Inverse electron demand asymmetric cycloadditions of cyclic carbonyl ylides catalyzed by chiral Lewis acids-Scope and limitations of diazo and olefinic substrates

Tetrahedron

Volumn 66, Issue 16, 2010, Pages 3070-3089

  Suga, Hiroyuki ^a   Higuchi, Satoshi ^a   Ohtsuka, Motoo ^a   Ishimoto, Daisuke ^a   Arikawa, Tadashi ^a   Hashimoto, Yuta ^a   Misawa, Shunta ^a   Tsuchida, Teruko ^a   Kakehi, Akikazu ^a   Baba, Toshihide ^b  

^a SHINSHU UNIVERSITY   (Japan)

^b TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

1,3 Dipolar cycloaddition; Asymmetric synthesis; Carbonyl ylide; Chiral Lewis acid; Diazocarbonyl compound; Metal catalyst

Indexed keywords

1 DIAZO 2,5 PENTANEDIONE DERIVATIVE; 2 BENZOPYRYLIUM 4 OLATE; 2,3 DIHYDROFURAN; 2,6 BIS[4,5 DIPHENYL 2 OXAZOLINYL]PYRIDINE; ALCOHOL; ALKENE DERIVATIVE; BINAPHTHYLDIIMINE; BUTYL TERT BUTYLDIMETHYLSILYLKETENE ACETAL; CYCLIC CARBONYL YLIDE; CYCLOHEXYL VINYL ETHER; LEWIS ACID; METHYL 2 (2 DIAZO 1,3 DIOXOALKYL)BENZOATE; UNCLASSIFIED DRUG;

ARTICLE; ASYMMETRIC SYNTHESIS; CATALYSIS; CHEMICAL REACTION; CHIRALITY; CYCLOADDITION; ELECTRON TRANSPORT; ENANTIOSELECTIVITY; PRIORITY JOURNAL;

EID: 77949567244     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tet.2010.01.095     Document Type: Article

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