On the mechanism of the palladium(II)-catalyzed decarboxylative olefination of arene carboxylic acids. Crystallographic characterization of non-phosphine palladium(II) intermediates and observation of their stepwise transformation in Heck-like processes

Journal of the American Chemical Society

Volumn 127, Issue 29, 2005, Pages 10323-10333

  Tanaka, Daisuke ^a   Romeril, Stuart P ^a   Myers, Andrew G ^a  

^a HARVARD UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CARBOXYLIC ACIDS; CATALYSIS; CHARACTERIZATION; CRYSTALLOGRAPHY; OLEFINS; REACTION KINETICS;

CARBOXYL EXCHANGE; HECK REACTIONS; OLEFINATION;

PALLADIUM;

CARBOXYLIC ACID DERIVATIVE; DIMETHYL SULFOXIDE; FLUOROACETIC ACID; NORBORNENE DERIVATIVE; PALLADIUM; PALLADIUM BIS(TRIFLUOROACETATE); PHOSPHINE DERIVATIVE; POLYCYCLIC AROMATIC HYDROCARBON; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL MODIFICATION; COMPLEX FORMATION; CRYSTALLOGRAPHY; DECARBOXYLATION; ELIMINATION REACTION; FUNCTIONAL ASSESSMENT; LIGAND BINDING; METAL BINDING; OLEFINATION; PROCESS MODEL; SPECTROSCOPY;

CARBOXYLIC ACIDS; CATALYSTS; CRYSTALLOGRAPHY; OLEFINS; PALLADIUM;

EID: 22944483170     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja052099l     Document Type: Article

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