED DRUG; VINYL DERIVATIVE;

AIR; ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CATALYSIS; CONJUGATION; CONTROLLED STUDY; CROSS COUPLING REACTION; CRYSTAL STRUCTURE; FIELD EMISSION; FLUORIDATION; GEL PERMEATION CHROMATOGRAPHY; HECK REACTION; INFRARED SPECTROSCOPY; MATRIX ASSISTED LASER DESORPTION IONIZATION TIME OF FLIGHT MASS SPECTROMETRY; MOLECULAR INTERACTION; MOLECULAR WEIGHT; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; RING CLOSING METATHESIS; SUBSTITUTION REACTION; SYNTHESIS; THERMOGRAVIMETRY; THERMOSTABILITY; ULTRAVIOLET SPECTROSCOPY;

EID: 77949831453     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja9087743     Document Type: Article

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