Rh(I)-catalyzed decarboxylative transformations of arenecarboxylic acids: Ligand- and reagent-controlled selectivity toward hydrodecarboxylation or heck-mizoroki products

Organic Letters

Volumn 12, Issue 5, 2010, Pages 992-995

  Sun, Zhong Ming ^a   Zhang, Jing ^a   Zhao, Pinjing ^a  

^a NORTH DAKOTA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 77749254929     PISSN: 15237060     EISSN: 15237052     Source Type: Journal    
DOI: 10.1021/ol100001b     Document Type: Article

References (42)

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41. For example, the DIPHOS, DPPP, and DPPB ligands, while being the best ligands to promote hydrodecarboxylation (Table 1), gave good to excellent overall yields yet very poor selectivities. In contrast, BIPHEP and racemic BINAP ligands efficiently promoted the formation of conjugate addition byproduct. Please see ref 9 for details.
42. (R,R)-DIOP = (4R,5R)-(-)-4,5- bis(diphenylphosphanylmethyl)-2,2dimethyl- 1,3-dioxolane.