Two-dimensional homochiral manganese(II)-azido frameworks incorporating an achiral ligand: Partial spontaneous resolution and weak ferromagnetism

Journal of the American Chemical Society

Volumn 125, Issue 17, 2003, Pages 4984-4985

  Gao, En Qing ^a,b   Bai, Shi Qiang ^b   Wang, Zhe Ming ^a   Yan, Chun Hua ^a  

^a PEKING UNIVERSITY   (China)

^b QUFU NORMAL UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

AZIDE; FERROMAGNETIC MATERIAL; LIGAND; MANGANESE DERIVATIVE; METAL ION;

ARTICLE; CHIRALITY; CRYSTAL; MAGNETISM; OPTICAL ROTATION; TEMPERATURE;

EID: 0242668325     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja034129v     Document Type: Article

References (29)

1. (a) Rikken, G. L. J. A.; Raupach, E. Nature 1997, 390, 493-494.
2. (b) Rikken, G. L. J. A.; Raupach, E. Nature 2000, 405, 932-935.
3. (a) Kumaiga, H.; Inoue, K. Angew. Chem., Int. Ed. 1999, 38, 1601-1603.
4. (b) Minguet, M.; Luneau, D.; Lhotel, E.; Villar, V.; Paulsen, C.; Amabilino, D. B.; Veciana, J. Angew. Chem., Int. Ed. 2002, 41, 586-589.
5. (c) Inoue, K.; Imai, H.; Ghalsasi, P. S.; Kikuchi, K.; Ohba, M.; Okawa, H.; Yakhmi, J. V. Angew. Chem., Int. Ed. 2001, 40, 4242-4245.
6. (d) Andrés, R.; Brissard, M.; Gruselle, M.; Train, C.; Vaissermann, J.; Male'zieux, B.; Jamet, J.-P.; Verdaguer, M. Inorg. Chem. 2001, 40, 4633-4640.
7. (e) Coronado, E.; Gómez-García, C. J.; Nuez, A.; Romero, F. M.; Rusanov, E.; Stoeckli-Evans, H. Inorg. Chem. 2002, 41, 4615-4617.
8. (a) Coronado, E.; Galán-Mascarós, J. R.; Gómez-García, C. J.; Martínez-Agudo, J. M. Inorg. Chem. 2001, 40, 113-120.
9. (b) Hernéndez-Molina, M.; Lloret, F.; Ruiz-Pérez, C.; Julve, M. Inorg. Chem. 1998, 37, 4131-4135.
10. (c) Caneschi, A.; Gatteschi, D.; Ray, P.; Sessoli, R. Inorg. Chem. 1991, 30, 3936-3941.
11. (d) Han, S.; Manson, J. L.; Kim, J.; Miller, J. Inorg. Chem. 2000, 39, 4182-4185.
12. (e) Sporer, C.; Wurst, K.; Amabilino, D. B.; Ruiz-Molina, D.; Kopacka, H.; Jaitner, P.; Veciana, J. Chem Commun. 2002, 2342-2343 and references therein.
13. von Zelewskv, A.; Knof, U. Angew. Chem., Int. Ed. 1999, 38, 302-322.
14. Pérez-García, L.; Amabilino, D. B. Chem. Soc. Rev. 2002, 31, 342-356.
15. (a) Katsuki, I.; Motoda, Y.; Sunatsuki, Y.; Matsumoto, N.; Nakashima, T.; Kojima, M. J. Am. Chem. Soc. 2002, 124, 629-640.
16. (b) Ezuhara, T.; Endo, K., Aoyama, Y. J. Am. Chem. Soc. 1999, 121, 3279-3283.
17. (c) Tabellion, F. M.; Seidel, S. R.; Arif, A. M.; Stang, P. J. Angew. Chem., Int. Ed. 2001, 40, 1529-1532.
18. (d) Sasa, M.; Tanaka, K.; Bu, X.-H.; Shiro, M.; Shionoya, M. J. Am. Chem. Soc. 2001, 123, 10750-10751.
19. (a) Ribas, J.; Escuer, A.; Monfort, M.; Vicente, R.; Cortés, R.; Lezama, L.; Rojo, T. Coord. Chem. Rev. 1999, 193-195, 1027-1068 and references therein.
20. (b) Fu, A. H.; Huang, X. Y.; Li, J.; Yuen, T.; Lin, C. L. Chem.-Eur. J. 2002, 8, 2239-2247 and references therein.
21. (a) Xu, Z.; Thompson, L. K.; Miller, D. O.; Clase, H. J.; Howard, J. A. K.; Goeta, A. E. Inorg. Chem. 1998, 37, 3620.
22. (b) Hamblin, J.; Jackson, A.; Alcock, N. W.; Hannon, M. J. J. Chem. Soc., Dalton Trans. 2002, 1635-1641.
23. (c) Guo, D.; He, C.; Duan, C.-Y.; Qian, C.-Q.; Meng, Q.-J. New J. Chem. 2002, 26, 796-802.
24. (d) Xu, Z.; Thompson, L. K.; Miller, D. O. Inorg. Chem. 1997, 36, 3985-3995.
25. 3, Z = 3, R = 0.0425, GOF = 1.026 (see Supporting Information for further details).
26. (a) Dzyaloshinsky, I. Phys. Chem. Solids 1958, 4, 241-255.
27. (b) Moriya, T. Phys. Rev. 1960, 120, 91-98.
28. (c) Rettig, S. J.; Storr, A.; Summers, D. A.; Thompson, R. C.; Trotter, J. J. Am. Chem. Soc. 1997, 119, 8675-8680.
29. While preparing this Communication, we obtained another spontaneously resolved chiral compound from Mn(II) and a different diazine ligand, following the same synthetic strategy. Preliminary magnetic measurements indicated ferrimagnetic and metamagnetic behaviors.