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Volumn 352, Issue 4, 2010, Pages 637-643

Combination of enantioselective metal catalysis and organocatalysis: Enantioselective sequential hydroformylation/ aldol reactions

Author keywords

Aldol reaction; Asymmetric catalysis; Hy droformylation; Organocatalysis; Tandem reactions

Indexed keywords


EID: 77949828672     PISSN: 16154150     EISSN: 16154169     Source Type: Journal    
DOI: 10.1002/adsc.200900780     Document Type: Article
Times cited : (42)

References (71)
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    • For a recent review on combining transition metal cat-alysis and organocatalysis, see: Z. Shao, H. Zhang, Chem. Soc. Rev. 2009, 38, 2745.
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    • 12]
    • 12];
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    • (5)-2-Phenylpropanal was synthesized cleanly from commercially available (5)-2-phenylpropanol according to the literature procedure: 1929. The aldehyde can be stored under argon in the fridge for several weeks without significant racemization
    • -(5)-2-Phenylpropanal was synthesized cleanly from commercially available (5)-2-phenylpropanol according to the literature procedure: C Botuha, M. Haddad, M. Larcheveque, Tetrahedron: Asymmetry 1998, 9, 1929. The aldehyde can be stored under argon in the fridge for several weeks without significant racemization.
    • (1998) Tetrahedron: Asymmetry , vol.9
    • Botuha, C.1    Haddad, M.2    Larcheveque, M.3
  • 54
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    • For (S)-6-catalyzed aldol reactions see: a) S. Hajra, A. K. Giri, J. Org. Chem. 2008, 73, 3935;
    • (2008) J. Org. Chem. , vol.73 , pp. 3935
    • Hajra, S.1    Giri, A.K.2
  • 64
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    • For (S)-proline-catalyzed aldol reactions see: a
    • For (S)-proline-catalyzed aldol reactions see: a) F. Zhang, Y. Peng, Y. Gong, Chirality 2008, 20, 805;
    • (2008) Chirality , vol.20 , pp. 805
    • Zhang, F.1    Peng, Y.2    Gong, Y.3
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    • [5a]
    • [5a]
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    • The ratios of the stereocenters bearing the Ph group are calculated from the dr and ee of aldol products. The Supporting Information contains the information presented in Table 1 and Table 2 in an alternative format; ratios of all four stereoisomers are provided to give a clearer picture of double asymmetric induction and racemization.
    • The ratios of the stereocenters bearing the Ph group are calculated from the dr and ee of aldol products. The Supporting Information contains the information presented in Table 1 and Table 2 in an alternative format; ratios of all four stereoisomers are provided to give a clearer picture of double asymmetric induction and racemization.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.