메뉴 건너뛰기




Volumn 51, Issue 14, 2010, Pages 1876-1879

Second-generation total synthesis of (-)-diversifolin

Author keywords

[No Author keywords available]

Indexed keywords

DIVERSIFOLIN; LACTONE; SESQUITERPENE LACTONE DERIVATIVE; UNCLASSIFIED DRUG;

EID: 77549085866     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2010.02.012     Document Type: Article
Times cited : (9)

References (33)
  • 16
    • 0003780608 scopus 로고
    • Hafner K., Lehn J.-M., Rees C.W., Schleyer P.v.R., Trost B.M., and Zahradník R. (Eds), Springer
    • Reetz M.T. In: Hafner K., Lehn J.-M., Rees C.W., Schleyer P.v.R., Trost B.M., and Zahradník R. (Eds). Organotitanium Reagents in Organic Synthesis Vol. 24 (1986), Springer 123-189
    • (1986) Organotitanium Reagents in Organic Synthesis , vol.24 , pp. 123-189
    • Reetz, M.T.1
  • 18
    • 29044439970 scopus 로고    scopus 로고
    • Isomerization of terminal alkene occurred to some extent during RCM without p-benzoquinone. See also for the effect of p-benzoquinone:
    • Isomerization of terminal alkene occurred to some extent during RCM without p-benzoquinone. See also for the effect of p-benzoquinone:. Hong S.H., Sanders D.P., Lee C.W., and Grubbs R.H. J. Am. Chem. Soc. 127 (2005) 17160-17161
    • (2005) J. Am. Chem. Soc. , vol.127 , pp. 17160-17161
    • Hong, S.H.1    Sanders, D.P.2    Lee, C.W.3    Grubbs, R.H.4
  • 20
    • 77549085894 scopus 로고    scopus 로고
    • For diversifolin numbering, see 1a,b,d
    • For diversifolin numbering, see 1a,b,d.
  • 24
    • 77549086070 scopus 로고    scopus 로고
    • note
    • Direct RCM reaction of diol 12 was not successful due to the decomposition of the starting material.
  • 25
    • 77549085549 scopus 로고    scopus 로고
    • note
    • 3b
  • 26
    • 77549086014 scopus 로고    scopus 로고
    • note
    • In the previous synthesis, the corresponding diol was directly treated with NaH, followed by the acylation with isobutyryl chloride. In the present synthesis, however, it is necessary to discriminate the two hydroxyl groups at C5 and C8.
  • 31
    • 0039277875 scopus 로고
    • Reviews on Chugaev elimination, see:
    • Reviews on Chugaev elimination, see:. DePuy C.H., and King R.W. Chem. Rev. 60 (1960) 431-457
    • (1960) Chem. Rev. , vol.60 , pp. 431-457
    • DePuy, C.H.1    King, R.W.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.