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Crystal data for 1 (C21H22N2O): orthorhombic, space group Pna21, Mr =318.41, a=16.8749(3), b=14.7594(2), c=6.8539(1) Å, ?=90?, V =1707.06(5)Å3, Z =4, ?calcd =1.239 g cm?3, ?= 0.077mm?1, R1 =0.0402, wR2 =0.1009, GOF=1.00 for all data, Flack x=0.1(2); Crystal data for 2 (C21H22N2O): monoclinic, space group Cc, Mr =318.41, a=14.7371(17), b=16.6050(18), c=6.9631(8) Å, ?=91.337(2)?, V =1703.5(3)Å3, Z =4, ?calcd = 1.242 g cm?3, ?=0.077mm?1, R1 =0.0442, wR2 =0.1114, GOF= 1.02 for all data, Flack x=?1.8(2); Crystal data for 3 (C22H22N2O3): orthorhombic, space group Pna21, Mr =362.42, a=10.3939(8), b=15.4715(12), c=11.7267(9) Å,V =1885.8(3)Å3, Z =4, ?calcd = 1.276 g cm?3, ?=0.086mm?1, R1 =0.0395, wR2 =0.1168, Flack x=1.2(1), GOF=1.03 for all data. CCDC reference number 632217-632219. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB21EZ, UK; fax: (+44) 1223-336-033; or deposit@ccdc.cam.ac.uk). As the crystals contain only non-heavy atoms, the Flack parameters for both absolute configurations are essentially meaningless and were not refined.
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